bis(3,5-dimethylpyrazol-1-yl)phenylphosphine | 61324-11-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: bis(3,5-dimethylpyrazol-1-yl)phenylphosphine
• 英文别名: bis(3,5-dimethylpyrazolyl)phenylphosphine；3,5,3',5'-tetramethyl-1H,1'H-1,1'-phenylphosphanediyl-bis-pyrazole；Bis-(dimethylpyrazolyl)-phenylphosphin；Phenyl-bis-dimethylpyrazolphosphin；1,1'-(Phenylphosphanediyl)bis(3,5-dimethyl-1H-pyrazole)；bis(3,5-dimethylpyrazol-1-yl)-phenylphosphane
• CAS: 61324-11-6
• 化学式: C₁₆H₁₉N₄P
• 分子量: 298.327
• InChiKey: ZBUWGYHLLDEQLK-UHFFFAOYSA-N

物化性质

• 沸点：
  466.3±55.0 °C(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.7
• 重原子数：
  21
• 可旋转键数：
  3
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  35.6
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  乙二醇二甲醚溴化镍 、 bis(3,5-dimethylpyrazol-1-yl)phenylphosphine 以 四氢呋喃 为溶剂， 反应 24.0h， 以72%的产率得到
  参考文献：
  名称：

  Nickel complexes incorporating pyrazole-based ligands for ethylene dimerization to 1-butylene

  摘要：

  In this study we synthesized and characterized bis(3,5-dimethylpyrazolyl)dimethylsilane (L1) and bis(3,5-dimethylpyrazolyl) phenylphosphine (L2) and then prepared bidentate (N boolean AND N) nickel complexes by reacting L1 or L2 with NiBr2(DME). In combination with methylaluminoxane, diethylchloroaluminum or ethyldichloroaluminum (EADC) as co-catalyst, L1/Ni and L2/Ni complexes exhibited moderate catalytic activities (240-1310 kg/mol(Ni) h) and high selectivities (up to 93.2%) for ethylene dimerization toward 1-butylene. The catalytic performance was substantially affected by the co-catalyst type and ligand environment, especially the bridge atom. (C) 2015 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2015.04.041
• 作为产物：
  描述：

  3,5-二甲基吡唑 、 苯基二氯化磷 在 三乙胺 作用下， 以 四氢呋喃 为溶剂， 反应 24.0h， 以94%的产率得到bis(3,5-dimethylpyrazol-1-yl)phenylphosphine
  参考文献：
  名称：

  Nickel complexes incorporating pyrazole-based ligands for ethylene dimerization to 1-butylene

  摘要：

  In this study we synthesized and characterized bis(3,5-dimethylpyrazolyl)dimethylsilane (L1) and bis(3,5-dimethylpyrazolyl) phenylphosphine (L2) and then prepared bidentate (N boolean AND N) nickel complexes by reacting L1 or L2 with NiBr2(DME). In combination with methylaluminoxane, diethylchloroaluminum or ethyldichloroaluminum (EADC) as co-catalyst, L1/Ni and L2/Ni complexes exhibited moderate catalytic activities (240-1310 kg/mol(Ni) h) and high selectivities (up to 93.2%) for ethylene dimerization toward 1-butylene. The catalytic performance was substantially affected by the co-catalyst type and ligand environment, especially the bridge atom. (C) 2015 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2015.04.041

文献信息

• Davis, Harry B.; Hoyano, James K.; Leung, Ping Yuen, Canadian Journal of Chemistry, 1980, vol. 58, p. 151 - 158
  作者：Davis, Harry B.、Hoyano, James K.、Leung, Ping Yuen、Peterson, Louis K.、Wolstenholme, Brian

  DOI：——

  日期：——