tris[4-(1-propynyl)phenyl]amine | 1205745-59-0

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: tris[4-(1-propynyl)phenyl]amine
• 英文别名: 4-prop-1-ynyl-N,N-bis(4-prop-1-ynylphenyl)aniline
• CAS: 1205745-59-0
• 化学式: C₂₇H₂₁N
• 分子量: 359.47
• InChiKey: SEIFRIWTBINHEZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.4
• 重原子数：
  28
• 可旋转键数：
  6
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.11
• 拓扑面积：
  3.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  tris[4-(1-propynyl)phenyl]amine 、 四苯基环戊二烯酮 以 二苯醚 为溶剂， 反应 23.0h， 以92%的产率得到tris(3'-methyl-2',5',6'-triphenyl-p-terphenyl-4-yl)amine
  参考文献：
  名称：

  Triarylamines Designed to Form Molecular Glasses. Derivatives of Tris(p-terphenyl-4-yl)amine with Multiple Contiguous Phenyl Substituents

  摘要：

  The principles of crystal engineering can be used in a contrary way to help devise molecules that resist crystallization and form long-lived glasses. This can be achieved by making structural changes that thwart established patterns of crystallization. In using this strategy to block the crystallization of triarylamines, we have found that the introduction of methylpentaphenyl groups is particularly effective, presumably because they inhibit efficient molecular packing and normal intermolecular interactions.

  DOI：

  10.1021/ol902841c
• 作为产物：
  描述：

  三(4-碘苯)胺 、 1-丙炔溴化镁 在 zinc dibromide 、 四(三苯基膦)钯 作用下， 以 四氢呋喃 为溶剂， 反应 1.0h， 以81%的产率得到tris[4-(1-propynyl)phenyl]amine
  参考文献：
  名称：

  Triarylamines Designed to Form Molecular Glasses. Derivatives of Tris(p-terphenyl-4-yl)amine with Multiple Contiguous Phenyl Substituents

  摘要：

  The principles of crystal engineering can be used in a contrary way to help devise molecules that resist crystallization and form long-lived glasses. This can be achieved by making structural changes that thwart established patterns of crystallization. In using this strategy to block the crystallization of triarylamines, we have found that the introduction of methylpentaphenyl groups is particularly effective, presumably because they inhibit efficient molecular packing and normal intermolecular interactions.

  DOI：

  10.1021/ol902841c

文献信息

• Multiphoton Activable Quinoline Derivatives, Their Preparation and Their Uses
  申请人：Dalko Peter

  公开号：US20130116281A1

  公开（公告）日：2013-05-09

  The present invention relates to multiphoton activable organic compounds responding to the following formula (I). The present invention also relates to a method of synthesizing the compounds of the invention, to an aqueous solution comprising at least one compound of the invention, and to their specific uses. The present invention also concerns a method of liberating organic ligands, said method involving the step of irradiating a compound according to the invention.

  本发明涉及响应以下式（I）的多光子可激活有机化合物。本发明还涉及一种合成本发明化合物的方法，涉及至少包含一种本发明化合物的水溶液，以及它们的特定用途。本发明还涉及一种释放有机配体的方法，该方法涉及照射本发明化合物的步骤。
• US8993767B2
  申请人：——

  公开号：US8993767B2

  公开（公告）日：2015-03-31
• Triarylamines Designed to Form Molecular Glasses. Derivatives of Tris(<i>p</i>-terphenyl-4-yl)amine with Multiple Contiguous Phenyl Substituents
  作者：Eric Gagnon、Thierry Maris、James D. Wuest

  DOI：10.1021/ol902841c

  日期：2010.2.5

  The principles of crystal engineering can be used in a contrary way to help devise molecules that resist crystallization and form long-lived glasses. This can be achieved by making structural changes that thwart established patterns of crystallization. In using this strategy to block the crystallization of triarylamines, we have found that the introduction of methylpentaphenyl groups is particularly effective, presumably because they inhibit efficient molecular packing and normal intermolecular interactions.