silver(I) thiobenzoate | 26144-41-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: silver(I) thiobenzoate
• 英文别名: thiobenzoic acid ; silver (I)-compound；AgSCOC6H5；Thiobenzoesaeure; Silber(I)-Verbindung；silver;thiobenzate
• CAS: 26144-41-2
• 化学式: C₇H₅AgOS
• 分子量: 245.05
• InChiKey: UNSOQLGGIMAFNX-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  1.37
• 重原子数：
  10
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  18.1
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  silver(I) thiobenzoate 在 N-溴代丁二酰亚胺(NBS) 作用下， 以 氯仿 为溶剂， 反应 0.5h， 以61%的产率得到Benzoylsulfenyl bromide
  参考文献：
  名称：

  A Convenient Preparation of Aromatic Acylsulfenyl Bromides and Iodides via Silver Thiocarboxylates

  摘要：

  DOI：

  10.1055/s-1983-30420
• 作为产物：
  描述：

  Triphenylmethyl-thiol-benzoat 在 乙醇 、 silver nitrate 作用下， 生成 silver(I) thiobenzoate
  参考文献：
  名称：

  Vorlaender; Mittag, Chemische Berichte, 1913, vol. 46, p. 3453

  摘要：

  DOI：

文献信息

• Synthesis, Structures, and Photophysics of Polynuclear Silver(I) Thiolate and Silver(I) Thiocarboxylate Complexes with Dppm Ligands
  作者：Hsiu-Yi Chao、Li Wu、Cheng-Luan Li、Wei Lu、Li Liu、Xiao-Long Feng

  DOI：10.1002/zaac.201100231

  日期：2011.9

  Trinuclear silver(I) thiolate and silver(I) thiocarboxylate complexes [Ag3(μ-dppm)3(μn-SR)2](ClO4) [n = 2, R = C6H4Cl-4 (1) and CO}Ph (2); n = 3, R = tBu (3)], pentanuclear silver(I) thiolate complex [Ag5(μ-dppm)4(μ3-SC6H4NO2-4)4](PF6) (4), and hexanuclear silver(I) thiolate complexes [Ag6(μ-dppm)4(μ3-SR)4]Y2 [Y = ClO4, R =C6H4CH3-4 (5) and C10H7 (2-naphthyl) (7); Y = PF6, R = C6H4OCH3-4(6)], were

  三核硫醇银 (I) 和硫代羧酸银 (I) 络合物 [Ag3(μ-dppm)3(μn-SR)2](ClO4) [n = 2, R = C6H4Cl-4 (1) 和 CO}Ph (2); n = 3，R = tBu (3)]、五核银 (I) 硫醇盐复合物 [Ag5(μ-dppm)4(μ3-SC6H4NO2-4)4](PF6) (4) 和六核硫醇银 (I)配合物 [Ag6(μ-dppm)4(μ3-SR)4]Y2 [Y = , R =C6H4CH3-4 (5) 和 C10H7 (2-萘基) (7); Y = PF6，R = C6H4OCH3-4(6)]，合成[dppm = 双(二苯基膦基)甲烷]，并研究了它们的晶体结构和光物理特性。在 77 K 的固态下，三核硫醇银（I）和硫代羧酸银（I）配合物 1 和 2 在 470-523 nm 处显示发光，暂时归因于源自硫醇盐或硫代羧酸盐配体的 3IL（内配体），而六核银
• Synthesis and characterization of ternary AgInS2 nanocrystals by dual- and multiple-source methods
  作者：Lu Tian、Jagadese J. Vittal

  DOI：10.1039/b707960e

  日期：——

  The precursors [In(bipy)(SCO}Ph)3] and [Ag(SCO}Ph)] have been used to prepare monodispersed polyhedral shaped AgInS2 nanocrystals (NCs). The NCs were fully characterized by X-ray powder diffraction, transmission electron microscopy, selected area electron diffraction and energy dispersive X-ray analysis. The synthesis of AgInS2 NCs was further investigated by varying the dual- and multiple-source precursors and other parameters such as surfactants, surfactant ratio, temperature and time duration, to optimize the conditions to get better quality NCs. In all these reactions, a heterobimetallic thiobenzoate intermediate similar to the single-source precursor [(Ph3P)2AgIn(SCO}Ph)4] has been proposed to have formed which decompose subsequently to AgInS2 NCs.

  利用前驱体[In(bipy)(SCO}Ph)3]和[Ag(SCO}Ph)]制备了单分散多面体形状的 AgInS2 纳米晶体（NCs）。通过 X 射线粉末衍射、透射电子显微镜、选区电子衍射和能量色散 X 射线分析对这些纳米晶体进行了全面表征。通过改变双源和多源前驱体以及表面活性剂、表面活性剂比例、温度和持续时间等其他参数，进一步研究了 AgInS2 NCs 的合成，以优化条件，获得更高质量的 NCs。在所有这些反应中，都形成了与单源前体[(Ph3P)2AgIn(SCO}Ph)4]类似的硫代苯甲酸异重金属中间体，随后分解成 AgInS2 NCs。
• Synthesis, structures and spectroscopic properties of cyclometalated tri-tert-butylphosphine complexes of platinum(II)
  作者：Ninad Ghavale、Amey Wadawale、Sandip Dey、Vimal K. Jain

  DOI：10.1016/j.jorganchem.2010.07.005

  日期：2010.10

  spectroscopy. Stereochemistry of the complexes has been deduced by NMR spectroscopy. Structures of [Pt2(μ-SPh)2(C∩P)2], [Pt2(μ-pz)2(C∩P)2], [PtCl(Spy)(PBut3)], [Pt2(μ-SCOPh)2(C∩P)2] and [PtS2P(OPri)2}(C∩P)] have been established by single crystal X-ray diffraction analyses. The complex [Pt2(μ-SPh)2(C∩P)2] adopts a sym cis configuration while other binuclear complexes exist in a sym trans configuration

  的[PT反应2（μ-Cl）的2（C ∩ P）2 ]（C ∩ P = CH 2 C（我2）PBU吨2 -C，P）与各种阴离子配体配位体咬合和齿合度不同的已经研究，所得产物已通过元素分析和NMR（1 H，13 C，31 P，195 PT）光谱进行了表征。配合物的立体化学已经通过NMR光谱法推导。的结构[PT 2（μ-SPH）2（C ∩ P）2 ]，[铂2（μ-PZ）2（C ∩ P）2 ]，[氯铂酸（间谍）（PBU吨3）]，[铂2（μ-SCOPh）2（C ∩ P）2 ]和[铂S 2 P（OPR我）2 } （C∩P）]已通过单晶X射线衍射分析确定。络合物[铂2（μ-SPH）2（C ∩ P）2 ]采用符号顺式构型，而其它的双核配合物在一个符号中存在的反式构型。[PT S 2 P（OPr i）的分子结构2 }（C∩P）]揭示了络合物由两个四元螯合环组成，但在溶液中已提出基于195 PT NMR数据的二聚结构。
• [EN] COMPOSITIONS AND METHODS FOR MODULATING LIVER ENDOTHELIAL CELL FENESTRATIONS<br/>[FR] COMPOSITIONS ET MÉTHODES POUR MODULER LES FENESTRATIONS DE CELLULES ENDOTHÉLIALES HÉPATIQUES
  申请人：LECOUTEUR DAVID

  公开号：WO2019109124A1

  公开（公告）日：2019-06-13

  There is provided compositions and methods for modulating the fenestration porosity, fenestration frequency or fenestration diameter of liver endothelial cells. In particular compositions comprising conjugates of quantum dots and a therapeutic are used to modulate the fenestration porosity, frequency or diameter of liver endothelial cells.

  本发明提供了一种调节肝内皮细胞的小孔孔隙度、小孔频率或小孔直径的组合物和方法。具体而言，包含量子点和治疗剂的共轭物被用于调节肝内皮细胞的小孔孔隙度、频率或直径。
• Preparation method of near-infrared silver sulfide quantum dots
  申请人：SUZHOU INSTITUTE OF NANO-TECH AND NANO-BIONICS, CHINESE ACADEMY OF SCIENCES

  公开号：US10421901B2

  公开（公告）日：2019-09-24

  Provided is a preparation method of near-infrared silver sulfide quantum dots. The silver sulfide quantum dots have hydrophilic groups derived from a mercapto-containing hydrophilic reagent attached on the surface thereof, and the hydrophilic reagent is any one of mercaptoacetic acid, mercaptopropionic acid, cysteine, cysteamine, thioctic acid and ammonium mercaptoacetate or any combination thereof. The silver sulfide quantum dots have high fluorescence yield, good fluorescence stability, good biocompatibility and uniform sizes. The preparation method has moderate reaction conditions, simple operation, short production cycle, good reproducibility and is easy to control. The silver sulfide quantum dots can be used in the application of cellular imaging and biological tissue imaging.

  本发明提供了一种近红外硫化银量子点的制备方法。硫化银量子点表面附有由含巯基亲水试剂衍生的亲水基团，亲水试剂为巯基乙酸、巯基丙酸、半胱氨酸、半胱胺、硫辛酸和巯基乙酸铵中的任意一种或它们的任意组合。硫化银量子点具有荧光产率高、荧光稳定性好、生物相容性好、尺寸均匀等特点。该制备方法反应条件适中，操作简单，生产周期短，重现性好，易于控制。硫化银量子点可用于细胞成像和生物组织成像。