perfluoropropylbenzene | 54326-26-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: perfluoropropylbenzene
• 英文别名: 1,2,3,4,5-Pentafluoro-6-(heptafluoropropyl)benzene；1,2,3,4,5-pentafluoro-6-(1,1,2,2,3,3,3-heptafluoropropyl)benzene
• CAS: 54326-26-0
• 化学式: C₉F₁₂
• 分子量: 336.08
• InChiKey: QLOLJBGOVYZWBA-UHFFFAOYSA-N

物化性质

• 沸点：
  133.0±40.0 °C(Predicted)
• 密度：
  1.689±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.7
• 重原子数：
  21
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  12

反应信息

• 作为反应物：
  描述：

  perfluoropropylbenzene 在 三氯化铝 作用下， 以 四氯化碳 为溶剂， 反应 10.0h， 生成 氯五氟苯
  参考文献：
  名称：

  Thermolytic transformations of polyfluoroorganic compounds

  摘要：

  The reaction of alpha,alpha-dichlorooctafluoroethylbenzene with tetrafluoroethylene as a source of difluorocarbene has been studied. The copyrolysis of these compounds gave not only the expected products, decafluoro-alpha-methylstyrene and alpha-chloroheptafluorostyrene, but also noticeable amounts of perfluoro-1-methylindan and perfluoro-7-methylbicyclo[4.3.0]nona-1,4,6-triene along with perfluoro-3-methylindene and octafluorostyrene. It has been suggested that indan and the triene are formed with the participation of the C6F5CClCF3 radical through sigmatropic shifts of fluorine atoms in the intermediate bicyclic compounds. The reaction of alpha,alpha-dichlorodecafluoropropylbenzene with tetrafluoroethylene afforded alpha-chloroheptafluorostyrene as the main product.

  DOI：

  10.1007/bf00697041
• 作为产物：
  描述：

  全氟烯丙基苯 在 钒五氟化物 作用下， 以 一氟三氯甲烷 为溶剂， 反应 0.33h， 以96%的产率得到perfluoropropylbenzene
  参考文献：
  名称：

  五氟化钒对多卤代不饱和化合物的氟化

  摘要：

  五氟化钒在−25°至100°C的温度下或在无溶剂的情况下，在CFCl 3中与多氟化和多氯化烯烃，链二烯，环烯烃和环二烯反应，形成两个通过CC键加成氟原子的产物。

  DOI：

  10.1016/s0022-1139(00)85033-2

文献信息

• Formation of polyfluorofluorenes in the reactions of perfluoro-1,1-diphenylalkanes with antimony pentafluoride
  作者：Tatyana V. Mezhenkova、Victor M. Karpov、Yaroslav V. Zonov

  DOI：10.1016/j.jfluchem.2017.12.018

  日期：2018.3

  Perfluoro-1,1-diphenylethane heated with SbF5 at 130 °C with further treatment of the reaction mixture with HF-pyridine and then with water, gave perfluorinated 9‐methylfluorene and 9-methyl-1,2,3,4-tetrahydrofluorene. Perfluoro-1,1-diphenylpropane under similar conditions formed perfluoro-9-ethylfluorene and perfluoro-9,9-dimethyl-1,2,3,4-tetrahydrofluorene. When perfluoroisobutylbenzene was heated

  全氟-1,1-二苯乙烷与SbF 5在130°C加热，并将反应混合物先后用HF-吡啶和水处理，得到全氟9-甲基芴和9-甲基-1,2,3,4-四氢芴。全氟-1，1-二苯基丙烷在相似条件下形成全氟-9-乙基芴和全氟-9，9-二甲基-1，2，3，4-四氢芴。当将全氟异丁苯与五氟苯在SbF 5介质中于130°C加热时，先用HF-吡啶，然后用水进一步处理反应混合物，得到全氟-9-异丙基芴。用SbF 5加热的全氟二苯甲烷用水处理反应混合物后，得到全氟二苯甲酮。在混合物中未发现全氟芴或其衍生物。
• Aromatic polyfluoro-compounds. Part LV. Preparation and reactions of some polyfluoro(alkylbenzenes)
  作者：Paul L. Coe、Alan Whittingham

  DOI：10.1039/p19740000917

  日期：——

  aldehyde, followed by oxidation of the resulting alcohol to the ketone, which in turn has been treated with sulphur tetrafluoride. Some nucleophilic substitution reactions of these compounds and perfluoro-n-propylbenzene are described. The possibility of the use of some of the products as surfactants is discussed.

  由五氟苯基溴化镁与相应的醛反应，然后将所得的醇氧化为酮，由此制得全氟正丁基，正辛基和ω - H-正戊基苯。已经用四氟化硫处理过。描述了这些化合物和全氟正丙基苯的一些亲核取代反应。讨论了使用某些产品作为表面活性剂的可能性。
• Petrov, V. A.; Bardin, V. V.; Furin, G. G., Journal of Organic Chemistry USSR (English Translation), 1987, vol. 23, p. 37 - 41
  作者：Petrov, V. A.、Bardin, V. V.、Furin, G. G.、Avramenko, A. A.、Galakhov, M. V.、et al.

  DOI：——

  日期：——
• Transformation of perfluorinated benzocycloalkenes and alkylbenzenes to their carbonyl derivatives under the action of CF3COOH/SbF5
  作者：Yaroslav V. Zonov、Victor M. Karpov、Vyacheslav E. Platonov

  DOI：10.1016/j.jfluchem.2007.05.020

  日期：2007.9

  Perfluorinated benzocycloalkenes (benzocyclobutene, indan, tetralin), alkylbenzocycloalkenes and alkylbenzenes react with CF3COOH/SbF5 at 20-50 degrees C giving the corresponding carbonyl derivatives. (c) 2007 Elsevier B.V. All rights reserved.
• Karpov; Mezhenkova; Platonov, Russian Journal of Organic Chemistry, 1999, vol. 35, # 8, p. 1176 - 1181
  作者：Karpov、Mezhenkova、Platonov

  DOI：——

  日期：——