2-(4-fluoro-3-methylphenyl)naphthalene | 1177398-89-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 2-(4-fluoro-3-methylphenyl)naphthalene
• CAS: 1177398-89-8
• 化学式: C₁₇H₁₃F
• 分子量: 236.289
• InChiKey: DYYSHYRNQVTKED-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.3
• 重原子数：
  18
• 可旋转键数：
  1
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.06
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  2-萘甲腈 、 2-(4-Fluoro-3-methylphenyl)-5,5-dimethyl-1,3,2-dioxaborinane 在 copper (II)-fluoride 、 二氯化双(三环己基膦)镍(II) 、 potassium tert-butylate 、 三环己基膦 作用下， 以 1,4-二氧六环 为溶剂， 反应 20.0h， 以59%的产率得到2-(4-fluoro-3-methylphenyl)naphthalene
  参考文献：
  名称：

  Carbon−Carbon Formation via Ni-Catalyzed Suzuki−Miyaura Coupling through C−CN Bond Cleavage of Aryl Nitrile

  摘要：

  The Suzuki-Miyaura coupling of aryl nitriles with aryl/alkenyl boronic esters is reported. With this method, the cyano group could be applied as a protecting group of arenes and finally as a leaving group to further construct polyaryl scaffolds.

  DOI：

  10.1021/ol901217m

文献信息

• Mutual Activation: Suzuki-Miyaura Coupling through Direct Cleavage of the sp2 CO Bond of Naphtholate
  作者：Da-Gang Yu、Zhang-Jie Shi

  DOI：10.1002/anie.201101461

  日期：2011.7.25

  Working together: A new approach of mutual activation between naphtholates and aryl boronic acid derivatives by the formation of borates to facilitate the Suzuki–Miyaura coupling through direct cleavage of the sp2 CO bond by nickel catalysis is described (see scheme; R′: annulated ring system). Various naphtholates and aryl boronic acid derivatives could be directly coupled in good yields.

  一起工作：由硼酸盐的形成相互活化的naphtholates和芳基硼酸衍生物之间的一种新方法，以促进通过SP的直接裂解铃木-宫浦偶合2 ç  Ò由镍催化键被描述（参见方案; R' ：环形环系统）。各种萘甲酸酯和芳基硼酸衍生物可以以良好的产率直接偶联。
• Novel compounds for electronic material and organic electronic device using the same
  申请人：Gracel Display Inc.

  公开号：EP2182002B1

  公开（公告）日：2012-07-04
• PYRENE-BASED COMPOUND AND ORGANIC LIGHT-EMITTING DIODE COMPRISING THE SAME
  申请人：SAMSUNG DISPLAY CO., LTD.

  公开号：US20140183468A1

  公开（公告）日：2014-07-03

  A pyrene-based compound and an organic light-emitting diode including the pyrene-based compound are provided. The pyrene-based compound of Formula 1 above may emit blue light having high color purity. For example, an organic light-emitting diode including the pyrene-based compounds of the invention may emit blue light having a y coordinate with a color purity of 0.1 or less, for example, a color purity of 0.09 or less, which is near to the NTSC or sRGB specification. A thin film including the pyrene-based compounds of the invention may be highly amorphous, and thus may have improved electrical stability. Accordingly, an organic light-emitting diode including the pyrene-based compounds of the invention may have improved lifetime characteristics.
• Carbon−Carbon Formation via Ni-Catalyzed Suzuki−Miyaura Coupling through C−CN Bond Cleavage of Aryl Nitrile
  作者：Da-Gang Yu、Miao Yu、Bing-Tao Guan、Bi-Jie Li、Yang Zheng、Zhen-Hua Wu、Zhang-Jie Shi

  DOI：10.1021/ol901217m

  日期：2009.8.6

  The Suzuki-Miyaura coupling of aryl nitriles with aryl/alkenyl boronic esters is reported. With this method, the cyano group could be applied as a protecting group of arenes and finally as a leaving group to further construct polyaryl scaffolds.