N,N-dichloro-1-[4-[(dichloroamino)methyl]phenyl]methanamine | 1158998-97-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N,N-dichloro-1-[4-[(dichloroamino)methyl]phenyl]methanamine
• CAS: 1158998-97-0
• 化学式: C₈H₈Cl₄N₂
• 分子量: 273.977
• InChiKey: YYHPPOGFPXBRRX-UHFFFAOYSA-N

物化性质

• 沸点：
  370.6±35.0 °C(Predicted)
• 密度：
  1.504±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.8
• 重原子数：
  14
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  6.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  N,N-dichloro-1-[4-[(dichloroamino)methyl]phenyl]methanamine 在 三乙胺 作用下， 以 二氯甲烷 为溶剂， 反应 3.5h， 以82%的产率得到对苯二腈
  参考文献：
  名称：

  Poly(N,N′-dichloro-N-ethylbenzene-1,3-disulfonamide) and N,N,N′,N′-Tetrachlorobenzene-1,3-disulfonamide as Novel Reagents for the Synthesis of N-Chloroamines, Nitriles and Aldehydes

  摘要：

  介绍了聚（N,N′-二氯-N-乙基苯-1,3-二磺酰胺）（PCBS）和 N,N,N′,N′-四氯苯-1,3-二磺酰胺（TCBDA）作为新型试剂在各种条件下从伯胺制备 N,N-二氯胺、腈类和醛类的应用。此外，还成功地利用 TCBDA 和 PCBS 在氨水中实现了将伯醇直接氧化转化为腈的简单而有效的过程。

  DOI：

  10.1055/s-0028-1087967
• 作为产物：
  描述：

  1,4-苯二甲胺 在 N,N,N',N'-tetrachlorobenzene-1,3-disulfonamide 作用下， 反应 0.03h， 以90%的产率得到N,N-dichloro-1-[4-[(dichloroamino)methyl]phenyl]methanamine
  参考文献：
  名称：

  Poly(N,N′-dichloro-N-ethylbenzene-1,3-disulfonamide) and N,N,N′,N′-Tetrachlorobenzene-1,3-disulfonamide as Novel Reagents for the Synthesis of N-Chloroamines, Nitriles and Aldehydes

  摘要：

  介绍了聚（N,N′-二氯-N-乙基苯-1,3-二磺酰胺）（PCBS）和 N,N,N′,N′-四氯苯-1,3-二磺酰胺（TCBDA）作为新型试剂在各种条件下从伯胺制备 N,N-二氯胺、腈类和醛类的应用。此外，还成功地利用 TCBDA 和 PCBS 在氨水中实现了将伯醇直接氧化转化为腈的简单而有效的过程。

  DOI：

  10.1055/s-0028-1087967

文献信息

• Polymerizable composition, optical material comprising the composition and method for producing the material
  申请人：——

  公开号：US20040254258A1

  公开（公告）日：2004-12-16

  A cured matter obtained by polymerizing and curing a polymerizable composition comprising a compound having at least one episulfide in a molecule is reduced in an odor by adding a perfume to the polymerizable composition comprising the compound having at least one episulfide in a molecule. A cloudiness of the lens is removed by raising a purity of sulfur to 98% or more. A reduction in a chlorine content of the sulfur compound described above to 0.1% by weight or less elevates an oxidation resistance and a light fastness of the high refractive index optical material and improves a color tone thereof. An optical product having a high refractive index and a high-degree transparency is provided by subjecting the composition in advance to deaerating treatment at 0 to 100° C. for one minute to 24 hours under a reduced pressure of 0.001 to 50 torr.

  通过聚合和固化至少含有一种环硫醚的化合物的可聚合组合物获得的治愈物质，通过向至少含有一种环硫醚的化合物的可聚合组合物中添加香水来减少其气味。通过将硫的纯度提高到98％或更高，可以消除镜片的混浊。将上述硫化合物的氯含量降低至0.1％或更低可以提高高折射率光学材料的氧化抗性和耐光性，并改善其色调。通过在0至100°C下将组合物事先进行脱气处理，以在0.001至50 torr的减压下持续1分钟至24小时，可提供具有高折射率和高度透明度的光学产品。
• Thermoplastic resin composition comprising a polyamide
  申请人：SUMITOMO CHEMICAL COMPANY, LIMITED

  公开号：EP0258040A1

  公开（公告）日：1988-03-02

  A thermoplastic synthetic resin composition having a flexural modulus as defined in JIS K7203 of from 500 to 15,000 kg/cm² is obtained by partial crosslinking upon melt kneading a mixture of by weight: (A) from 20 to 60 parts of a polyamide resin; and (B) from 80 to 40 parts of an ethylene copolymer comprising the units (a) 40 to 90% of ethylene, (b) 5 to 60% of an α,β-unsaturated carboxylic acid alkyl ester, and (c) from 0.3 to 10% of maleic anhydride or a partially ionized maleic anhydride; with (C) from 0.01 to 20 parts, based on 100 parts by weight of the sum of the components (A) and (B), of a polyfunctional compound containing in its molecule at least two functional groups, e.g. an amino, epoxy, dihydrooxazolyl, carboxyl, carboxylic anhydride or hydroxyl group, which are reactive to a carboxyl, carboxylic anhydride or amino group. The composition is moldable and the excellent moldings have impact strength at low temperatures, low heat distortion, and high tensile strength at break and have a good balance between mechanical properties and thermal properties.

  一种热塑性合成树脂组合物，其弯曲模量在 JIS K7203 中定义为 500 至 15,000 kg/cm²，是通过部分交联熔融捏合按重量计的混合物而获得的： (A) 20 至 60 份聚酰胺树脂；和 (B) 80 至 40 份乙烯共聚物，其单元包括 (a) 40 至 90%的乙烯，(b) 5 至 60%的α，β-不饱和羧酸烷基酯，和 (c) 0.3 至 10%的顺丁烯二酸酐或部分离子化顺丁烯二酸酐；与 (C) 以 100 份组分(A)和(B)的重量总和为基准，0.01 至 20 份的多官能团化合物， 其分子中含有至少两个官能团，如氨基、环氧基、二氢恶唑基、羧基、羧酸酐或羟基， 这些官能团可与羧基、羧酸酐或氨基反应。 该组合物可模塑，其优良的模塑物具有低温冲击强度、低热变形和高断裂拉伸强度，并且在机械性能和热性能之间具有良好的平衡。
• Process for producing polymeric polyamide resin composition
  申请人：SUMITOMO CHEMICAL COMPANY, LIMITED

  公开号：EP0284379A2

  公开（公告）日：1988-09-28

  A polyamide resin composition is produced by melt kneading (A) 20 to 60 parts of a polyamide resin and (B) 40 to 80 parts of an ethylene copolymer comprising (a) 40 to 90 wt% of an ethylene unit, (b) 5 to 60 wt% of an α,β-unsaturated carboxylic acid alkyl ester unit and (c) 0.3 to 10 wt% of a maleic anhydride unit to form a partially crosslinked composition (I) and adding 50 to 1,000 parts by weight of a polyamide resin to 100 parts by weight of the composition (I) and melt kneading the resulting mixture. The resultant composition is moldable and has excellent impact resistance. Preferably to the composition (I) is added a poly­functional compound which reacts with (B) and (C) and causes cross-linking thereof in the kneading.

  一种聚酰胺树脂组合物是通过熔融捏合(A)20 至 60 份聚酰胺树脂和(B)40 至 80 份乙烯共聚物生产的，乙烯共聚物包括(a)40 至 90 wt%的乙烯单元，(b)5 至 60 wt%的 α，β-不饱和羧酸烷基酯单元和(c)0.3 至 10 wt%的马来酸酐单元，以形成部分交联的组合物 (I)，然后将 50 至 1,000 重量份的聚酰胺树脂加入 100 重量份的组合物 (I)中，并熔融捏合所得混合物。 这样得到的组合物具有良好的可模塑性和抗冲击性。 最好在组合物(I)中加入一种多官能化合物，它能与(B)和(C)发生反应，并在捏合过程中使其交联。
• Method for producing a thermoplastic resin composition
  申请人：SUMITOMO CHEMICAL COMPANY, LIMITED

  公开号：EP0285256A2

  公开（公告）日：1988-10-05

  Disclosed is a method for producing a thermoplastic resin composition which can be easily molded into articles having good balance in properties and good appearance. Said method comprises melt-kneading (A) 60-97 parts by weight of a saturated polyester resin and (B) 40-3 parts by weight of an epoxy group-containing ethylene copolymer and then melt-kneading the resulting composition with (C) 0.01-20 parts by weight of a poly­functional compound containing in one molecule at least two functional groups having reactivity with epoxy group, carboxyl group or hydroxyl group to carry out partial crosslinking reaction.

  本发明公开了一种热塑性树脂组合物的生产方法，该组合物可以很容易地模塑成具有良好性能平衡和外观的物品。该方法包括将(A)60-97 重量份的饱和聚酯树脂和(B)40-3 重量份的含环氧基的乙烯共聚物熔融捏合，然后将所得组合物与(C)0.01-20 重量份的在一个分子中至少含有两个与环氧基、羧基或羟基有反应活性的官能团的多官能化合物熔融捏合，以进行部分交联反应。
• Method for producing thermoplastic elastomer composition
  申请人：SUMITOMO CHEMICAL COMPANY, LIMITED

  公开号：EP0400890A2

  公开（公告）日：1990-12-05

  A thermoplastic elastomer composition which is excellent in balance of properties such as mechanical properties and thermal properties and in appearance is prepared by melt-kneading (A) 20-58 parts by weight of a saturated polyester resin and (B) 42-80 parts by weight of an epoxy group-containing ethylene copolymer and then melt-kneading 100 parts by weight of the resulting composition with (C) 0.01-20 parts by weight of a polyfunctional compound containing in one molecule at least two functional groups selected from an amino group, a carboxylic acid anhydride group, a hydroxyl group and group wherein both X and Y are oxygen atoms or sulfur aroms, or either X or Y is an oxygen atom and another is a sulfur atom, or (D) 0.01-9 parts by weight of a polyfunctional compound having in one molecule at least two carboxyl groups or both at least one carboxyl group and at least one functional group selected from an amino group, a carboxylic acid anhydride group, a hydroxyl group and the group wherein X and Y are defined above.

  一种热塑性弹性体组合物，其在机械性能和热性能等性能的平衡方面以及在外观方面都很出色，其制备方法是将(A)20-58 份(重量)饱和聚酯树脂和(B)42-80 份(重量)含环氧基的乙烯共聚物熔融捏合，然后将所得组合物的 100 份(重量)与(C)0.01-20 份(重量)的多官能团化合物，该化合物在一个分子中含有至少两个官能团，这两个官能团选自氨基、羧酸酐基、羟基和羧基。 其中 X 和 Y 均为氧原子或硫芳香基，或 X 或 Y 为氧原子，另一个为硫原子，或 (D) 0.01-9(重量份)的多官能团化合物，其一个分子中含有至少两个羧基或至少 一个羧基和至少一个选自氨基、羧酸酐基、羟基和硫芳香基的官能团，其中 X 和 Y 定义为氧原子或硫原子。 其中 X 和 Y 定义如上。