bis-ammine phthalocyaninatoruthenium(II) | 150814-60-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 四吡咯及其衍生物
• 英文名称: bis-ammine phthalocyaninatoruthenium(II)
• 英文别名: diammineruthenium phthalocyanine；Azane;2,11,20,29,37,39-hexaza-38,40-diazanidanonacyclo[28.6.1.13,10.112,19.121,28.04,9.013,18.022,27.031,36]tetraconta-1,3,5,7,9,11,13,15,17,19(39),20,22,24,26,28,30(37),31,33,35-nonadecaene;ruthenium(2+)
• CAS: 150814-60-1
• 化学式: C₃₂H₂₂N₁₀Ru
• 分子量: 647.664
• InChiKey: VXGPZJCACPWJPV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.45
• 重原子数：
  43
• 可旋转键数：
  0
• 环数：
  9.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  78.2
• 氢给体数：
  2
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  bis-ammine phthalocyaninatoruthenium(II) 、 苯甲腈 以 氯仿 、 苯甲腈 为溶剂， 以60%的产率得到Ru(PhCN)₂Pc
  参考文献：
  名称：

  Self-Assembled Mono- and Multilayers on Gold from 1,4-Diisocyanobenzene and Ruthenium Phthalocyanine

  摘要：

  Self-assembled monolayers of 1,4-diisocyanobenzene on gold were used to bind ruthenium phthalocyanines to the surface by axial ligation of the macrocycle with isocyanide groups pointing out from the SAM. The 1,4-diisocyanobenzene SAM and the RuPc-1,4-diisocyanobenzene bilayer were characterized by ellipsometry, IRRAS, XPS, and SPM. The grafting of RuPc to the SAM is stable. The thickness of the film increases from 10 to 15 Angstrom upon RuPc ligation. IRRAS reveals that both ends of the 1,4-diisocyanobenzene are affected by the N=C to metal interaction occurring at the other end. XPS indicates that each RuPc macrocycle covers similar to 12 1,4-diisocyanobenzene molecules in the bilayer.

  DOI：

  10.1021/jp992438v
• 作为产物：
  描述：

  水合三氯化钌 、 1,2-二氰基苯 在 戊醇 、 氨 、 对苯二酚 作用下， 以 戊醇 为溶剂， 生成 bis-ammine phthalocyaninatoruthenium(II)
  参考文献：
  名称：

  Bossard, Gerald E.; Abrams, Michael J.; Darkes, Marilyn C., Inorganic Chemistry, 1995, vol. 34, # 6, p. 1524 - 1527

  摘要：

  DOI：

文献信息

• Self-Assembled Mono- and Multilayers on Gold from 1,4-Diisocyanobenzene and Ruthenium Phthalocyanine
  作者：Vincent Huc、Jean-Philippe Bourgoin、Christophe Bureau、Françoise Valin、Gilbert Zalczer、Serge Palacin

  DOI：10.1021/jp992438v

  日期：1999.11.1

  Self-assembled monolayers of 1,4-diisocyanobenzene on gold were used to bind ruthenium phthalocyanines to the surface by axial ligation of the macrocycle with isocyanide groups pointing out from the SAM. The 1,4-diisocyanobenzene SAM and the RuPc-1,4-diisocyanobenzene bilayer were characterized by ellipsometry, IRRAS, XPS, and SPM. The grafting of RuPc to the SAM is stable. The thickness of the film increases from 10 to 15 Angstrom upon RuPc ligation. IRRAS reveals that both ends of the 1,4-diisocyanobenzene are affected by the N=C to metal interaction occurring at the other end. XPS indicates that each RuPc macrocycle covers similar to 12 1,4-diisocyanobenzene molecules in the bilayer.
• Bossard, Gerald E.; Abrams, Michael J.; Darkes, Marilyn C., Inorganic Chemistry, 1995, vol. 34, # 6, p. 1524 - 1527
  作者：Bossard, Gerald E.、Abrams, Michael J.、Darkes, Marilyn C.、Vollano, Jean F.、Brooks, Robert C.

  DOI：——

  日期：——