1-(4-hydroxy-2-naphthyl)-2,2-diisopropyl-1-methoxyethylene | 232938-37-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 1-(4-hydroxy-2-naphthyl)-2,2-diisopropyl-1-methoxyethylene
• CAS: 232938-37-3
• 化学式: C₁₉H₂₄O₂
• 分子量: 284.398
• InChiKey: KDRNBELLZGRLRN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.21
• 重原子数：
  21.0
• 可旋转键数：
  4.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.37
• 拓扑面积：
  29.46
• 氢给体数：
  1.0
• 氢受体数：
  2.0

反应信息

• 作为反应物：
  描述：

  1-(4-hydroxy-2-naphthyl)-2,2-diisopropyl-1-methoxyethylene 在 咪唑 、 氧气 、 tetraphenylporphyrin 作用下， 以 二氯甲烷 、 N,N-二甲基甲酰胺 为溶剂， 生成 3-[4-(tert-butyldimethylsiloxy)-2-naphthyl]-4,4-diisopropyl-3-methoxy-1,2-dioxetane
  参考文献：
  名称：

  Synthesis of 3,3-diisopropyl-4-methoxy-4-(siloxy-2-naphthyl)-1,2-dioxetanes and their F−-induced chemiluminescent decomposition

  摘要：

  Six isomeric 3,3-diisopropyl-4-methoxy-4-(siloxy-2-napthyl)-1,2-dioxetanes (3) were synthesized and their F--induced chemiluminescencent decomposition were examined in DMSO. The 'odd/even' relationship in (CL)-C-Phi holds for all the dioxetanes (3). On the other band, the 'odd/even' relationship in emission half-lives t(1/2) is observed for dioxetanes (3e-3f) with a trigger on the ring B but not for dioxetanes (3a and 3b) with a trigger on the ring A. (C) 1999 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4020(99)00336-1
• 作为产物：
  描述：

  4-甲氧基萘-2-羧酸甲酯 在 lithium aluminium tetrahydride 、 titanium(III) chloride 、 sodium hydride 、 三乙胺 、 乙硫醇 作用下， 以 四氢呋喃 、 N,N-二甲基甲酰胺 为溶剂， 反应 4.0h， 生成 1-(4-hydroxy-2-naphthyl)-2,2-diisopropyl-1-methoxyethylene
  参考文献：
  名称：

  Synthesis of 3,3-diisopropyl-4-methoxy-4-(siloxy-2-naphthyl)-1,2-dioxetanes and their F−-induced chemiluminescent decomposition

  摘要：

  Six isomeric 3,3-diisopropyl-4-methoxy-4-(siloxy-2-napthyl)-1,2-dioxetanes (3) were synthesized and their F--induced chemiluminescencent decomposition were examined in DMSO. The 'odd/even' relationship in (CL)-C-Phi holds for all the dioxetanes (3). On the other band, the 'odd/even' relationship in emission half-lives t(1/2) is observed for dioxetanes (3e-3f) with a trigger on the ring B but not for dioxetanes (3a and 3b) with a trigger on the ring A. (C) 1999 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4020(99)00336-1

文献信息

• Synthesis of 3,3-diisopropyl-4-methoxy-4-(siloxy-2-naphthyl)-1,2-dioxetanes and their F−-induced chemiluminescent decomposition
  作者：Nobuko Watanabe、Hisako Kobayashi、Mitsunori Azami、Masakatsu Matsumoto

  DOI：10.1016/s0040-4020(99)00336-1

  日期：1999.5

  Six isomeric 3,3-diisopropyl-4-methoxy-4-(siloxy-2-napthyl)-1,2-dioxetanes (3) were synthesized and their F--induced chemiluminescencent decomposition were examined in DMSO. The 'odd/even' relationship in (CL)-C-Phi holds for all the dioxetanes (3). On the other band, the 'odd/even' relationship in emission half-lives t(1/2) is observed for dioxetanes (3e-3f) with a trigger on the ring B but not for dioxetanes (3a and 3b) with a trigger on the ring A. (C) 1999 Elsevier Science Ltd. All rights reserved.