N-ethyl-N,N'-diphenyl-acetamidine | 65957-23-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N-ethyl-N,N'-diphenyl-acetamidine
• 英文别名: N-Aethyl-N,N'-diphenyl-acetamidin；N1-ethyl-N1,N2-diphenyl-acetamidine；N-ethyl-N,N'-diphenylethanimidamide
• CAS: 65957-23-5
• 化学式: C₁₆H₁₈N₂
• 分子量: 238.332
• InChiKey: SHBBQRRJLKRDAL-UHFFFAOYSA-N

物化性质

• 熔点：
  41-42 °C
• 沸点：
  349.3±25.0 °C(Predicted)
• 密度：
  0.96±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.5
• 重原子数：
  18
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.19
• 拓扑面积：
  15.6
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  N-ethyl-N,N'-diphenyl-acetamidine 、 碘甲烷 生成 N-Methyl-N-aethyl-N.N'-diphenyl-acetamidiniumjodid
  参考文献：
  名称：

  学术牙医对英国学术牙科职业的看法。

  摘要：

  DOI：

  10.1038/sj.bdj.4800418a
• 作为产物：
  描述：

  N,N'-Diphenyl-N-methyl-N'-ethyl-1,1-diaminoethylen 在 二乙胺 作用下， 生成 N-ethyl-N,N'-diphenyl-acetamidine
  参考文献：
  名称：

  Synthesis of N,N,N',N'-tetrasubstituted 1,1-diaminoethylenes and their thermal rearrangement

  摘要：

  DOI：

  10.1021/jo00406a037

文献信息

• Access to Amidines and Arylbenzimidazoles: Zinc-Promoted Rearrangement of Oxime Acetates
  作者：Zhongzhi Zhu、Jinghe Cen、Xiaodong Tang、Jianxiao Li、Wanqing Wu、Huanfeng Jiang

  DOI：10.1002/adsc.201701490

  日期：2018.5.16

  zinc‐promoted rearrangement of oxime acetates with arylamines for the synthesis of amidines has been developed under mild conditions. This process involves N−O/C−C bond cleavages and C−C/C−N bond formations. Various oxime acetates and arylamines are suitable for this transformation. Furthermore, diverse arylbenzimidazoles could also be prepared through simple one‐pot procedure.

  在温和的条件下，已开发出一种有效且直接的锌促进肟肟与芳胺的锌促进重排以合成for的方法。此过程涉及N / O / C-C键断裂和C-C / C-N键形成。各种肟乙酸酯和芳胺适合于该转化。此外，还可以通过简单的一锅法制备各种芳基苯并咪唑。
• ‘Britain's Irish Question: Britain's European Question?’ British-Irish relations in the context of European Union and The Belfast Agreement
  作者：ELIZABETH MEEHAN

  DOI：10.1017/s0260210500000838

  日期：2000.1

  If students of world politics can be reasonably accused of ignoring the Troubles in Northern Ireland—in part because they seemed to have little to do with the larger East-West confrontation and partly because they were so obviously about something distinctly national in character—then by the same token specialists on Northern Ireland can justly be accused of a certain intellectual parochialism and of failing to situate the long war within a broader global perspective. The quite unexpected outbreak of peace however only emphasizes the need for a wider understanding of the rise and fall of the Northern Irish conflict. This article explores the relationship between the partial resolution of the Irish Question—as expressed in the Good Friday Agreement of 1998—and the changing character of the European landscape. Its central thesis is that while there were many reasons for the outbreak of peace in the 1990s, including war weariness, it is difficult to understand what happened without situating it in a larger European framework and the new definition of sovereignty to which the EU has given birth.

  如果可以合理地指责研究世界政治的学生忽视了北爱尔兰的动乱--部分原因是这些动乱似乎与更广泛的东西方对抗关系不大，部分原因是这些动乱显然是关于一些明显具有民族特色的事情--那么，同样地，研究北爱尔兰问题的专家也可以被合理地指责为某种知识上的狭隘主义，未能将这场长期战争置于更广泛的全球视角之中。然而，出乎意料的和平爆发只是强调了更广泛地理解北爱尔兰冲突兴衰的必要性。本文探讨了部分解决爱尔兰问题（1998 年《耶稣受难日协议》）与欧洲格局变化之间的关系。文章的中心论点是，虽然 20 世纪 90 年代爆发和平有许多原因，包括对战争的厌倦，但如果不将其置于更大的欧洲框架和欧盟对主权的新定义中，就很难理解所发生的一切。
• BDJ readership survey
  作者：J. Montgomery

  DOI：10.1038/sj.bdj.4800440a

  日期：2000.3.11

  Over the summer, BDJ readers were surveyed about the BDJ as part of a series of BDJ surveys conducted since 1992. As well as assessing general views about the BDJ, the survey also aimed to discover how successful the 1998 BDJ redesign had been in incorporating reader's views from earlier surveys. The findings from the 1999 survey showed that the BDJ and BDA News continue to be the most read dental

  整个夏天，作为自 1992 年以来进行的一系列 BDJ 调查的一部分，BDJ 读者接受了关于 BDJ 的调查。除了评估对 BDJ 的一般看法外，该调查还旨在发现 1998 年 BDJ 重新设计在纳入读者的早期调查的观点。1999 年的调查结果表明，BDJ 和 BDA 新闻仍然是阅读量最大的牙科出版物。读者在寻找工作和研究报告之前，会先于任何其他英国牙科期刊转向 BDJ。调查的完整结果报告如下。
• v.Braun; Jostes; Heymons, Chemische Berichte, 1927, vol. 60, p. 99
  作者：v.Braun、Jostes、Heymons

  DOI：——

  日期：——
• Synthesis of N,N,N',N'-tetrasubstituted 1,1-diaminoethylenes and their thermal rearrangement
  作者：Yoshiro Sato、Masami Kato、Toyohiko Aoyama、Michiharu Sugiura、Hideaki Shirai

  DOI：10.1021/jo00406a037

  日期：1978.6