N-butyl-N-phenethylaniline | 115419-50-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N-butyl-N-phenethylaniline
• 英文别名: N-butyl-N-(2-phenylethyl)aniline
• CAS: 115419-50-6
• 化学式: C₁₈H₂₃N
• 分子量: 253.387
• InChiKey: SSUNBVPEGZLKSE-UHFFFAOYSA-N

物化性质

• 沸点：
  377.9±21.0 °C(Predicted)
• 密度：
  0.996±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5.3
• 重原子数：
  19
• 可旋转键数：
  7
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  3.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  N-(1-benzotriazolylbutyl)aniline 在 T406石油添加剂 、 sodium tetrahydroborate 作用下， 以 四氢呋喃 为溶剂， 反应 27.0h， 生成 N-butyl-N-phenethylaniline
  参考文献：
  名称：

  Katritzky, Alan R.; Rachwal, Stanislaw; Wu, Jing, Canadian Journal of Chemistry, 1990, vol. 68, # 3, p. 456 - 463

  摘要：

  DOI：

文献信息

• Alkylation of amines using trivalent bismuth derivatives
  作者：Derek H.R. Barton、Nubar Ozbalik、Manian Ramesh

  DOI：10.1016/s0040-4039(00)82466-1

  日期：1988.1

  Mixed alkylaryl BiIII derivatives have been prepared by both anionic and free radical methods. The thermal stability of these compounds permits them to be used in the presence of cupric acetate for the alkylation of amines. Trialkylbismuth compounds can also be used in the same way.

  混合的烷基芳基Bi III衍生物已经通过阴离子和自由基方法制备。这些化合物的热稳定性使它们可以在乙酸铜的存在下用于胺的烷基化。三烷基铋化合物也可以相同的方式使用。
• La-Catalyzed Decarbonylation of Formamides and Its Applications
  作者：Shaocheng Li、Thayalan Rajeshkumar、Jincheng Liu、Laurent Maron、Xigeng Zhou

  DOI：10.1021/acs.orglett.2c03981

  日期：2023.1.13

  Herein we report the first catalytic decarbonylation and decarbonylative hydroamination of formamides without using additives enabled by a redox-neutral rare earth catalyst. The protocol displays complete N-aryl/alkenyl formamide-selectivity, thus providing a wide variety of creative uses of the N-formylation and N-deformylation method and opening up new prospects for minimizing waste and controlling

  在这里，我们报告了甲酰胺的首次催化脱羰和脱羰加氢胺化，而不使用由氧化还原中性稀土催化剂启用的添加剂。该协议显示了完整的N-芳基/烯基甲酰胺选择性，从而提供了N-甲酰化和N-脱甲酰化方法的广泛创造性用途，并为最大限度地减少浪费和控制胺转化事件中所需的选择性开辟了新的前景。
• GROUP-15 CATIONIC COMPOUNDS FOR OLEFIN POLYMERIZATION CATALYSTS
  申请人：——

  公开号：US20020111265A1

  公开（公告）日：2002-08-15

  This description addresses fluorinated amine compounds meeting the general formula R′ i ArF-ER 2 , where ArF is a fluoroaryl group, E is nitrogen or phosphorous, each R is independently a C 1 -C 20 hydrocarbyl group, or the two Rs may connect to form an unsubstituted or substituted C 2 -C 20 cycloaliphatic group, R′ is a C 1 -C 20 hydrocarbyl or halogenated hydrocarbyl, and i is 0, 1 or 2. These compounds may be protonated with strong Bronsted acids to form protonated amine compounds that are useful for the preparation of organometallic catalyst-cocatalyst compounds comprising noncoordinating or weakly coordinating anions. The resulting organometallic catalyst-cocatalyst complexes can be effectively used as olefin polymerization catalysts. High number-average molecular weight polymers at high rates of productivity were observed from the use of metallocene catalyst complexes prepared with [N-pentafluorophenyl pyrrolidinium][tetrakis(pentafluorophenyl)borate] of [N-pentafluorophenyl pyrrolidinium][chloride].

  本说明涉及符合通式 R′ 的氟化胺化合物 i ArF-ER 2 其中 ArF 是氟芳基，E 是氮或磷，每个 R 独立地是 C 1 -C 20 烃基，或两个 R 可连接形成未取代或取代的 C 2 -C 20 环脂族基团，R′是一个 C 1 -C 20 烃基或卤代烃基，i 为 0、1 或 2。这些化合物可以用强勃朗斯特酸质子化，形成质子化胺化合物，用于制备包含非配位或弱配位阴离子的有机金属催化剂-催化剂化合物。由此得到的有机金属催化剂-催化剂复合物可有效地用作烯烃聚合催化剂。使用 [N-pentafluorophenyl pyrrolidinium][tetrakis(pentafluorophenyl)borate] of [N-pentafluorophenyl pyrrolidinium][chloride] 制备的茂金属催化剂络合物，可以观察到生产率高的高平均分子量聚合物。
• Olefin polymerization catalysts derived from Group-15 cationic compounds and processes using them
  申请人：——

  公开号：US20020115806A1

  公开（公告）日：2002-08-22

  Fluorinated amine compounds, R′ i ArF-ER 2 , where ArF is a fluoroaryl substituent, E is nitrogen or phosphorous, each R is independently a C 1 -C 20 hydrocarbyl substituent, or the two R's may be connected to form an unsubstituted or substituted C 2 -C 20 cycloaliphatic substituent, R′ is a C 1 -C 20 hydrocarbyl or halogenated hydrocarbyl, and i is 0, 1 or 2 are disclosed. These compounds may be protonated and complexed with suitable substantially noncoordinating anions to prepare polymerization catalyst components. When these catalyst components are combined with organometallic catalyst precursors, the catalyst precursor is activated to a catalyst. This catalyst is combined with monomer under olefin polymerization conditions to prepare polymer. High number-average molecular weight polymers at high productivity rates were observed from using metallocene catalysts activated with [N-pentafluorophenyl pyrrolidinium][tetrakis(pentafluorophenyl)borate].

  氟化胺化合物，R′ i i ArF-ER 2 其中 ArF 是氟芳基取代基，E 是氮或磷，每个 R 独立地是 C 1 -C 20 烃基取代基，或者两个 R 可以连接形成未取代或取代的 C 2 -C 20 环脂族取代基，R′是 C 1 -C 20 烃基或卤代烃基，i 为 0、1 或 2。这些化合物可以质子化并与合适的基本上不配位的阴离子络合，制备聚合催化剂组分。当这些催化剂组分与有机金属催化剂前体结合时，催化剂前体被活化成催化剂。催化剂在烯烃聚合条件下与单体结合，制备聚合物。使用经 N-五氟苯基吡咯烷硼酸酯和四(五氟苯基)硼酸酯活化的茂金属催化剂，可以观察到生产率高、平均分子量高的聚合物。
• KATRITZKY, ALAN R.;, RACHWAL STANISLAW;WU, JING, CAN. J. CHEM., 68,(1990) N, C. 456-463
  作者：KATRITZKY, ALAN R.、, RACHWAL STANISLAW、WU, JING

  DOI：——

  日期：——