dichloroglyoxime | 17019-17-9

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 有机氯化物
• 英文名称: dichloroglyoxime
• 英文别名: anti-dichloroglyoxime；Dichloroglyoxime；(1Z,2Z)-N,N'-dihydroxyethanediimidoyl dichloride
• CAS: 17019-17-9
• 化学式: C₂H₂Cl₂N₂O₂
• 分子量: 156.956
• InChiKey: KTQVJAPIQPIIPF-IOBHVTPZSA-N

物化性质

• 沸点：
  334.6±25.0 °C(Predicted)
• 密度：
  1.80±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.2
• 重原子数：
  8
• 可旋转键数：
  1
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  65.2
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  dichloroglyoxime 生成 cyanogen di-N-oxide
  参考文献：
  名称：

  Maier, Guenther; Teles, Joaquim Henrique, Angewandte Chemie, 1987, vol. 99, # 2, p. 152 - 153

  摘要：

  DOI：
• 作为产物：
  描述：

  1,2-乙二酮二肟 在 氯 作用下， 生成 dichloroglyoxime
  参考文献：
  名称：

  Pigenet,C. et al., Bulletin de la Societe Chimique de France, 1970, p. 2124 - 2132

  摘要：

  DOI：

文献信息

• Synthesis and Extraction Properties of 1,2-Bis(amidoxime) Derivatives
  作者：Ramazan Gup、H. Korkmaz Alpoguz、A. Dincer Beduk

  DOI：10.1135/cccc20020209

  日期：——

  Four 1,2-bis(amidoxime)s bearing benzoate groups were synthesized. Their complexing properties were studied by the liquid-liquid extraction of selected alkali (Na⁺ and K⁺) and transition metals (Hg²⁺, Cu²⁺, Pb²⁺ and Ni²⁺). It has been observed that all ligands show a high affinity to Cu²⁺ and Hg²⁺ ions, whereas almost no affinity to alkali metals.

  合成了四种带苯甲酸基的1,2-双(酰肟)类化合物。通过对所选碱金属（Na+和K+）和过渡金属（Hg2+、Cu2+、Pb2+和Ni2+）的液液萃取研究了它们的络合性能。结果表明，所有配体均对Cu2+和Hg2+离子显示出高亲和力，而对碱金属几乎没有亲和力。
• Synthesis of diferrocenylglyoxime and some of its transition metal complexes
  作者：Mümtaz Ertas、Ali R. Koray、Vefa Ahsen、Özer Bekâroğlu

  DOI：10.1016/0022-328x(86)80541-1

  日期：1986.12

  Diferrocenylglyoxime has been prepared by the reaction of monolithioferrocene or dilithioferrocene with anti-dichloroglyoxime. Characterization of this novel vic-dioxime and some of its transition metal complexes are described.

  二茂铁乙二醛肟已通过单硫代二茂铁或二硫代二茂铁与抗二氯乙二肟的反应制备。描述了这种新颖的vic- dioxime及其一些过渡金属配合物的表征。
• Gas sensing with hexafluoroisopropanol substituted phthalocyanines andvic-dioximes: a comparative study
  作者：Mika HARBECK、Zafer ŞEN、Dilek ERBAHAR、Gülay GÜMÜŞ、Emel MUSLUOĞLU

  DOI：10.3906/kim-1811-27

  日期：——

  Phthalocyanines (Pcs) are established sensitive materials for chemical gas sensors due to their superb sensing characteristics and the achievable manifold in their analyte interaction properties. Their sorption properties are determined by the metal ion center and substituents attached to the periphery of the ring system. Similarly, vic-dioximes can be modified in their sorption properties and employed as sensitive materials. In this work, a nickel Pc and various vic-dioximes functionalized with the same hexafluoroisopropanol moiety are assessed and compared in their gas-sensing properties using the quartz crystal microbalance for the first time. This specific substituent is selected for its hydrogen bond acidity for strong interactions with analytes having corresponding sites. The synthesis and characterization of the new compounds are described. Sensor results are presented for ten selected organic compounds and the chemical warfare agent simulant dimethyl methylphosphonate (DMMP). Both compound classes exhibit good sensing performance but were found to exhibit very diverging analyte preferences, as preferential sorption of either amines or polar compounds was observed depending on the molecule type. Thus, by applying the same substituent to different base molecules, sensitive compounds with very distinct sensing properties can be realized.

  酞菁 (Pcs) 因其卓越的传感特性和可实现的多种分析物相互作用特性而成为化学气体传感器的敏感材料。它们的吸附特性由金属离子中心和连接到环系统外围的取代基决定。类似地，vic-二肟可以改变其吸附特性并用作敏感材料。在这项工作中，首次使用石英晶体微天平评估和比较了镍PC和用相同的六氟异丙醇部分功能化的各种vic-二肟的气敏特性。该特定取代基因其氢键酸性而被选择，以与具有相应位点的分析物发生强相互作用。描述了新化合物的合成和表征。显示了十种选定的有机化合物和化学战剂模拟物甲基膦酸二甲酯 (DMMP) 的传感器结果。这两类化合物均表现出良好的传感性能，但发现其分析物偏好存在很大差异，因为根据分子类型观察到胺或极性化合物的优先吸附。因此，通过将相同的取代基应用于不同的基础分子，可以实现具有非常不同的传感特性的敏感化合物。
• Channel architecture via self assembly of oxamideoximes complexes
  作者：Fatma Yuksel、Gülay Gümüş、İlke Gürol、Vefa Ahsen、Yurii Chumakov、Erwann Jeanneau、Dominique Luneau

  DOI：10.1039/b707930c

  日期：——

  The nickel(II) and palladium(II) complexes of oxamide oximes substituted with alkyl chains of different length (C4-C8) were synthesized from the reaction of dichloroglyoxime with the corresponding amine derivatives. All compounds have been characterized by X-ray diffraction on single crystals and were found to be centrosymmetric at the metal center which is bound by the four oximic nitrogen atoms of

  由二氯乙二肟与相应的胺衍生物反应合成了被不同长度的烷基链（C4-C8）取代的乙酰胺肟的镍（II）和钯（II）配合物。所有化合物均已通过单晶的X射线衍射进行了表征，并发现在正方形平面环境中，金属中心是中心对称的，该中心被两个配体的四个氧肟基氮原子结合。Ni（II）和Pd（II）配合物的晶体结构分析表明，所有Pd（II）配合物，但只有己基取代的乙酰胺肟Ni（II）配合物形成了无限的管状通道。
• Synthesis and Complexation of a Novel Soluble vic -Dioxime Ligand
  作者：Süleyman Gürsoy、Ali Cihan、Makbule B. Koçak、Özer Bekaroğlu

  DOI：10.1007/s007060170059

  日期：2001.8

  4-(isobutyl)-2,3- bis -(hydroxyimino)-5,6-phenylpiperazine was prepared as a mixture of isomers from anti -dichloroglyoxime and N,N′- bis -(isobutyl)-stilbendiamine which reacts to N,N′-coordinated planar metal complexes with Ni(II), Cu(II), Co(II), and Pd(II). Oxidation of the Co(II) complex in the presence of pyridine leads to an octahedral complex containing pyridine and chloride as axial ligands

   一种新的可溶性 VIC -dioxime 1,4-（异丁基）-2,3- 二 - （羟基亚氨基）-5,6-苯基哌嗪制备从异构体的混合物 的抗 -dichloroglyoxime和N，N'- 双 - （异丁基）-乙二胺与N，N'配位的平面金属络合物与Ni（II），Cu（II），Co（II）和Pd（II）反应。在吡啶存在下，Co（II）配合物的氧化会导致八面体配合物，除了 vic- dioxime配体之外，还包含吡啶和氯化物作为轴向配 体。铀酰复合物具有1：1的金属：配体比率和具有μ-羟基桥的双核结构。