1,2-bis(dimethyl(phenyl)silyl)-1,2-diphenylhydrazine | 5994-97-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1,2-bis(dimethyl(phenyl)silyl)-1,2-diphenylhydrazine
• 英文别名: N,N'-Bis-dimethylphenylsilyl-N,N'-diphenyl-hydrazin；1,2-Bis(dimethylphenylsilyl)-1,2-diphenylhydrazine；1,2-bis[dimethyl(phenyl)silyl]-1,2-diphenylhydrazine
• CAS: 5994-97-8
• 化学式: C₂₈H₃₂N₂Si₂
• 分子量: 452.746
• InChiKey: NKTJMLQNIDGICA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.14
• 重原子数：
  32
• 可旋转键数：
  7
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  6.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  偶氮苯 在 lithium dicyclohexylamide 作用下， 以 四氢呋喃 为溶剂， 生成 1,2-bis(dimethyl(phenyl)silyl)-1,2-diphenylhydrazine
  参考文献：
  名称：

  Interaction of Azobenzene and Benzalaniline with Strong Amido Bases

  摘要：

  The interaction of azobenzene with lithium dicyclohexylamide (Cy2NLi) in THF or Et2O afforded the ion-radical salt of azobenzene (1) structurally characterized for the first time and dicyclohexylaminyl radical, which begins a novel chain of transformations leading eventually to the imino-enamido lithium complex (3). Benzalaniline, being a relative of azobenzene, reacted with Cy2NLi without electron transfer by a proton-abstraction mechanism to form the dilithium salt of N-1,N-2,1,2-tetraphenylethene-1,2-diamine quantitatively.

  DOI：

  10.1021/acs.orglett.5b02860

文献信息

• Interaction of Azobenzene and Benzalaniline with Strong Amido Bases
  作者：Alexander N. Kornev、Vyacheslav V. Sushev、Natalia V. Zolotareva、Evgenii V. Baranov、Georgy K. Fukin、Gleb A. Abakumov

  DOI：10.1021/acs.orglett.5b02860

  日期：2015.12.18

  The interaction of azobenzene with lithium dicyclohexylamide (Cy2NLi) in THF or Et2O afforded the ion-radical salt of azobenzene (1) structurally characterized for the first time and dicyclohexylaminyl radical, which begins a novel chain of transformations leading eventually to the imino-enamido lithium complex (3). Benzalaniline, being a relative of azobenzene, reacted with Cy2NLi without electron transfer by a proton-abstraction mechanism to form the dilithium salt of N-1,N-2,1,2-tetraphenylethene-1,2-diamine quantitatively.