1,3-bis(3,3'-dimethyldiphenylamino)benzene | 124591-08-8

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 1,3-bis(3,3'-dimethyldiphenylamino)benzene
• 英文别名: tetrakis-(3-methylphenyl)-N,N,N',N'-2,5-phenylenediamine；1,3-Benzenediamine, N,N,N',N'-tetrakis(3-methylphenyl)-；1-N,1-N,3-N,3-N-tetrakis(3-methylphenyl)benzene-1,3-diamine
• CAS: 124591-08-8
• 化学式: C₃₄H₃₂N₂
• 分子量: 468.641
• InChiKey: SBFJWYYUVYESMJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  9.9
• 重原子数：
  36
• 可旋转键数：
  6
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.12
• 拓扑面积：
  6.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  间碘甲苯 、 间苯二胺 在 铜 potassium carbonate 作用下， 以 硝基苯 为溶剂， 反应 8.0h， 以37.1%的产率得到1,3-bis(3,3'-dimethyldiphenylamino)benzene
  参考文献：
  名称：

  Getautis; Stanisauskaite; Paliulis, Journal fur Praktische Chemie (Weinheim), 2000, vol. 342, # 1, p. 58 - 62

  摘要：

  DOI：

文献信息

• HETEROCYCLIC COMPOUND AND ORGANIC LIGHT-EMITTING DEVICE
  申请人：Ohrui Hiroki

  公开号：US20080138656A1

  公开（公告）日：2008-06-12

  Provided is a novel heterocyclic compound which is useful as a material for an organic electroluminescent device. The heterocyclic compound is represented by the general formula [I]: wherein X represents a nitrogen atom or a carbon atom; Y represents O or S; R 1 and R 2 each represent, independently of one another, a group selected from the group consisting of a substituted or unsubstituted alkyl group and the like; a represents 0 or more and 3 or less; b represents 0 or more and 3 or less; and Ar 1 represents a substituted or unsubstituted heterocyclic ring or the like; and n represents an integer of 2 to 10.

  提供了一种新颖的杂环化合物，可用作有机电致发光器件的材料。这种杂环化合物由通用公式[I]表示：其中X代表氮原子或碳原子；Y代表O或S；R1和R2分别独立地代表从取代或未取代的烷基等组成的组；a表示0或更多，但不超过3；b表示0或更多，但不超过3；Ar1代表取代或未取代的杂环环或类似物；n表示2到10之间的整数。
• Red organic ligh-emitting compound and organic light-emitting device comprising the same
  申请人：Hwang Ha-Geun

  公开号：US20060022584A1

  公开（公告）日：2006-02-02

  A red organic light-emitting compound which has a superior heat-resistance and is capable of adjusting the color of the emitted light, and an organic light-emitting device including the same are disclosed. The organic light-emitting compound has the structure of the following chemical formula, and the organic light-emitting device includes the first electrode having a high work function; the second electrode having a low work function; and at least one organic layer formed between the first electrode and the second electrode, which includes the red organic light-emitting compound, wherein, X is C, O, S, SO 2 or N; Y is S or —CR 11 ═CR 12 —; R 1 , R 2 , R 3 , R 11 and R 12 can be the same or different, and are hydrogen, alkyl group of 1 to 20 carbon atoms, alkoxy group of 1 to 5 carbon atoms, aryl or heteroaryl group of 4 to 24 carbon atoms, heterocyclic group of 4 to 6 carbon atoms, or fused ring group of 4 to 24 carbon atoms; R 4 and R 5 can be the same or different, and are the functional group defined for R 1 or O; when R 4 and R 5 are O. R 4 and R 5 can be connected to form a heterocyclic ring; is the functional group defined for R 1 or amine group; and n is 1, 2 or 3.

  揭示了一种具有优越耐热性并能够调节发射光的颜色的红色有机发光化合物，以及包括该化合物的有机发光器件。该有机发光化合物具有以下化学式的结构，有机发光器件包括具有高功函数的第一电极；具有低功函数的第二电极；以及形成在第一电极和第二电极之间的至少一个有机层，其中包括红色有机发光化合物，其中，X为C、O、S、SO2或N；Y为S或—CR11═CR12—；R1、R2、R3、R11和R12可以相同也可以不同，为氢、1至20个碳原子的烷基、1至5个碳原子的烷氧基、4至24个碳原子的芳基或杂芳基、4至6个碳原子的杂环基，或4至24个碳原子的融合环基；R4和R5可以相同也可以不同，为R1或O定义的官能团；当R4和R5为O时，R4和R5可以连接形成杂环；为R1或胺基定义的官能团；n为1、2或3。
• Nitrogen-containing heterocyclic compound
  申请人：——

  公开号：US20030057826A1

  公开（公告）日：2003-03-27

  A nitrogen-containing heterocyclic compound represented by the following formula (I): 1 wherein X 1 and X 2 each represent an electron attractive group such as a cyano group; and the rings Z 1 and Z 2 each represent a hydrocarbon ring or a heterocycle (e.g., benzene ring having an electron donative group such as hydroxyl group, an alkoxy group, amino group and an N-substituted amino group, or a condensed ring being a benzene ring condensed with a heterocycle having a nitrogen atom as a hetero atom) is provided. An organic EL device is obtained by allowing an organic layer containing the compound described-above to be interposed between a pair of electrodes. The present invention provides a nitrogen-containing heterocyclic compound useful as a functional material and a process for producing the same, and an organic EL device using the same.

  提供一种含氮杂环化合物，其化学式如下（I）：其中X1和X2各代表一个电子吸引基团，如氰基；环Z1和Z2各代表一个碳氢环或杂环（例如，苯环具有一个电子给体基团，如羟基、烷氧基、氨基和N-取代氨基，或者是一个与氮原子作为杂原子的杂环缩合环的苯环）。通过在一对电极之间插入含有上述化合物的有机层，可以获得有机EL器件。本发明提供了一种作为功能材料有用的含氮杂环化合物，以及制备该化合物的方法和使用该化合物的有机EL器件。
• Azepine compounds
  申请人：——

  公开号：US20020091256A1

  公开（公告）日：2002-07-11

  The azepine compound capable of emitting a light by light-irradiation or action of an electric field is represented by the following formula (I) or (II): 1 wherein X 1 and X 2 are the same or different, each representing an electron attractive group; R 1 represents a hydrogen atom, an alkyl group, an aryl group, an aralkyl group, or an alkoxy group; R 2 represents an amino group or an N-substituted amino group, or, in the formula (I), R 2 bonds a carbon atom adjacent to a ring Z to form a ring; and the ring Z represents a hydrocarbon ring which may have a substituent or a heterocycle which may have a substituent. The compound is useful as a functional material, thus, an organic electroluminescence device can be obtained by interposing an organic layer composed of the above compound between a pair of electrodes.

  具有通过光照射或电场作用而发出光的氮杂环化合物的化学式如下（I）或（II）：1其中，X1和X2相同或不同，分别表示电子吸引基团；R1表示氢原子、烷基、芳基、芳基烷基或烷氧基；R2表示氨基或N-取代氨基，或在式（I）中，R2与环Z相邻的碳原子连接以形成环；环Z表示可能具有取代基的碳氢环或可能具有取代基的杂环。该化合物可用作功能材料，因此，在一对电极之间插入由上述化合物组成的有机层可获得有机电致发光器件。
• PYRENE COMPOUND AND ORGANIC LIGHT EMITTING DEVICE
  申请人：Suzuki Koichi

  公开号：US20080119671A1

  公开（公告）日：2008-05-22

  An object of the present invention is to provide a novel pyrene compound. Provided is a pyrene compound represented by the following general formula (I): wherein: R 1 and R 2 each represent a substituted or unsubstituted alkyl group; and Ar 1 , Ar 2 , Ar 3 , and Ar 4 each represent a substituted or unsubstituted aryl group and the like.

  本发明的目的是提供一种新型的芘化合物。提供的是一种由以下通式（I）表示的芘化合物： 其中：R1和R2各代表取代或未取代的烷基；Ar1、Ar2、Ar3和Ar4各代表取代或未取代的芳基等。