1,4-dimethyl-2-cyclopentylbenzene | 62379-92-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1,4-dimethyl-2-cyclopentylbenzene
• 英文别名: 1-cyclopentyl-2,5-dimethylbenzene；2-cyclopentyl-1,4-dimethylbenzene；2-cyclopentyl-1,4-dimethyl-benzene；2-Cyclopentyl-1,4-dimethyl-benzol；1,4-Dimethyl-2-cyclopentyl-benzol；1-Cyclopentyl-2,5-dimethyl-benzol
• CAS: 62379-92-4
• 化学式: C₁₃H₁₈
• 分子量: 174.286
• InChiKey: YSVADLJGCIUWQF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.6
• 重原子数：
  13
• 可旋转键数：
  1
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.54
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  alkaline earth salt of/the/ methylsulfuric acid 在 溶剂黄146 、 锌 作用下， 生成 1,4-dimethyl-2-cyclopentylbenzene
  参考文献：
  名称：

  v. Braun; Kuehn, Chemische Berichte, 1927, vol. 60, p. 2566

  摘要：

  DOI：

文献信息

• Novel reductive Friedel-Crafts alkylation of aromatics catalyzed by indium compounds: Chemoselective utilization of carbonyl moieties as alkylating reagents
  作者：Takashi Miyai、Yoshiyuki Onishi、Akio Baba

  DOI：10.1016/s0040-4020(98)01130-2

  日期：1999.1

  Reductive Friedel-Crafts alkylation of aromatics with ketones or aldehydes was characteristically catalyzed by indium compounds in preference to general catalysts like AlCl3 and BF3, where hydrosilanes would play an important role both as a hydride donor and as a co-catalyst. Chemoselective utilization of ketone moieties as alkylating reagents took place even in the presence of halogen, ester or ether

  铟化合物优先于一般催化剂（如AlCl 3和BF 3），其特征在于铟化合物可催化芳香族化合物与酮或醛的还原Friedel-Crafts烷基化反应，其中氢硅烷既可作为氢化物供体，又可作为助催化剂。甚至在卤素，酯或醚部分的存在下，酮部分作为烷基化试剂的化学选择性利用也发生了，在传统的弗瑞德-克拉夫茨条件下，卤素，酯或醚部分非常容易受到影响。通过一些受控实验对合理的中间体进行了讨论。
• Iron-Catalyzed Arene Alkylation Reactions with Unactivated Secondary Alcohols
  作者：Latisha R. Jefferies、Silas P. Cook

  DOI：10.1021/ol500606d

  日期：2014.4.4

  A simple, iron-based catalytic system allows for the inter- and intramolecular arylation of unactivated secondary alcohols. This transformation expands the substrate scope beyond the previously required activated alcohols and proceeds under mild reaction conditions, tolerating air and moisture. Furthermore, the use of an enantioenriched secondary alcohol provides an enantioenriched product for the intramolecular reaction, thereby offering a convenient approach to nonracemic products.
• Pajeau,R.; Begue,J.-P., Bulletin de la Societe Chimique de France, 1962, p. 1923 - 1927
  作者：Pajeau,R.、Begue,J.-P.

  DOI：——

  日期：——
• Partitioning the Nutrient and Nonnutrient Contributions Of Compost to Dryland-Organic Wheat
  作者：Paul D. Stukenholtz、Richard T. Koenig、David J. Hole、Bruce E. Miller

  DOI：10.1080/1065657x.2002.10702085

  日期：2002.6
• Pokrovskaya, 1950, vol. 1, # 2, p. 264
  作者：Pokrovskaya

  DOI：——

  日期：——