4-(2-methoxyphenyl)-1,2,3,3a,4,8b-hexahydrocyclopenta[b]indole | 1378027-21-4

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 4-(2-methoxyphenyl)-1,2,3,3a,4,8b-hexahydrocyclopenta[b]indole
• CAS: 1378027-21-4
• 化学式: C₁₈H₁₉NO
• 分子量: 265.355
• InChiKey: BGFVLIBHRBBVMQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.48
• 重原子数：
  20.0
• 可旋转键数：
  2.0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  12.47
• 氢给体数：
  0.0
• 氢受体数：
  2.0

反应信息

• 作为反应物：
  描述：

  4-(2-methoxyphenyl)-1,2,3,3a,4,8b-hexahydrocyclopenta[b]indole 在 哌啶 、 三氯氧磷 作用下， 以 正丁醇 为溶剂， 反应 4.0h， 生成
  参考文献：
  名称：

  N-(2-Alkoxyphenyl)-substituted double rhodanine indoline dyes for zinc oxide dye-sensitized solar cell

  摘要：

  The effect of N-(2-alkoxyphenyl) group in double rhodanine indoline dye on the performance of zinc oxide dye-sensitized solar cell was examined. Both J(sc) and V-oc were improved by introducing long alkoxy group due to prevention of H-aggregates formation and inhibition of electron recombination from zinc oxide surface to electrolyte. (C) 2012 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2012.03.060
• 作为产物：
  描述：

  1,2,3,3a,4,8b-六氢环戊二烯并[b]吲哚 、 2-溴苯甲醚 在 2-双环己基膦-2',6'-二甲氧基联苯 、 palladium diacetate 、 sodium t-butanolate 作用下， 以 甲苯 为溶剂， 以68%的产率得到4-(2-methoxyphenyl)-1,2,3,3a,4,8b-hexahydrocyclopenta[b]indole
  参考文献：
  名称：

  N-(2-Alkoxyphenyl)-substituted double rhodanine indoline dyes for zinc oxide dye-sensitized solar cell

  摘要：

  The effect of N-(2-alkoxyphenyl) group in double rhodanine indoline dye on the performance of zinc oxide dye-sensitized solar cell was examined. Both J(sc) and V-oc were improved by introducing long alkoxy group due to prevention of H-aggregates formation and inhibition of electron recombination from zinc oxide surface to electrolyte. (C) 2012 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2012.03.060

文献信息

• N-(2-Alkoxyphenyl)-substituted double rhodanine indoline dyes for zinc oxide dye-sensitized solar cell
  作者：Masaki Matsui、Takahiro Shiota、Yasuhiro Kubota、Kazumasa Funabiki、Jiye Jin、Tsukasa Yoshida、Shinji Higashijima、Hidetoshi Miura

  DOI：10.1016/j.tet.2012.03.060

  日期：2012.6

  The effect of N-(2-alkoxyphenyl) group in double rhodanine indoline dye on the performance of zinc oxide dye-sensitized solar cell was examined. Both J(sc) and V-oc were improved by introducing long alkoxy group due to prevention of H-aggregates formation and inhibition of electron recombination from zinc oxide surface to electrolyte. (C) 2012 Elsevier Ltd. All rights reserved.