phenylphosphonothioic diamide | 3969-46-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: phenylphosphonothioic diamide
• 英文别名: phenyl-thiophosphonic acid diamide；Phenyl-thiophosphonsaeure-diamid；Phenyl-thiophosphonsaeurediamid；Phenylthiophosphonsaeure-diamid；p-Phenylphosphonothioic diamide；diaminophosphinothioylbenzene
• CAS: 3969-46-8
• 化学式: C₆H₉N₂PS
• 分子量: 172.191
• InChiKey: SSLGNAGLEPLLMO-UHFFFAOYSA-N

物化性质

• 熔点：
  41 °C
• 沸点：
  321.3±25.0 °C(Predicted)
• 密度：
  1.30±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.2
• 重原子数：
  10
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  84.1
• 氢给体数：
  2
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  phenylphosphonothioic diamide 反应 6.0h， 以72%的产率得到2,4,6-trithio-2,4,6-triphenylcyclotriphosphazane
  参考文献：
  名称：

  Argent, Peter J.; Healy, James D.; Ibrahim, Ezzeldine H., Phosphorus and Sulfur and the Related Elements, 1981, vol. 12, p. 95 - 102

  摘要：

  DOI：
• 作为产物：
  描述：

  苯基硫代膦酰二氯 在 氨 作用下， 以74%的产率得到phenylphosphonothioic diamide
  参考文献：
  名称：

  磷氮化合物。第51部分。苯基硫代硫代二（单烷基酰胺）的碳13和磷31核磁共振特性。13 C核磁共振波谱法测定芳族取代基常数

  摘要：

  已获得一系列苯基膦硫基二（单烷基酰胺），PhP（S）（NHR）2（R = H，Me，Et，Pr n，Pr i，Pr i，环丙基，Bu的碳13和磷31 nmr光谱n，Bu i，Bu s，Bu t，新戊基，环戊基，环己基或CH 2 Ph）。电感和共振取代基系数被采用双取代参数法从相对shieldings评估元-和对位-苯环中的碳原子核。还尝试将来自不同nmr测量值的数据与化学行为相关联，并探索上述一组化合物的碳13和磷31 nmr化学位移数据之间的关系。

  DOI：

  10.1039/dt9870002479

文献信息

• Nitrogen Compounds of the Phosphoric and Phosphonic Acids. III. Preparation and Properties of Amides of Phenylphosphonic and Phenylphosphonothioic Acids¹
  作者：WILLIAM C. SMITH、L. F. AUDRIETH

  DOI：10.1021/jo01354a010

  日期：1957.3
• Thiadiazatrimethylenemethane and N,N′,P-triphenylphosphonothioic diamide complexes of platinum(<scp>II</scp>)
  作者：William Henderson、Raymond D. W. Kemmitt、Simon Mason、Mark R. Moore、John Fawcett、David R. Russell

  DOI：10.1039/dt9920000059

  日期：——

  Reaction of N,N'-diphenylthiourea with cis-[PtCl2L2] [L = PPh3, PMePh2, PMe2Ph, PEt2Ph, PPh2(NEt2) or L2 = Ph2PCH2CH2PPh2 (dppe) in the presence of silver(I) oxide gives the thiadiazatrimethylenemethane complexes [activated PtSC(=NPh)NPh}L2] an X-ray study on [activated PtSC(= NPh)NPh}(PPh3)2] establishing the presence of a flat activated Pt-S-C-N ring. Related activated Pt-S-P-N ring complexes which contain a reactive nucleophilic P = NPh group are formed upon treatment of PhNHP(S) (Ph)NHPh with cis-[PtCl2L2] [L = PPh3, L2 = dppe, Ph2P(CH2)3PPh2 or Ph2P(CH2)4PPh2] and potassium hydroxide. Treatment of [activated PtSP(= NPh)(Ph)NPh}L2] with Mel afforded an aminophosphonium salt, whilst with substrates containing either C = O or C = S functionalities new complexes of the type [activated [PtSPO(O)(Ph)NPh}L2] or [PtSP(S)(Ph)S}L2] were formed respectively.
• US4364991A
  申请人：——

  公开号：US4364991A

  公开（公告）日：1982-12-21
• [EN] NON-TOXIC CORROSION-PROTECTION PIGMENTS BASED ON MANGANESE<br/>[FR] PIGMENTS ANTI-CORROSION NON TOXIQUES A BASE DE MANGANESE
  申请人：UNIV DAYTON

  公开号：WO2004065305A1

  公开（公告）日：2004-08-05

  Corrosion-inhibiting pigments based on manganese are described that contain a trivalent or tetravalent manganese/valence stabilizer complex. An inorganic or organic material is used to stabilize the trivalent or tetravalent manganese ion to form a compound that is sparingly soluble, exhibits low solubility, or is insoluble in water, depending upon the intended usage. Specific stabilizers are chosen to control the release rate of trivalent or tetravalent manganese during exposure to water and to tailor the compatibility of the powder when used as a pigment in a chosen binder system. Stabilizers may also modify the processing and handling characteristics of the formed powders. Manganese/valence stabilizer combinations are chosen based on the well­founded principles of manganese coordination chemistry. Many manganese-valence stabilizer combinations are presented that can equal the performance of conventional hexavalent chromium or tetravalent lead systems.
• Argent, Peter J.; Healy, James D.; Ibrahim, Ezzeldine H., Phosphorus and Sulfur and the Related Elements, 1981, vol. 12, p. 95 - 102
  作者：Argent, Peter J.、Healy, James D.、Ibrahim, Ezzeldine H.、Shaw, Robert A.、Woods, Michael

  DOI：——

  日期：——