2-methyl-1,1-bis(2-hydroxyphenyl)propane | 67897-10-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2-methyl-1,1-bis(2-hydroxyphenyl)propane
• 英文别名: 2,2'-(2-Methylpropylidene)bis(phenol)；2,2'-(2-Methylpropane-1,1-diyl)diphenol；2-[1-(2-hydroxyphenyl)-2-methylpropyl]phenol
• CAS: 67897-10-3
• 化学式: C₁₆H₁₈O₂
• 分子量: 242.318
• InChiKey: GNECNKSOMNJZKM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.3
• 重原子数：
  18
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  40.5
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  2-methyl-1,1-bis(2-hydroxyphenyl)propane 、 乙基溴化镁 生成 magnesium;2-[1-(2-hydroxyphenyl)-2-methylpropyl]phenolate;bromide
  参考文献：
  名称：

  CASNATI, G.;POCHINI, A.;TERENGHI, M. G.;UNGARO, R., J. ORG. CHEM., 1983, 48, N 21, 3783-3787

  摘要：

  DOI：
• 作为产物：
  描述：

  bromomagnesium phenolate 、 异丁醛 以70%的产率得到
  参考文献：
  名称：

  CASNATI, G.;POCHINI, A.;TERENGHI, M. G.;UNGARO, R., J. ORG. CHEM., 1983, 48, N 21, 3783-3787

  摘要：

  DOI：

文献信息

• Trifunctional olefinic-capped polymers and compositions that include such polymers
  申请人：——

  公开号：US20030032732A1

  公开（公告）日：2003-02-13

  A polymer having at least one reactive terminal or pendant functional group that has been capped with a trifunctional olefinic compound. The polymer can be made by contacting a base polymer having at least one reactive terminal or pendant functional group with a trifunctional olefinic compound under conditions effective to react at least one of the terminal or pendant functional groups with the trifunctional olefinic compound. The capped polymers are particularly suitable as crosslinking toughening agents in multi-components compositions such as adhesives, coatings and matrices for composites.

  具有至少一个反应端或挂链官能团的聚合物，该聚合物已被三官能基烯烃化合物封顶。该聚合物可以通过将至少具有一个反应端或挂链官能团的基础聚合物与三官能基烯烃化合物接触，在有效反应条件下至少反应一个端或挂链官能团与三官能基烯烃化合物。封顶的聚合物在多组分组成物中特别适用于交联增韧剂，例如粘合剂、涂料和复合材料基体。
• Internally coordinated organoboranes
  申请人：Lord Corporation

  公开号：US20040242817A1

  公开（公告）日：2004-12-02

  Disclosed are internally coordinated organoboranes as 5, 6, or 7-membered rings formed from an unsaturated amine, amidine, or guanidine and dialkylhydroborane under hydroboration conditions, as well as two-part adhesive or coating kits containing radical polymerizable material and the internally coordinated organoborane. A representative internally coordinated organoborane is: 1

  本发明涉及在氢化硼条件下，从不饱和胺、酰胺或脲和二烷基氢硼烷形成的5、6或7元环的内部配位有机硼化合物，以及包含自由基聚合材料和内部配位有机硼烷的两部分粘合剂或涂料套件。代表性的内部配位有机硼化合物为：1。
• TRIFUNCTIONAL OLEFINIC-CAPPED POLYMERS AND COMPOSITIONS THAT INCLUDE SUCH POLYMERS
  申请人：——

  公开号：US20020128418A1

  公开（公告）日：2002-09-12

  A polymer having at least one reactive terminal or pendant functional group that has been capped with a trifunctional olefinic compound. The polymer can be made by contacting a base polymer having at least one reactive terminal or pendant functional group with a trifunctional olefinic compound under conditions effective to react at least one of the terminal or pendant functional groups with the trifunctional olefinic compound. The capped polymers are particularly suitable as crosslinking toughening agents in multi-components compositions such as adhesives, coatings and matrices for composites.

  具有至少一个反应末端或挂链官能团，并已用三官能双键化合物封顶的聚合物。该聚合物可以通过将至少具有一个反应末端或挂链官能团的基础聚合物与三官能双键化合物接触，在有效反应条件下使末端或挂链官能团中的至少一个与三官能双键化合物反应而制得。封顶聚合物特别适用于多组分组合物中的交联增韧剂，例如粘合剂、涂料和复合材料基体。
• Thermochromic dry offset ink, and printed article produced using the same
  申请人：——

  公开号：US20020121218A1

  公开（公告）日：2002-09-05

  A thermochromic dry offset ink comprising a dry offset ink medium and a thermochromic pigment material dispersed therein, wherein the thermochromic pigment material is a pigment material which has a microcapsular form having non-round particle cross section and has a thermochromic material enclosed in the microcapsules. Also disclosed is a printed article produced using the ink. The thermochromic dry offset ink can more improve pressure resistance and heat resistance and also can more satisfy uniform printability and high-speed continuous printability in offset printing especially on articles such as containers.

  一种热致变色干胶印油墨，包括干胶印油墨介质和分散在其中的热致变色颜料材料，其中热致变色颜料材料是一种具有微胶囊形式的颜料材料，该微胶囊具有非圆形颗粒横截面，并在微胶囊中包覆有热致变色材料。此外，还公开了一种使用该油墨生产的印刷品。 这种热致变色干胶印油墨能更好地提高耐压性和耐热性，还能更好地满足胶印中的均匀印刷性和高速连续印刷性，尤其是在容器等物品上。
• Internally blocked organoborate initiators and adhesives therefrom
  申请人：Lord Corporation

  公开号：US20030138651A1

  公开（公告）日：2003-07-24

  Disclosed are internally blocked borates useful for polymerizable compositions, and polymerizable adhesives made therewith. The internally blocked borates have general structures: 1 wherein X represents —CHR 6 —, oxygen or sulfur; n is an integer; R 1 , R 2 , R 3 , R 4 , R 5 , and R 6 are independently selected, for example, from unsubstituted and substituted C 1 -C 10 alkyl, alkylene groups, or aryl groups, including other embodiments further defined, and M is a counter ion with positive charge m.

  所公开的是可用于可聚合组合物的内部封端硼酸盐，以及用其制成的可聚合粘合剂。这些内部封端硼酸盐具有一般结构： 1 其中 X 代表 -CHR 6 -、氧或硫；n 为整数；R 1 , R 2 , R 3 , R 4 , R 5 和 R 6 独立地选自例如未取代和取代的 C 1 -C 10 烷基、亚烷基或芳基，包括进一步定义的其他实施方案，而 M 是带正电荷 m 的反离子。