3-[3-[3,5-Bis(3,5-dipyridin-3-ylphenyl)phenyl]-5-pyridin-3-ylphenyl]pyridine | 832080-38-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 3-[3-[3,5-Bis(3,5-dipyridin-3-ylphenyl)phenyl]-5-pyridin-3-ylphenyl]pyridine
• CAS: 832080-38-3
• 化学式: C₅₄H₃₆N₆
• 分子量: 768.92
• InChiKey: WUFBJHVXSLIWSD-UHFFFAOYSA-N

物化性质

• 密度：
  1.208±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  10.1
• 重原子数：
  60
• 可旋转键数：
  9
• 环数：
  10.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  77.3
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  ethylenediamine palladium(II) nitrate 、 3-[3-[3,5-Bis(3,5-dipyridin-3-ylphenyl)phenyl]-5-pyridin-3-ylphenyl]pyridine 以 neat (no solvent) 为溶剂， 生成 [(((C5NH4)2(C6H3))3(C6H3))4((1,2-ethanediamine)Pd)12(NO3)24]
  参考文献：
  名称：

  夹有钯（II）的芳香族三明治。

  摘要：

  DOI：

  10.1002/anie.200460868
• 作为产物：
  描述：

  3,5-二溴苯乙酮 在 potassium phosphate 、 四(三苯基膦)钯 、 四氯化硅 作用下， 以 乙醇 、 水 、 甲苯 为溶剂， 反应 72.0h， 生成 3-[3-[3,5-Bis(3,5-dipyridin-3-ylphenyl)phenyl]-5-pyridin-3-ylphenyl]pyridine
  参考文献：
  名称：

  夹有钯（II）的芳香族三明治。

  摘要：

  DOI：

  10.1002/anie.200460868

文献信息

• BIPIRIDINE DERIVATIVE AND ORGANIC ELECTROLUMINESCENCE ELEMENT CONTAINING THE SAME
  申请人：Kimura Masato

  公开号：US20100327265A1

  公开（公告）日：2010-12-30

  The present invention provides a new bipyridine derivative which is suitable for an electron transport material of an organic electronics element and which has bipyridyl central rings as a core, and further provides an organic electroluminescence element containing the derivative. The bipyridine derivative is expressed by the following general formula. (where A 1 , A 2 : represent an aromatic heterocyclic group (except for a carbazolyl group) and an aromatic hydrocarbon group and the aromatic heterocyclic group may be combined; a, b=1 or 2; Ar 1 , Ar 2 : represent a divalent or trivalent aromatic hydrocarbon group which may be substituted by hydrogen atom, an alkyl group, a cycloalkyl group, or an alkoxy group; B 1 , B 2 : represent hydrogen atom, an alkyl group, a cycloalkyl group, an alkoxy group, an aromatic hydrocarbon group, or an aromatic heterocyclic group; and ring E 1 , ring E 2 : represent a pyridine ring, and may have hydrogen atom, an alkyl group, a cycloalkyl group, or an alkoxy group.), which is used as an electron transport material.

  本发明提供了一种新的联吡啶衍生物，适用于有机电子元件的电子传输材料，并且以联吡啶中心环为核心，并进一步提供了含有该衍生物的有机电致发光元件。该联吡啶衍生物由以下通用公式表示（其中A1、A2：表示芳香杂环基团（除了羰基苯胺基团）和芳香烃基团，芳香杂环基团可以结合；a、b=1或2；Ar1、Ar2：表示可以被氢原子、烷基基团、环烷基基团或烷氧基取代的二价或三价芳香烃基团；B1、B2：表示氢原子、烷基基团、环烷基基团、烷氧基、芳香烃基团或芳香杂环基团；环E1、环E2：表示吡啶环，并且可能带有氢原子、烷基基团、环烷基基团或烷氧基），该衍生物用作电子传输材料。
• Bipiridine derivative and organic electroluminescence element containing the same
  申请人：Yamagata Promotional Organization for Industrial Technology

  公开号：EP2275409A1

  公开（公告）日：2011-01-19

  The present invention provides a new bipyridine derivative which is suitable for an electron transport material of an organic electronics element and which has bipyridyl central rings as a core, and further provides an organic electroluminescence element containing the derivative. The bipyridine derivative is expressed by the following general formula. (where A1, A2: represent an aromatic heterocyclic group (except for a carbazolyl group) and an aromatic hydrocarbon group and the aromatic heterocyclic group may be combined; a, b = 1 or 2; Ar1, Ar2: represent a divalent or trivalent aromatic hydrocarbon group which may be substituted by hydrogen atom, an alkyl group, a cycloalkyl group, or an alkoxy group; B1, B2: represent hydrogen atom, an alkyl group, a cycloalkyl group, an alkoxy group, an aromatic hydrocarbon group, or an aromatic heterocyclic group; and ring E1, ring E2: represent a pyridine ring, and may have hydrogen atom, an alkyl group, a cycloalkyl group, or an alkoxy group.), which is used as an electron transport material.

  本发明提供了一种新的联吡啶衍生物，适用于有机电子元件的电子传输材料，并且具有联吡啶中心环作为核心，并进一步提供了含有该衍生物的有机电致发光元件。联吡啶衍生物由以下一般公式表示（其中A1、A2：代表芳香杂环基团（除了吲哚基团）和芳香烃基团，芳香杂环基团可以结合；a，b = 1或2；Ar1，Ar2：代表可由氢原子、烷基、环烷基或烷氧基取代的二价或三价芳香烃基团；B1，B2：代表氢原子、烷基、环烷基、烷氧基、芳香烃基团或芳香杂环基团；环E1，环E2：代表吡啶环，并且可以具有氢原子、烷基、环烷基或烷氧基）。该衍生物用作电子传输材料。
• ORGANIC ELECTROLUMINESCENCE MATERIAL AND ELEMENT USING THE SAME
  申请人：ODA Atsushi

  公开号：US20090160328A1

  公开（公告）日：2009-06-25

  An organic EL element having one or a plurality of organic layers including a light emitting layer between a pair of electrodes is arranged such that at least one layer of the above-mentioned organic layers contains a compound as expressed by the following general formula (1) independently or as a mixture. (where R 1 -R 4 are selected from the group consisting of hydrogen, an alkyl group, a cycloalkyl group, an alkoxy group, a cycloalkoxy group, and an aryloxy group, and they may be the same groups or the groups different from one another, and A 1 -A 4 are selected from the group consisting of a phenyl group which is either substituted or unsubstituted and a 5 or 6 member heterocyclic ring group which is either substituted or unsubstituted, and they may be the same groups or the groups different from one another.)

  一种有机EL元件，其中包括一对电极之间的发光层和一个或多个有机层，使得上述有机层中的至少一层独立地或混合地包含以下一般式（1）所表示的化合物。（其中R1-R4选择自氢、烷基、环烷基、烷氧基、环烷氧基和芳氧基组成的群体，它们可以是相同的群体或不同的群体，并且A1-A4选择自苯基（取代或未取代）和5或6个成员的杂环环基（取代或未取代）组成的群体，它们可以是相同的群体或不同的群体。）
• Organic electroluminescence element
  申请人：Yamagata Promotional Organization for Industrial Technology

  公开号：EP2075305A2

  公开（公告）日：2009-07-01

  An organic EL element having one or a plurality of organic layers including a light emitting layer between a pair of electrodes is arranged such that at least one layer of the above-mentioned organic layers contains a compound as expressed by the following general formula (1) independently or as a mixture. (where, R1-R4 are selected from the group consisting of hydrogen, an alkyl group, a cycloalkyl group, an alkoxy group, a cycloalkoxy group, and an aryloxy group, and they may be the same groups or the groups different from one another, and A1-A4 are selected from the group consisting of a phenyl group which is either substituted or unsubstituted and a 5 or 6 member heterocyclic ring group which is either substituted or unsubstituted, and they may be the same groups or the groups different from one another.)

  有机电致发光元件具有一个或多个有机层，其中包括位于一对电极之间的发光层，其布置方式为上述有机层中至少有一层单独或作为混合物含有下式（1）表示的化合物。 (其中，R1-R4选自由氢、烷基、环烷基、烷氧基、环烷氧基和芳氧基组成的组，它们可以是相同的基团，也可以是彼此不同的基团；A1-A4选自由取代或未取代的苯基和取代或未取代的5或6个杂环组成的组，它们可以是相同的基团，也可以是彼此不同的基团)。
• Organic electroluminescence material and element using the same
  申请人：Yamagata Promotional Organization for Industrial Technology

  公开号：EP2075306A2

  公开（公告）日：2009-07-01

  An organic EL element having one or a plurality of organic layers including a light emitting layer between a pair of electrodes is arranged such that at least one layer of the above-mentioned organic layers contains a compound as expressed by the following general formula (1) independently or as a mixture. (where R1-R4 are selected from the group consisting of hydrogen, an alkyl group, a cycloalkyl group, an alkoxy group, a cycloalkoxy group, and an aryloxy group, and they may be the same groups or the groups different from one another, and A1-A4 are selected from the group consisting of a phenyl group which is either substituted or unsubstituted and a 5 or 6 member heterocyclic ring group which is either substituted or unsubstituted, and they may be the same groups or the groups different from one another.)

  有机电致发光元件具有一个或多个有机层，其中包括位于一对电极之间的发光层，其布置方式为上述有机层中至少有一层单独或作为混合物含有下式（1）表示的化合物。 (其中 R1-R4 选自氢、烷基、环烷基、烷氧基、环烷氧基和芳氧基组成的组，它们可以是相同的基团或彼此不同的基团，A1-A4 选自取代或未取代的苯基和取代或未取代的 5 或 6 个杂环组成的组，它们可以是相同的基团或彼此不同的基团)。