[4-(Dimethylamino)phenyl] prop-2-enoate | 110608-33-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚酯
• 英文名称: [4-(Dimethylamino)phenyl] prop-2-enoate
• CAS: 110608-33-8
• 化学式: C₁₁H₁₃NO₂
• 分子量: 191.23
• InChiKey: VDHMFBVEJUXEOC-UHFFFAOYSA-N

物化性质

• 沸点：
  310.9±21.0 °C(Predicted)
• 密度：
  1.082±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.4
• 重原子数：
  14
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.18
• 拓扑面积：
  29.5
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  苯甲醛 、 [4-(Dimethylamino)phenyl] prop-2-enoate 在 三乙烯二胺 作用下， 反应 84.0h， 以62%的产率得到3-phenyl-3-hydroxy-2-methylene-propanoic acid p-N,N-dimethylaminophenyl ester
  参考文献：
  名称：

  The ‘Baylis - Hillman Reaction’ mechanism and applications revisited

  摘要：

  It is shown that reaction of aryl, benzyl, alkyl and functionalised alkyl acrylic esters with benzaldehyde, in the presence of 1,4-diazabicyclo[2.2.2] octane, strongly depends upon the electronic and steric effects of the ester part. This influence is also observed in condensation of furfuraldehyde. Moreover, for the first time, it is shown that the overall condensation is equilibrated.

  DOI：

  10.1016/s0040-4020(01)88227-2
• 作为产物：
  描述：

  4-二甲氨基苯酚 、 丙烯酰氯 在 三乙胺 作用下， 以 氯仿 为溶剂， 反应 12.0h， 生成 [4-(Dimethylamino)phenyl] prop-2-enoate
  参考文献：
  名称：

  The ‘Baylis - Hillman Reaction’ mechanism and applications revisited

  摘要：

  It is shown that reaction of aryl, benzyl, alkyl and functionalised alkyl acrylic esters with benzaldehyde, in the presence of 1,4-diazabicyclo[2.2.2] octane, strongly depends upon the electronic and steric effects of the ester part. This influence is also observed in condensation of furfuraldehyde. Moreover, for the first time, it is shown that the overall condensation is equilibrated.

  DOI：

  10.1016/s0040-4020(01)88227-2

文献信息

• Coating compositions for preventing adhesion of aquatic organisms
  申请人：KANSAI PAINT CO. LTD.

  公开号：EP0327021A2

  公开（公告）日：1989-08-09

  Disclosed is a coating composition for preventing adhesion of aquatic organisms, the composition containing as a vehicle component a copolymer prepared by copolymerizing about 5 to about 85% by weight of (A) a monohydric and/or polyhydric phenol ester of acrylic or methacrylic acid; about 15 to about 75% by weight of (B) an ethylenically unsaturated monomer having a soluble parameter of about 8.0 to about 9.5 and a glass transition temperature of about 0°C or higher; and about 0 to about 50% by weight of (C) a water-soluble, ethylenically unsaturated monomer containing carboxyl group or amino group, based on the total monomer components.

  公开了一种用于防止水生生物粘附的涂层组合物，该组合物含有作为载体组分的共聚物，该共聚物是通过共聚以下物质制备的：(A)丙烯酸或甲基丙烯酸的单水和/或多水苯酚酯，约5%至约85%(重量)；(B)乙烯基不饱和单体，约15%至约75%(重量)，该乙烯基不饱和单体具有约8.0至约9.5和玻璃化温度约为0℃或更高的乙烯基不饱和单体；以及以单体总组分为基准，约0至约50%(重量)的(C)含羧基或氨基的水溶性乙烯基不饱和单体。
• Positive Charge Control Resin for Electrophotographic Functional Component Parts, Developing Roller, and Electrophotographic Apparatus
  申请人：Yoshida Tatsurou

  公开号：US20080247787A1

  公开（公告）日：2008-10-09

  To provide a positive charge control resin with which an electrophotographic functional component part coming into contact with a toner can be made chargeable in a polarity reverse to the polarity of the toner, and which has superior dispersibility in, and compatibility with, a main binder. The present invention is a positive charge control resin having a copolymer obtained by polymerizing specific acrylate or methacrylate monomer, amino-group-containing monomer(s) and carboxyl-group-containing monomer(s) as copolymerization components.
• US3961961A
  申请人：——

  公开号：US3961961A

  公开（公告）日：1976-06-08
• US4939219A
  申请人：——

  公开号：US4939219A

  公开（公告）日：1990-07-03
• US6758559B1
  申请人：——

  公开号：US6758559B1

  公开（公告）日：2004-07-06