4-(4-aminophenyloxy)dodecanamide | 947489-02-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 4-(4-aminophenyloxy)dodecanamide
• 英文别名: N-[4-(4-aminophenoxy)phenyl]dodecanamide
• CAS: 947489-02-3
• 化学式: C₂₄H₃₄N₂O₂
• 分子量: 382.546
• InChiKey: IQZBWFZTDVLGBY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.1
• 重原子数：
  28
• 可旋转键数：
  13
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.46
• 拓扑面积：
  64.4
• 氢给体数：
  2
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  4-(4-aminophenyloxy)dodecanamide 、 1,1'-二茂铁二甲醛 在 盐酸 作用下， 以 乙醇 为溶剂， 以85%的产率得到1,1'-bis[4,4'-dodecanamido-N-phenyloxybenzimine]ferrocene
  参考文献：
  名称：

  Synthesis and physico-analytical studies of some novel ferrocenyl Schiff base derivatives

  摘要：

  A series of ferrocenyl Schiff base derivatives was synthesized by condensation reactions of 1,1'-ferrocenedicarboxaldehyde and aromatic amines containing long chain alkyl groups as free ends which were characterized by their physical properties, elemental, FTIR, H-1 NMR, C-13 NMR spectral and thermal analysis. The thermal behaviour of the synthesized compounds was studied by differential scanning calorimetry (DSC) which revealed that these compounds may exhibit mesomorphic properties. The DSC results of aromatic amines and ferrocenyl Schiff bases were compared to study the effects of structure, i.e. rigid core and terminal chain length, on the phase transition behaviour. (c) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2007.03.034
• 作为产物：
  描述：

  4-硝基-4'-氨基二苯醚 在 palladium on activated charcoal 三乙胺 作用下， 以 乙醇 、 甲苯 为溶剂， 反应 19.0h， 生成 4-(4-aminophenyloxy)dodecanamide
  参考文献：
  名称：

  Synthesis and physico-analytical studies of some novel ferrocenyl Schiff base derivatives

  摘要：

  A series of ferrocenyl Schiff base derivatives was synthesized by condensation reactions of 1,1'-ferrocenedicarboxaldehyde and aromatic amines containing long chain alkyl groups as free ends which were characterized by their physical properties, elemental, FTIR, H-1 NMR, C-13 NMR spectral and thermal analysis. The thermal behaviour of the synthesized compounds was studied by differential scanning calorimetry (DSC) which revealed that these compounds may exhibit mesomorphic properties. The DSC results of aromatic amines and ferrocenyl Schiff bases were compared to study the effects of structure, i.e. rigid core and terminal chain length, on the phase transition behaviour. (c) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2007.03.034

文献信息

• Synthesis and physico-analytical studies of some novel ferrocenyl Schiff base derivatives
  作者：Zareen Akhter、Asifa Nigar、Muhammad Y. Razzaq、Humaira M. Siddiqi

  DOI：10.1016/j.jorganchem.2007.03.034

  日期：2007.7

  A series of ferrocenyl Schiff base derivatives was synthesized by condensation reactions of 1,1'-ferrocenedicarboxaldehyde and aromatic amines containing long chain alkyl groups as free ends which were characterized by their physical properties, elemental, FTIR, H-1 NMR, C-13 NMR spectral and thermal analysis. The thermal behaviour of the synthesized compounds was studied by differential scanning calorimetry (DSC) which revealed that these compounds may exhibit mesomorphic properties. The DSC results of aromatic amines and ferrocenyl Schiff bases were compared to study the effects of structure, i.e. rigid core and terminal chain length, on the phase transition behaviour. (c) 2007 Elsevier B.V. All rights reserved.