6-bromo-6-methyl-hept-1-en-4-yne | 34455-75-9

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 有机溴化物
• 英文名称: 6-bromo-6-methyl-hept-1-en-4-yne
• 英文别名: 2-Dibrom-2-methyl-hepten-(6)-in-(3)；2-Brom-2-methyl-hepten-(6)-in-(3)；6-Bromo-6-methylhept-1-en-4-yne
• CAS: 34455-75-9
• 化学式: C₈H₁₁Br
• 分子量: 187.079
• InChiKey: BAGFCVPXOQJZMN-UHFFFAOYSA-N

物化性质

• 沸点：
  39.5-40.5 °C(Press: 3 Torr)
• 密度：
  1.1796 g/cm3

计算性质

• 辛醇/水分配系数(LogP)：
  2.9
• 重原子数：
  9
• 可旋转键数：
  1
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  6-bromo-6-methyl-hept-1-en-4-yne 生成 6-Methyl-1,3,4,5-heptatetraen
  参考文献：
  名称：

  MXITARYAN G. R.; KINOYAN F. S.; XRIMYAN A. P.; BADANYAN SH. O., ARM. XIM. ZH., 1979, 32, NO 2, 113-119

  摘要：

  DOI：
• 作为产物：
  描述：

  2-methyl-hepta-1,6-dien-3-yne 在 氢溴酸 作用下， 生成 6-bromo-6-methyl-hept-1-en-4-yne
  参考文献：
  名称：

  Petrov,A.A.; Porfir'eva,Yu.I., Journal of General Chemistry of the USSR, 1963, vol. 33, p. 413 - 420

  摘要：

  DOI：

文献信息

• Diene Condensation of Cyclopentadiene with Dienophiles of Allylacetylene Series
  作者：M. G. Veliev、A. Z. Chalabieva、M. I. Shatirova、E. G. Akperova

  DOI：10.1023/b:rujo.0000003159.15212.50

  日期：2003.6

  Diene condensation of cyclopentadiene with 2-substituted allylacetylenes occurs nonselectively at a double and triple bonds; therewith the dienophile activity grows in parallel with the electron-withdrawing properties of the substituent. Depending on electronic character of functional groups the reaction proceeds as ''neutral" diene synthesis. The relative activity of cyclopentadiene and 1,3-cyclohexadiene in reactions with allylacetylenes is essentially governed by the different distance between the 1,4-reactive sites in these systems.
• ——
  作者：M.G. Veliev、A.Z. Zhalobieva、M.I. Shatirova、E.Sh. Mamedov、I.M. Mamedov

  DOI：10.1023/a:1012326912373

  日期：——

  Diene condensations of hexachlorocyclopentadiene and 5,5-dimethoxytetrachlorocyclopentadiene were carried out with dienophiles of allylacetylene series. The reaction was demonstrated to proceed stercospecifically yielding adducts of the endo-configuration. The reactivity of functionalized allylacetylene compounds in the diene synthesis with hexachlorocyclopentadiene was studied, and the reaction was established to occur by the type of a "neutral" diene synthesis. It was established that the Faworsky decomposition of polychlorobicyclic alcohols containing in the side chain a triple bond adjacent to a methylene group occurred with acetylene-allene isomerization.
• MXITARYAN G. R.; KINOYAN F. S.; XRIMYAN A. P.; BADANYAN SH. O., ARM. XIM. ZH., 1979, 32, NO 2, 113-119
  作者：MXITARYAN G. R.、 KINOYAN F. S.、 XRIMYAN A. P.、 BADANYAN SH. O.

  DOI：——

  日期：——
• Petrov,A.A.; Porfir'eva,Yu.I., Journal of General Chemistry of the USSR, 1963, vol. 33, p. 413 - 420
  作者：Petrov,A.A.、Porfir'eva,Yu.I.

  DOI：——

  日期：——