2,4,6-(CH3)3C6H2HgCl | 20883-32-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2,4,6-(CH3)3C6H2HgCl
• 英文别名: (mercury)(mesityl)Cl；Chlormercuri-mesitylen
• CAS: 20883-32-3
• 化学式: C₉H₁₁ClHg
• 分子量: 355.229
• InChiKey: CDVQLMATJCPQMS-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  2.47
• 重原子数：
  11
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  2,4,6-(CH3)3C6H2HgCl 在 sulfur 作用下， 以 环丁砜 为溶剂， 生成 bis(2,4,6-trimethylphenyl)disulfide
  参考文献：
  名称：

  Preparation of disulphides from organomercury compounds and sulphur

  摘要：

  DOI：

  10.1016/s0022-328x(00)91091-x
• 作为产物：
  描述：

  magnesium,1,3,5-trimethylbenzene-6-ide,bromide 在 dioxane 作用下， 以 四氢呋喃 为溶剂， 生成 2,4,6-(CH3)3C6H2HgCl
  参考文献：
  名称：

  Machelett, B., Zeitschrift fur Chemie, 1976, vol. 16, p. 116 - 117

  摘要：

  DOI：

文献信息

• Mercury in organic chemistry. 20. Alkylation of organomercurials via organocopper reagents
  作者：R.C. Larock、D.R. Leach

  DOI：10.1016/s0040-4039(01)81925-0

  日期：1981.1

  Aryl-, alkenyl-, and alkylmercurials readily cross-couple with primary and secondary alkyl- and alkenylcuprate reagents to provide the first truly general method for the alkylation of a wide variety of organomercurials.

  芳基，烯基和烷基汞容易与伯，仲烷基和烯基铜酸盐试剂交联，从而为各种有机汞的烷基化提供了第一个真正通用的方法。
• Crystal Structures and Chemical Properties of Dimesitylcadmium and Dimesitylmercury
  作者：Mari Hayashi、Michael Bolte、Matthias Wagner、Hans-Wolfram Lerner

  DOI：10.1002/zaac.201100049

  日期：2011.5

  Mesityllithium was used to synthesize dimesitylcadmium and dimesitylmercury from CdCl2 and HgCl2, respectively. X-ray-crystallographic data show that the group 12 metal compounds M[Mes]2 (M = Zn, Cd, Hg) are isomorphous (monoclinic, P21/n). The asymmetric unit of M[Mes]2 (M = Zn, Cd, Hg) consists of one mesityl group bonded to the metal atom, which is related to the second substituent by an inversion

  Mesityllithium 用于分别从 CdCl2 和 HgCl2 合成二甲苯镉和二甲苯汞。X 射线晶体学数据显示第 12 族金属化合物 M[Mes]2（M = Zn、Cd、Hg）是同晶的（单斜晶系，P21/n）。M[Mes]2 的不对称单元（M = Zn、Cd、Hg）由一个与金属原子键合的均三甲苯基团组成，该基团通过反转中心与第二个取代基相关。此外，我们研究了 BBr3 与 M[Mes]2 (M = Cd, Hg) 的反应，以了解无供体组 12 甲基化合物的反应性。M[Mes]2 (M = Cd, Hg) 与过量的 BBr3 反应生成 MesBBr2。紫外诱导的苯中 Hg[Mes]2 转化产生了定量的均三甲苯和汞，而将 Hg[Mes]2 的氯仿溶液照射 1290 分钟（λmax = 510 nm）得到均三甲苯、Hg[Mes]Cl、和 HgCl2 的比例为 6:4:1。反应溶液的缓慢浓缩导致两个
• Kreisel, G.; Scholz, P.; Seidel, W., Zeitschrift fur Anorganische und Allgemeine Chemie
  作者：Kreisel, G.、Scholz, P.、Seidel, W.

  DOI：——

  日期：——
• Mesityl gold(III) complexes. X-ray structure of mononuclear [Au(mes)2Cl(PPh3)] and the dimer [Au(mes)2Cl]2
  作者：Marı́a Contel、Andrew J Edwards、Julián Garrido、Michael B Hursthouse、Mariano Laguna、Raquel Terroba

  DOI：10.1016/s0022-328x(00)00306-5

  日期：2000.8

  The reaction between PPN[AuCl4] and [Hg(mes)(2)] gives the anionic complex cis-PPN[Au(mes)(2)Cl-2] (1) and [Hg(mes)Cl] as side-product. Complex 1 is a precursor to other compounds both neutral and cationic. Removal of one chloride ligand affords the mononuclear neutral complexes cis-[Au(mes)(2)ClL] (L = PPh3 (2), Pp-tol}(3) (3), AsPh3 (4), SPPh3 (5)) by addition of a neutral ligand or, alternatively if no ligand is added, dimeric cis-[Au(mes)(2)Cl](2) (6). If both chloride groups in 1 are removed, cationic compounds can be obtained by addition of a potentially bidentate ligand affording cis-[Au(mes)(2)(L-L)]X complexes (X = ClO4, L-L = bipy (7), L-L = phen (8), L-L = dppe (9) X = SO3CF3, L-L = dppm (10)). Dithiocarbamate- or acetate salts can be added to solutions of 'Au(mes)(2)X' (obtained by removal of two chloride anions in 1) leading to the neutral compounds cis-[Au(mes),(L-L)] (L-L = S2CNR2 (R = Me (11), Et (12), Bz (13)), O2CCF3 (14)). The structures of cis-[Au(mes)(2)Cl(PPh3)] (2) and cis-[Au(mes)(2)Cl](2) (6) have been established by an X-ray diffraction study. (C) 2000 Elsevier Science S.A. All rights reserved.
• Aromatic haloethylation with palladium and copper halides
  作者：Richard F. Heck

  DOI：10.1021/ja01022a038

  日期：1968.9