3,5-dibromo-2-methoxybenzamide | 90050-67-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 3,5-dibromo-2-methoxybenzamide
• 英文别名: 3,5-dibromo-2-methoxy-benzoic acid amide；3,5-Dibrom-2-methoxy-benzoesaeure-amid；3.5-Dibrom-2-methoxy-benzamid
• CAS: 90050-67-2
• 化学式: C₈H₇Br₂NO₂
• mdl: MFCD13187461
• 分子量: 308.957
• InChiKey: QXBSMIREDHYMFV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.2
• 重原子数：
  13
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.12
• 拓扑面积：
  52.3
• 氢给体数：
  1
• 氢受体数：
  2

安全信息

• 危险等级：
  IRRITANT

反应信息

• 作为反应物：
  描述：

  3,5-dibromo-2-methoxybenzamide 、 三氯乙醛 生成 3,5-dibromo-2-methoxy-benzoic acid-(2,2,2-trichloro-1-hydroxy-ethylamide)
  参考文献：
  名称：

  Hirwe; Gavankar; Patil, Proceedings - Indian Academy of Sciences, Section A, 1940, vol. 11, p. 512,515

  摘要：

  DOI：
• 作为产物：
  描述：

  3,5-二溴-2-羟基苯甲酸 在 sodium hydroxide 、 五氯化磷 作用下， 生成 3,5-dibromo-2-methoxybenzamide
  参考文献：
  名称：

  RAPD Analysis of Aromatic and Non-aromatic Rice (Oryza sativa L.)

  摘要：

  Genetic variation in nine aromatic and four nonaromatic rice varieties (Oryza sativa L.) was investigated at the DNA level using the randomly amplified polymorphic DNA (RAPD) technique. Twenty six random primers were used to amplify DNA segments and 177 PCR products were obtained of which 98 were polymorphic. One primer did not show polymorphism. A dendrogram showing the genetic distances of 13 rice varieties was constructed based on RAPD data.

  DOI：

  10.1007/bf03263078

文献信息

• Preparation of Primary Amides from Functionalized Organozinc Halides
  作者：Matthias A. Schade、Georg Manolikakes、Paul Knochel

  DOI：10.1021/ol101469f

  日期：2010.8.20

  Organozinc halides, which are prepared either by direct zinc insertion or halogen magnesium exchange and subsequent transmetalation with ZnCl2, react smoothly with commercially available trichloroacetyl isocyanate to give, after hydrolysis, the corresponding primary amides. This method is compatible with a variety of functional groups such as an ester or a cyano group. Also heterocyclic-, alkenyl, and acetylenic zinc reagents are converted to the corresponding primary amides under these conditions.
• Hirwe; Gavankar; Patil, Proceedings - Indian Academy of Sciences, Section A, 1940, vol. <A> 11, p. 512,515
  作者：Hirwe、Gavankar、Patil

  DOI：——

  日期：——
• RAPD Analysis of Aromatic and Non-aromatic Rice (Oryza sativa L.)
  作者：S. Baishya、Archana Sachdev、R. P. Johari、S. L. Mehta

  DOI：10.1007/bf03263078

  日期：2000.1

  Genetic variation in nine aromatic and four nonaromatic rice varieties (Oryza sativa L.) was investigated at the DNA level using the randomly amplified polymorphic DNA (RAPD) technique. Twenty six random primers were used to amplify DNA segments and 177 PCR products were obtained of which 98 were polymorphic. One primer did not show polymorphism. A dendrogram showing the genetic distances of 13 rice varieties was constructed based on RAPD data.