4-[N,N-bis-(3,4-dimethylphenyl)-amino] styrene | 190334-78-2

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 4-[N,N-bis-(3,4-dimethylphenyl)-amino] styrene
• 英文别名: 4-›N,N-bis-(3,4-dimethylphenyl)[amino]styrene；4-(N,N-di(3,4-dimethylphenyl)amino)styrene；4-[N,N-bis(3,4-dimethylphenyl)amino]styrene；N-(3,4-dimethylphenyl)-N-(4-ethenylphenyl)-3,4-dimethylaniline
• CAS: 190334-78-2
• 化学式: C₂₄H₂₅N
• 分子量: 327.469
• InChiKey: JFCRMLAWUGDKSG-UHFFFAOYSA-N

物化性质

• 沸点：
  482.2±45.0 °C(Predicted)
• 密度：
  1.050±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  7.4
• 重原子数：
  25
• 可旋转键数：
  4
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.17
• 拓扑面积：
  3.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  4-[N,N-bis-(3,4-dimethylphenyl)-amino] styrene 、 三乙氧基硅烷 在 Diplatinum (0) tris(tetramethyldivinyldisiloxane) 作用下， 以 甲苯 为溶剂， 反应 3.0h， 以to obtain oily pale yellow 4-[N,N-bis(3,4-dimethylphenyl)amino]-[2-(triethoxysilyl)ethyl]benzene in an amount of 13.4 g (yield: 90.1%)的产率得到4-[N,N-bis-(3,4-dimethylphenyl)-amino]-[2-(triethoxysilyl)-ethyl] benzene
  参考文献：
  名称：

  Electrophotographic photosensitive member, a process-cartridge inclusive

  摘要：

  本发明提供了一种电子照相感光体，其具有基板和感光层，其中感光体的表面保护层包含由可固化有机硅聚合物和有机硅改性的正空穴传输化合物固化而得的树脂；一种工艺盒，除了电子照相感光体外，还至少包括一个初级充电装置、一个显影装置和一个清洁装置，这些装置都放置在一个外壳内，可以可逆地安装到图像形成设备上；以及使用电子照相感光体的图像形成设备。

  公开号：

  US05879847A1
• 作为产物：
  描述：

  乙二醇二甲醚 、 4-[N,N-bis-(3,4-dimethylphenyl)-amino] benzaldehyde 、 trimethylphosphonium bromide 以85%的产率得到4-[N,N-bis-(3,4-dimethylphenyl)-amino] styrene
  参考文献：
  名称：

  Organosilicon-modified charge transporting compound and curable composition containing the compound and having charge transporting ability

  摘要：

  一种具有以下式（I）所表示结构的有机硅修饰的传输电荷化合物：其中A代表传输电荷基团，Q代表水解基团或羟基，R2代表含有1至15个碳原子的一价碳氢基团或卤素取代的一价碳氢基团，n为1至18，m为1至3，l为1至5；以及含有该有机硅修饰的传输电荷化合物和主要由有机硅高聚物组成的固化型树脂的可固化组合物。

  公开号：

  US06376695B1

文献信息

• Method of manufacturing a silicon-type charge transporting material
  申请人：Dow Corning Asia, Ltd.

  公开号：US05688961A1

  公开（公告）日：1997-11-18

  A method of manufacturing charge transporting materials which impart a charge transporting property to a polysiloxane resin, and which is soluble in the resin. The charge transporting material is an aromatic substituted tertiary amine with a plurality of aromatic groups, and a silyl group introduced via a hydrocarbon group, into at least one of the aromatic groups. The method is characterized by using an unsaturated aliphatic group bonded to an aromatic group which makes up the silicon-type charge transporting compound, or using a newly bonded unsaturated aliphatic group which is bonded to a silane in which the substituent for silicon is hydrogen or a hydrolyzable group. This is conducted in the presence of a platinum compound as catalyst by means of hydrosilylation. The silicon-type charge transporting material is then brought into contact with an adsorbent for the platinum compound, causing the platinum compound to be adsorbed onto the adsorbent. The platinum compound is removed along with the adsorbent, so that the concentration of residual platinum compound is less than 10 ppm.

  一种制造电荷传输材料的方法，该材料赋予聚硅氧烷树脂电荷传输性能，并且能够溶解在树脂中。电荷传输材料是一种含有多个芳香基团的芳基取代的三级胺，且通过碳氢基引入了一个硅基团，至少其中一个芳香基团中。该方法的特点在于，使用与构成硅型电荷传输化合物的芳香基团结合的不饱和脂肪基，或者使用新结合的与硅烷键合的不饱和脂肪基，其中硅的取代基是氢或可水解基。这是通过氢硅烷化反应，在铂化合物的存在下进行的。然后，将硅型电荷传输材料与铂化合物的吸附剂接触，使铂化合物被吸附到吸附剂上。然后将铂化合物与吸附剂一起移除，以使残留的铂化合物浓度小于10 ppm。
• Method of manufacturing sililcon-type charge transporting materials
  申请人：Dow Corning Asia, Ltd.

  公开号：US05824443A1

  公开（公告）日：1998-10-20

  A method of manufacturing solvent-soluble charge transporting materials capable of imparting charge-tranporting properties to polysiloxane resins. These materials have the formula A-\x9bR.sup.1 SiR.sup.2.sub.3-n Q.sub.n !.sub.p where A is a tertiary amine and organic group derived from a compound having charge transporting properties with an ionization potential of 4.5-6.2 eV; R.sup.1 is an alkylene group of 1-18 carbon atoms; R.sup.2 is a monovalent hydrocarbon group or a monovalent halogen-substituted hydrocarbon group of 1-15 carbon atoms; Q is a hydrolyzable group such as--OR.sup.3 where R.sup.3 is an alkyl group of 1-6 carbon atoms; n and p are each 1-3. This silicon-type charge transporting material is characterized by aromatic groups, and alkoxysilyl groups bonded via hydrocarbon groups onto the aromatic rings.

  一种制造溶剂可溶性电荷传输材料的方法，能够赋予聚硅氧烷树脂电荷传输特性。这些材料的公式为A-\x9bR.sup.1 SiR.sup.2_sub.3-n Q_sub.n !.sub.p，其中A是来自具有电荷传输性质并具有4.5-6.2电子伏特电离势的化合物的三级胺和有机基团；R.sup.1是1-18个碳原子的烷基；R.sup.2是1-15个碳原子的单价碳氢基团或单价卤素取代的碳氢基团；Q是可水解的基团，例如-OR.sup.3，其中R.sup.3是1-6个碳原子的烷基；n和p均为1-3。这种硅型电荷传输材料的特点是芳香族基团和通过碳氢基团连接到芳香环上的烷氧基硅基团。
• Electrophotographic photosensitive member, a process-cartridge inclusive
  申请人：Canon Kabushiki Kaisha

  公开号：US05879847A1

  公开（公告）日：1999-03-09

  The present invention provides an electrophotographic photosensitive member having a substrate and a photosensitive layer thereupon, wherein a surface protecting layer of the photosensitive member contains a resin which is obtained by curing a curable organosilicon polymer and an organosilicon-modified positive hole transporting compound; a process-cartridge which has, in addition to the electrophotographic photosensitive member, at least one from among a primary charging means, a developing means, and a cleaning means placed into a housing, and which can be reversibly mounted to an image forming apparatus; and the image forming apparatus using the electrophotographic photosensitive member.

  本发明提供了一种电子照相感光体，其具有基板和感光层，其中感光体的表面保护层包含由可固化有机硅聚合物和有机硅改性的正空穴传输化合物固化而得的树脂；一种工艺盒，除了电子照相感光体外，还至少包括一个初级充电装置、一个显影装置和一个清洁装置，这些装置都放置在一个外壳内，可以可逆地安装到图像形成设备上；以及使用电子照相感光体的图像形成设备。
• Electrophotographic photosensitive member, a process-cartridge inclusive thereof, and an image forming apparatus
  申请人：Canon Kabushiki Kaisha

  公开号：US06296978B1

  公开（公告）日：2001-10-02

  The present invention provides an electrophotographic photosensitive member having a substrate and a photosensitive layer thereupon, wherein a surface layer of the photosensitive member contains a resin which is obtained by being subject to polycondensation as a monomer component only an organosilicon-modified positive hole transporting compound; a process cartridge which has, in addition to the electrophotographic photosensitive member, at least one from among a primary charging means, a developing means, and a cleaning means placed into a housing; and the image forming apparatus using the electrophotographic photosensitive member.

  本发明提供了一种电子照相感光元件，其具有基板和其上的感光层，其中感光元件的表面层包含一种树脂，该树脂通过仅将有机硅修饰的正电荷传输化合物作为单体组分进行聚合得到；一种过程盒，该过程盒除了具有电子照相感光元件外，还将至少一个从主要充电手段、显影手段和清洁手段中的一个放置在壳体中；以及使用电子照相感光元件的图像形成设备。
• Silicon containing charge transport compounds
  申请人：DOW CORNING ASIA, Ltd.

  公开号：EP0771806B1

  公开（公告）日：2002-02-27