trimethylphosphonium bromide

• 分子结构分类: 有机化合物 - 有机磷化合物
• 英文名称: trimethylphosphonium bromide
• 英文别名: Trimethylphosphine hydrogen bromide；trimethylphosphane;hydrobromide
• 化学式: Br*C₃H₁₀P
• 分子量: 156.99
• InChiKey: ZUBQQDQYKGOZGK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -1.91
• 重原子数：
  5
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  聚合甲醛 、 trimethylphosphonium bromide 以 水 为溶剂， 反应 3.0h， 生成 hydroxymethyl-trimethyl-phosphonium bromide
  参考文献：
  名称：

  [（CH 3）3 PCH 2 OH] [CdBr 3 ]是高于室温的钙钛矿型铁弹性化合物

  摘要：

  一种新的有机-无机钙钛矿型化合物[（CH 3）3 PCH 2 OH] [CdBr 3 ]在339 K下表现出铁弹性相变。观察并分析了畴结构。相变的原点可以归因于的运动或重新定向的[（CH 3）3 PCH 2 OH] +的阳离子和Cd的位移2+和Br -固态晶体离子。

  DOI：

  10.1039/c7cc01771e
• 作为产物：
  描述：

  三甲基膦 在 氢溴酸 作用下， 以 乙醚 为溶剂， 反应 4.0h， 生成 trimethylphosphonium bromide
  参考文献：
  名称：

  [（CH 3）3 PCH 2 OH] [CdBr 3 ]是高于室温的钙钛矿型铁弹性化合物

  摘要：

  一种新的有机-无机钙钛矿型化合物[（CH 3）3 PCH 2 OH] [CdBr 3 ]在339 K下表现出铁弹性相变。观察并分析了畴结构。相变的原点可以归因于的运动或重新定向的[（CH 3）3 PCH 2 OH] +的阳离子和Cd的位移2+和Br -固态晶体离子。

  DOI：

  10.1039/c7cc01771e

文献信息

• Organosilicon-modified charge transporting compound and curable composition containing the compound and having charge transporting ability
  申请人：Dow Corning Asia Ltd.

  公开号：US06376695B1

  公开（公告）日：2002-04-23

  An organosilicon-modified charge transporting compound having a structure represented by the following Formula (I): wherein A represents a charge transporting group, Q represents a hydrolytic group or a hydroxyl group, R2 represents a monovalent hydrocarbon group or a halogen-substituted monovalent hydrocarbon group having 1 to 15 carbon atoms, n is 1 to 18, m is 1 to 3, and 1 is 1 to 5; and a curable composition containing the organosilicon-modified charge transporting compound and a cure type resin chiefly composed of an organosilicon high polymer.

  一种具有以下式（I）所表示结构的有机硅修饰的传输电荷化合物：其中A代表传输电荷基团，Q代表水解基团或羟基，R2代表含有1至15个碳原子的一价碳氢基团或卤素取代的一价碳氢基团，n为1至18，m为1至3，l为1至5；以及含有该有机硅修饰的传输电荷化合物和主要由有机硅高聚物组成的固化型树脂的可固化组合物。
• Weak complexes of sulphur and selenium. Part I. Complex species of SO2, SOCl2, and SO2Cl2 with chloride, bromide, and iodide ions
  作者：A. Salama、S. B. Salama、M. Sobeir、Saad Wasif

  DOI：10.1039/j19710001112

  日期：——

  The formation of 1 : 1 complex species between SO2, SOCl2, SO2Cl2, and Cl–, Br–, and l– is reported. The stability constants of the SO2X– species were determined in acetonitrile, dimethyl sulphoxide, and water. The stability constants of SOCl2,X– and SO2Cl2,X– were determined in acetonitrile. The standard enthalpies of formation point to weak association of a charge-transfer type. The nature of association

  SO之间1个复合物种类：1的形成2，的SOCl 2，SO 2氯2和Cl - ，溴- ，和L -报道。确定了SO 2 X –物质在乙腈，二甲基亚砜和水中的稳定性常数。的SOCl的稳定常数2，X -和SO 2氯2，X -在乙腈中测定。形成的标准焓指示电荷转移类型的弱缔合。配合物之间的酸碱特性讨论了配合物之间缔合的性质。
• Electrophotographic photosensitive member, a process-cartridge inclusive
  申请人：Canon Kabushiki Kaisha

  公开号：US05879847A1

  公开（公告）日：1999-03-09

  The present invention provides an electrophotographic photosensitive member having a substrate and a photosensitive layer thereupon, wherein a surface protecting layer of the photosensitive member contains a resin which is obtained by curing a curable organosilicon polymer and an organosilicon-modified positive hole transporting compound; a process-cartridge which has, in addition to the electrophotographic photosensitive member, at least one from among a primary charging means, a developing means, and a cleaning means placed into a housing, and which can be reversibly mounted to an image forming apparatus; and the image forming apparatus using the electrophotographic photosensitive member.

  本发明提供了一种电子照相感光体，其具有基板和感光层，其中感光体的表面保护层包含由可固化有机硅聚合物和有机硅改性的正空穴传输化合物固化而得的树脂；一种工艺盒，除了电子照相感光体外，还至少包括一个初级充电装置、一个显影装置和一个清洁装置，这些装置都放置在一个外壳内，可以可逆地安装到图像形成设备上；以及使用电子照相感光体的图像形成设备。
• Electrophotographic photosensitive member, a process-cartridge inclusive thereof, and an image forming apparatus
  申请人：Canon Kabushiki Kaisha

  公开号：US06296978B1

  公开（公告）日：2001-10-02

  The present invention provides an electrophotographic photosensitive member having a substrate and a photosensitive layer thereupon, wherein a surface layer of the photosensitive member contains a resin which is obtained by being subject to polycondensation as a monomer component only an organosilicon-modified positive hole transporting compound; a process cartridge which has, in addition to the electrophotographic photosensitive member, at least one from among a primary charging means, a developing means, and a cleaning means placed into a housing; and the image forming apparatus using the electrophotographic photosensitive member.

  本发明提供了一种电子照相感光元件，其具有基板和其上的感光层，其中感光元件的表面层包含一种树脂，该树脂通过仅将有机硅修饰的正电荷传输化合物作为单体组分进行聚合得到；一种过程盒，该过程盒除了具有电子照相感光元件外，还将至少一个从主要充电手段、显影手段和清洁手段中的一个放置在壳体中；以及使用电子照相感光元件的图像形成设备。
• ACTIVATING AGENT FOR PEROXISOME PROLIFERATOR ACTIVATED RECEPTOR
  申请人：Sakuma Shogo

  公开号：US20110098480A1

  公开（公告）日：2011-04-28

  A compound represented by the formula (I) or a pharmacologically acceptable salt thereof is used as an activator of PPAR. wherein each of R 1 and R 2 is hydrogen, C 1-8 alkyl, C 1-8 alkyl substituted with halogen, or the like; each of R 3 , R 4 , R 5 , and R 6 is hydrogen, C 1-8 alkyl, or the like; X is sulfur or the like; Y is oxygen, a bond, or the like; p is 0 or 1; A is oxygen, CH 2 , N—NH 2 , or the like; when p is 1, B is phenyl, which can have a substituent; when p is 0, B is a condensed ring such as benzisoxazole, which can have a substituent; m is an integer of 1 to 4; and n is an integer of 0 to 5.

  化合物(I)或其药理学上可接受的盐被用作PPAR的激活剂，其中R1和R2中的每一个都是氢、C1-8烷基、以卤素取代的C1-8烷基或类似物；R3、R4、R5和R6中的每一个都是氢、C1-8烷基或类似物；X是硫或类似物；Y是氧、键或类似物；p为0或1；A是氧、CH2、N—NH2或类似物；当p为1时，B是苯基，可以有取代基；当p为0时，B是类似苯并异噁唑的融合环，可以有取代基；m是1至4的整数；n是0至5的整数。