di(p-tolyl)(2-naphthyl)amine | 141388-60-5

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: di(p-tolyl)(2-naphthyl)amine
• 英文别名: (2-naphthyl)di(p-tolyl)amine；N,N-bis(4-methylphenyl)naphthalen-2-amine
• CAS: 141388-60-5
• 化学式: C₂₄H₂₁N
• 分子量: 323.437
• InChiKey: UEHFSSSMJZMPTB-UHFFFAOYSA-N

物化性质

• 沸点：
  499.9±34.0 °C(Predicted)
• 密度：
  1.125±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  7.1
• 重原子数：
  25
• 可旋转键数：
  3
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.08
• 拓扑面积：
  3.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  2-碘萘 、 4,4'-二甲基二苯胺 在 正丁基氯化镁 作用下， 以 2-甲基四氢呋喃 、 均三甲苯 为溶剂， 反应 75.0h， 以71%的产率得到di(p-tolyl)(2-naphthyl)amine
  参考文献：
  名称：

  酰胺化镁与碘化碘的电子催化偶联

  摘要：

  发现有一个电子催化二芳基酰胺镁与芳基碘化物的偶合，并通过自由基阴离子中间体产生三芳基胺。这种转变不需要过渡金属催化剂或添加剂，并且可以以优异的产率生产出各种各样的产品。

  DOI：

  10.1002/chem.201800011

文献信息

• Nickel-catalyzed triarylamine synthesis: synthetic and mechanistic aspects
  作者：Xin-Le Li、Wei Wu、Xin-Heng Fan、Lian-Ming Yang

  DOI：10.1039/c3ob42053a

  日期：——

  An improved protocol was described for the amination of chloroarenes with diarylamines under NiCl2(PCy3)2 catalysis in the presence of a Grignard reagent as base. This method fully suits bromo-/iodoarene substrates as well, and even is expanded to certain aryl tosylates. A preliminary investigation into the mechanism suggests that this amination reaction might proceed through NiI and NiIII intermediates rather than via the usually expected Ni0–NiII cycle.

  在以格氏试剂为碱的条件下，描述了一种在 NiCl2(PCy3)2 催化下将氯代烯烃与二芳基胺胺化的改进方案。这种方法也完全适用于溴/碘烯烃底物，甚至可以扩展到某些芳基对甲苯磺酸盐。对其机理的初步研究表明，这种胺化反应可能是通过 NiI 和 NiIII 中间体进行的，而不是通常预期的 Ni0-NiII 循环。
• COMPOSITE STRUCTURED ORGANIC FILMS
  申请人：HEUFT Matthew A.

  公开号：US20100227157A1

  公开（公告）日：2010-09-09

  A structured organic film with an added functionality comprising a plurality of segments and a plurality of linkers arranged as a covalent organic framework, wherein the structured organic film may be a multi-segment thick structured organic film.

  一种具有附加功能的有序有机薄膜，包括多个片段和多个连接剂，排列成共价有机框架，其中有序有机薄膜可以是多片段厚有序有机薄膜。
• Electrophotographic photoreceptor, electrophotographic photoreceptor cartridge, image forming apparatus, and polyarylate resin
  申请人：Mitsubishi Chemical Corporation

  公开号：US10185237B2

  公开（公告）日：2019-01-22

  An electrophotographic photoreceptor comprises a conductive support and, at least a photosensitive layer on the conductive support, wherein the photosensitive layer includes a polyarylate resin and the polyarylate resin has a repeating structure represented by formula (1), and the amount of bisphenol residues represented by formula (3) after the polyarylate resin is hydrolyzed, is 0.2% to 1%, in terms of intensity ratio, based on the total amount of bisphenol residues represented by formula (2) and formula (3) after the polyarylate resin is hydrolyzed, the bisphenol residues being detected with a gas chromatograph employing a hydrogen flame ionization detector (FID).

  一种电致发光感光器包括导电支架和至少位于导电支架上的感光层，其中感光层包括聚芳酸酯树脂，聚芳酸酯树脂具有由式(1)表示的重复结构，在聚芳酸酯树脂水解后，由式(3)表示的双酚残留物的量为0.以强度比计，在聚芳酯树脂水解后，以式(2)和式(3)表示的双酚残留物总量的基础上，双酚残留物的含量为 0.2%至 1%，双酚残留物用气相色谱仪检测，气相色谱仪采用氢火焰离子化检测器 (FID)。
• Electrophotographic photoreceptor and image forming apparatus
  申请人：Mitsubishi Chemical Corporation

  公开号：US10725391B2

  公开（公告）日：2020-07-28

  The present invention relates to an electrophotographic photoreceptor comprising: a conductive support; and a photosensitive layer disposed on the conductive support, wherein the photosensitive layer includes a polyester resin containing a dihydric phenol residue and a dicarboxylic acid residue, and the dihydric phenol residue includes at least one dihydric phenol residue selected from the group of the specific dihydric phenol residues, and the other specific dihydric phenol residue.

  本发明涉及一种电子照相感光器，包括：导电支架；以及设置在导电支架上的感光层，其中感光层包括含有二水酚残基和二羧酸残基的聚酯树脂，二水酚残基包括从特定二水酚残基和其他特定二水酚残基组中选出的至少一种二水酚残基。
• Electrophotographic photoreceptor, and electrophotographic cartridge and image forming apparatus including same
  申请人：Mitsubishi Chemical Corporation

  公开号：US10884348B2

  公开（公告）日：2021-01-05

  The present invention aims to provide an electrophotographic photoreceptor which is excellent in abrasion resistance against practical load and excellent in initial electrical properties, preferably further excellent in adhesion between layers by containing a polyester resin excellent in abrasion resistance, which is an electrophotographic photoreceptor containing a photosensitive layer and a conductive support, the electrophotographic photoreceptor containing a polyester resin having a specific structure α with a number average molecular weight of 15,000 or less and containing a divalent phenol residue and a divalent carboxylic acid residue.

  本发明的目的是提供一种电致发光感光体，该感光体具有优异的耐磨性和初始电性能，尤其是通过含有耐磨性优异的聚酯树脂而进一步提高了层间的附着力，该感光体是一种电致发光感光体，包含感光层和导电支架，该电致发光感光体含有一种聚酯树脂，该聚酯树脂具有特定结构α，其平均分子量在 15000 或以下，并含有二价苯酚残基和二价羧酸残基。