N-4-diethylaminosalicylidene-N'-4-nitrobenzoyl-hydrazine | 316133-62-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N-4-diethylaminosalicylidene-N'-4-nitrobenzoyl-hydrazine
• 英文别名: N-4-diethylaminosalicylidene-N'-nitrobenzoyl hydrazine；N-[[4-(diethylamino)-2-hydroxyphenyl]methylideneamino]-4-nitrobenzamide
• CAS: 316133-62-7
• 化学式: C₁₈H₂₀N₄O₄
• mdl: MFCD00368884
• 分子量: 356.381
• InChiKey: XZLNLOGXVHIPRF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.2
• 重原子数：
  26
• 可旋转键数：
  6
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.22
• 拓扑面积：
  111
• 氢给体数：
  2
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  N-4-diethylaminosalicylidene-N'-4-nitrobenzoyl-hydrazine 在 sodium acetate 、 KOH 作用下， 以 四氢呋喃 、 吡啶 为溶剂， 生成 (pyridine)Pd(N-4-diethylaminosalicylidene-N'-4-nitrobenzoyl-hydrazine)
  参考文献：
  名称：

  Synthesis, Structure, and Second-Order Nonlinear Optical Properties of Copper(II) and Palladium(II) Acentric Complexes with N-Salicylidene-N ‘-aroylhydrazine Tridentate Ligands

  摘要：

  Two new N-salicylidene-N'-aroylhydrazines ligands have been prepared: N-4-diethylaminosalicylidene-N'-4-nitrobenzoyl-hydrazine (L-1) and N-4-diethylaminosalicylidene-N'-4-(4-nitrophenylethylidene)-benzoyl-hydrazine (L-2). The ligands are properly functionalized with strong electron donor-acceptor groups and are of potential interest in second-order nonlinear optics (NLO), Dimeric copper(II) and palladium(II) complexes with L-1 and L-2 have been prepared, and, starting from these, mononuclear acentric adducts with pyridine as a further ligand have been prepared and characterized. The X-ray structures of three adducts are also reported. The NLO activity of the adducts has been determined by EFISH measurements giving mubeta values up to 1500 x 10(-48) esu for an incident wavelength of 1.907 mum.

  DOI：

  10.1021/ic020127k

文献信息

• Six-coordinate monooxo molybdenum(VI) complexes with N-4-diethylaminosalicylidene-N′-4-nitrobenzoyl hydrazine and catechol ligands: preparation and spectroscopic properties
  作者：Jalal U. Mondal、Elky Almaraz、Narayan G. Bhat

  DOI：10.1016/j.inoche.2004.08.022

  日期：2004.11

  Abstract Preparation and spectroscopic characterization are reported for monooxo molybdenum(VI) complexes, MoO(cat)L, where L 2− = dianion of N -4-diethylaminosalicylidene- N ′-4-nitrobenzoyl hydrazine and cat 2− = catecholate (Cat 2− ), 4-methylcatecholate (Mecat 2− ), 3,5-di- tert -butylcatecholate (DTBcat 2− ), or 4-nitrocatecholate (NO 2 cat 2− ). The compounds were prepared by replacement of an

  摘要 报道了单氧代钼 (VI) 配合物 MoO(cat)L 的制备和光谱表征，其中 L 2− = N -4-二乙氨基水杨基-N '-4-硝基苯甲酰肼的二价阴离子和 cat 2− = 儿茶酚酸盐（Cat 2 − )、4-甲基儿茶酚酸盐 (Mecat 2− )、3,5-二叔丁基儿茶酚酸盐 (DTBcat 2− ) 或 4-硝基儿茶酚酸盐 (NO 2 cat 2− )。通过用邻苯二酚替换MoO 2 L 上的氧代基团来制备化合物。MoO(cat)L 配合物在 935-938 cm -1 处表现出 Mo O 伸缩振动 ( ν Mo O ) 和一系列在 UV-Vis 区域的五个吸收，包括在 655-658 nm 的长波长带归因于 cat → Mo 电荷转移。报告了 1 H 和 13 C NMR 数据，发现与单体 MoO(cat)L 化合物的形成一致。