1,1,3,5,5,7-hexaphenoxy-3,7-dichlorocyclotetraphosphazene | 344416-23-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1,1,3,5,5,7-hexaphenoxy-3,7-dichlorocyclotetraphosphazene
• 英文别名: 2,6-dichlorohexaphenoxycyclotetraphosphazene；2,6-Dichloro-2,4,4,6,8,8-hexaphenoxy-1,3,5,7-tetraza-2lambda5,4lambda5,6lambda5,8lambda5-tetraphosphacycloocta-1,3,5,7-tetraene；2,6-dichloro-2,4,4,6,8,8-hexaphenoxy-1,3,5,7-tetraza-2λ5,4λ5,6λ5,8λ5-tetraphosphacycloocta-1,3,5,7-tetraene
• CAS: 344416-23-5
• 化学式: C₃₆H₃₀Cl₂N₄O₆P₄
• 分子量: 809.458
• InChiKey: LCRKCBJCMSOXAM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  13.5
• 重原子数：
  52
• 可旋转键数：
  12
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  105
• 氢给体数：
  0
• 氢受体数：
  10

反应信息

• 作为产物：
  描述：

  sodium phenoxide 在 octachlorocyclotetraphosphazene 作用下， 以 丙酮 为溶剂， 生成 2,4,6-trichloro-2-cis-4-trans-6,8,8-pentaphenoxycyclotetraphosphazene 、 2,4-dichlorohexaphenoxycyclotetraphosphazene 、 1,1,3,5,5,7-hexaphenoxy-3,7-dichlorocyclotetraphosphazene
  参考文献：
  名称：

  Dhathathreyan, Kaveripatnam S.; Krishnamurthy, Setharmpattu S.; Woods, Michael, Journal of the Chemical Society, Dalton Transactions, 1982, p. 2151 - 2158

  摘要：

  DOI：

文献信息

• Structural and chemosensor properties of FDA and FDP derivatives of fluorenylidene bridged cyclotetraphosphazenes
  作者：Elif Şenkuytu、Gönül Yenilmez Çiftçi

  DOI：10.1016/j.poly.2016.04.046

  日期：2016.9

  The first series of 4,4'-(9-fluorenylidene)diphenol (FDP) (5) and 4,4'-(9-fluorenylidene)dianiline (FDA) (6) bridged and open chained cyclotetraphosphazene derivatives (15-23) have been synthesized. Their florescence and chemosensor properties are reported. Nucleophilic substitution reactions of octachlorocyclotetraphosphazene (1) with mono-functional reagents [phenol (2), 2-naphthol (3) and 1-hydroxypyrene (4)] were carried out and the heptasubstituted derivatives (8, 11 and 14) were obtained. Then the reactions of 8, 11 and 14 with 4,4'-(9-fluorenylidene)diphenol (FDP) (5) and 4,4'-(9-fluorenylidene)dianiline (FDA) (6), respectively gave bridged and open chained compounds. The structures of the synthesized compounds (7-23) were verified by elemental analyses, mass spectrometry, DV Vis, H-1 and P-31 NMR techniques and fluorescence spectroscopy. The metal sensing properties of the novel bridged open chain cyclotetraphosphazene derivatives were also examined by fluorescence spectroscopy. These complexes showed high selectivity for Cu2+ and Fe3+ ions in solution. (C) 2016 Elsevier Ltd. All rights reserved.
• DHATHATHREYAN, KAVERIPATNAM, S.;KRISHNAMURTHY, SETHARMPATTU, S.;WOODS, M., J. CHEM. SOC. DALTON TRANS., 1982, N 11, 2151-2157
  作者：DHATHATHREYAN, KAVERIPATNAM, S.、KRISHNAMURTHY, SETHARMPATTU, S.、WOODS, M.

  DOI：——

  日期：——
• Dhathathreyan, Kaveripatnam S.; Krishnamurthy, Setharmpattu S.; Woods, Michael, Journal of the Chemical Society, Dalton Transactions, 1982, p. 2151 - 2158
  作者：Dhathathreyan, Kaveripatnam S.、Krishnamurthy, Setharmpattu S.、Woods, Michael

  DOI：——

  日期：——