3-cyclopropylnorcarane | 89914-06-7

• 分子结构分类: 有机化合物 - 碳氢化合物 - 多环烃
• 英文名称: 3-cyclopropylnorcarane
• 英文别名: 3-Cyclopropyl-norcaran；Bicyclo[4.1.0]heptane, 3-cyclopropyl-；3-cyclopropylbicyclo[4.1.0]heptane
• CAS: 89914-06-7
• 化学式: C₁₀H₁₆
• 分子量: 136.237
• InChiKey: SDTZGGLOOGQXTC-UHFFFAOYSA-N

物化性质

• 沸点：
  40 °C(Press: 10 Torr)
• 密度：
  0.8967 g/cm3

计算性质

• 辛醇/水分配系数(LogP)：
  3.8
• 重原子数：
  10
• 可旋转键数：
  1
• 环数：
  3.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  4-乙烯基-1-环己烯 、 重氮甲烷 以65%的产率得到
  参考文献：
  名称：

  TOMILOV, YU. V.;BORDAKOV, V. G.;DOLGIJ, I. E.;NEFEDOV, O. M., IZV. AN CCCP. CEP. XIM., 1984, N 3, 582-588

  摘要：

  DOI：

文献信息

• Regioselective Simmons–Smith-type cyclopropanations of polyalkenes enabled by transition metal catalysis
  作者：Jacob Werth、Christopher Uyeda

  DOI：10.1039/c7sc04861k

  日期：——

  A cobalt catalyst imparts a high degree of regioselectivity in the reductive cyclopropanation of polyalkenes.

  一种钴催化剂在多烯的还原环丙烷化反应中赋予高度的位置选择性。
• Reaction of diazoalkanes with unsaturated compounds Communication 1. Cyclopropanation of olefins with diazomethane in the presence of copper compounds
  作者：O. M. Nefodov、I. E. Dolgii、Yu. V. Tomilov、V. G. Bordakov

  DOI：10.1007/bf00956238

  日期：1984.1
• Synthesis of Polycyclic Hydrocarbons Containing Cyclopropyl Groups¹
  作者：STANLEY D. KOCH、ROBERT M. KLISS、DOLORES V. LOPIEKES、ROBERT J. WINEMAN

  DOI：10.1021/jo01067a019

  日期：1961.9
• Regioselectivity and solvent effects in cyclopropanation of alkadienes
  作者：Edwin C. Friedrich、Fatemeh Niyati-Shirkhodaee

  DOI：10.1021/jo00006a044

  日期：1991.3

  A comparison of the regioselectivities for monocyclopropanation of limonene and 4-vinylclohexene using diiodomethane with zinc dust and copper(I) chloride in ether, with diethylzinc in toluene, or with triethylaluminum in toluene-dichloromethane has been carried out. Some studies were also done using dibromomethane with zinc dust and copper(I) chloride in ether. The procedure using diethylzinc in toluene exhibited the least steric hindrance toward cyclopropanation at more highly substituted, electron-rich double bonds. In a study of solvent effects on the diiodomethane, zinc dust, and copper(I) chloride procedure, use of diisopropyl ether as a reaction solvent proved to be a satisfactory method for almost doubling the steric requirements of the cyclopropanating reagent.
• Reaction of diazoalkanes with unsaturated compounds. Communication 2. Cyclopropanation of olefins by diazomethane in the presence of palladium compounds
  作者：Yu. V. Tomilov、V. G. Bordakov、I. E. Dolgii、O. M. Nefedov

  DOI：10.1007/bf00995691

  日期：1984.3