Isopropylidene-octyl-amine | 57368-74-8

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: Isopropylidene-octyl-amine
• 英文别名: N-octylpropan-2-imine
• CAS: 57368-74-8
• 化学式: C₁₁H₂₃N
• 分子量: 169.31
• InChiKey: SJMRCIJIMPIGCR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.5
• 重原子数：
  12
• 可旋转键数：
  7
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.91
• 拓扑面积：
  12.4
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  Isopropylidene-octyl-amine 在 盐酸 作用下， 以 水 为溶剂， 生成 辛胺盐酸盐
  参考文献：
  名称：

  Transfer Hydrogenation of Nitriles with 2-Propanol and Raney® Nickel

  摘要：

  Raney nickel in refluxing 2-propanol containing 2% KOH is an effective catalytic system for reducing nitriles to amines.

  DOI：

  10.1081/scc-120023995
• 作为产物：
  描述：

  正辛腈 、 异丙醇 在 镍 氢氧化钾 作用下， 反应 3.0h， 生成 Isopropylidene-octyl-amine
  参考文献：
  名称：

  Transfer Hydrogenation of Nitriles with 2-Propanol and Raney® Nickel

  摘要：

  Raney nickel in refluxing 2-propanol containing 2% KOH is an effective catalytic system for reducing nitriles to amines.

  DOI：

  10.1081/scc-120023995

文献信息

• Tuneable Hydrogenation of Nitriles into Imines or Amines with a Ruthenium Pincer Complex under Mild Conditions
  作者：Jong-Hoo Choi、Martin H. G. Prechtl

  DOI：10.1002/cctc.201403047

  日期：2015.3

  selective hydrogenation of aromatic and aliphatic nitriles into amines and imines is described. Using a ruthenium pincer complex, the selectivity towards amines or imines can be controlled by simple parameter changes. The reactions are conducted under very mild conditions between 50–100 °C at 0.4 MPa H2 pressure without any additives at low catalytic loadings of 0.5–1 mol %, which results in quantitative conversions

  描述了将芳族和脂族腈选择性氢化为胺和亚胺的方法。使用钌钳配合物，可以通过简单的参数更改来控制对胺或亚胺的选择性。反应在0.4 MPa H 2压力下在50-100°C的非常温和的条件下进行，在0.5-1 mol％的低催化负载下没有任何添加剂，从而实现了定量转化和高选择性。
• Photoluminescent organic material
  申请人：Wu Jau-Yann

  公开号：US09061969B2

  公开（公告）日：2015-06-23

  A compound of formula (I) is disclosed: wherein definitions of R1, R2, and R3 are the same as those defined in the specification. The compound of formula (I) can emit light via an intramolecular interaction of an imino group and an electron-donatable moiety contained in the compound. A photoluminescent organic composition is also disclosed, which includes a compound represented by formula (II) in the presence of an electron-donatable compound, wherein definitions of R4, R5, and R6 are the same as those defined in the specification. The photoluminescent organic composition can emit light via an intermolecular interaction of an imino group contained in the compound of formula (II) and an electron-donatable moiety contained in the electron-donatable compound.

  公开了一种化合物的化学式(I)，其中R1、R2和R3的定义与说明书中定义的相同。化合物(I)可以通过分子内亚胺基和化合物中含有的电子供体基团的相互作用发射光。还公开了一种光致发光有机组合物，其中包括在电子供体化合物的存在下，由化学式(II)表示的化合物，其中R4、R5和R6的定义与说明书中定义的相同。光致发光有机组合物可以通过化合物(II)中含有的亚胺基和电子供体化合物中含有的电子供体基团的相互作用发射光。
• SYNTHESIS AND PHYSIOLOGICAL ACTIVITIES OF NEW ACYCLIC AMINOPHOSPHONATES
  作者：J. S. Wieczorek、R. Gancarz、K. Bielecki、E. Grzyś、J. Sarapuk

  DOI：10.1080/10426500008076535

  日期：2000.1.1

  The dependence of biological activity of 37 newly synthesized acyclic aminomethanephosphonic acid derivatives on their structure was studied. It was found that the phytotoxicity of the compounds studied depended on their hydrophobic parameters, and in a smaller extent on the electronic parameters of the substituents on nitrogen and phosphorus atoms. No phytotoxicity dependence on the steric parameters of compounds was found. Tested organism was Spirodela oligorrhiza and the parameter studied was the concentration of compounds causing 50 % growth inhibition (EC50) The test had preliminary character and permitted to eliminate the less promising compounds out of further studies.
• US4139560A
  申请人：——

  公开号：US4139560A

  公开（公告）日：1979-02-13
• US4357476A
  申请人：——

  公开号：US4357476A

  公开（公告）日：1982-11-02