Anthrachinon-1,2,3-trisulfonsaeure | 802287-49-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: Anthrachinon-1,2,3-trisulfonsaeure
• 英文别名: 9,10-Dioxoanthracene-1,2,3-trisulfonic acid；9,10-dioxoanthracene-1,2,3-trisulfonic acid
• CAS: 802287-49-6
• 化学式: C₁₄H₈O₁₁S₃
• 分子量: 448.409
• InChiKey: PDKNKWRYRJPPPO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.9
• 重原子数：
  28
• 可旋转键数：
  3
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  222
• 氢给体数：
  3
• 氢受体数：
  11

反应信息

• 作为产物：
  描述：

  硫酸 、 1-蒽醌磺酸 生成 9,10-二氢-9,10-二氧代蒽-1,7-二磺酸 、 Anthrachinon-1,2,3-trisulfonsaeure
  参考文献：
  名称：

  DE170329

  摘要：

  公开号：

文献信息

• OXIDANT/DOPANT SOLUTION FOR PRODUCING CONDUCTIVE POLYMER, CONDUCTIVE POLYMER AND SOLID ELECTROLYTIC CAPACITOR
  申请人：Tayca Corporation

  公开号：EP2479201A1

  公开（公告）日：2012-07-25

  There is provided an oxidant and dopant which can produce a conductive polymer. The conductive polymer can be used in a solid electrolyte capacitor as solid electrolyte. The solid electrolyte capacitor can be provided with improved breakdown voltage and voltage resistance, as well as less generation of the defects due to leak current. There is provided an oxidant and dopant solution for conductive polymer production including an oxidant and dopant for an organic ferric sulfonate, and an alcohol with a carbon number of 1 to 4. The oxidant and dopant solution further includes a compound with a glycidyl group, or its ring-opened compound. Faborably, a polyalcohol is further added. Using the oxidant and dopant solution, a thiophene or its derivative is subject to an oxidation polymerization to prepare a conductive polymer, which can be used as solid electrolyte of a solid electrolyte capacitor.

  提供了一种氧化剂和掺杂剂，可生成导电聚合物。该导电聚合物可用作固体电解质电容器的固体电解质。固体电解质电容器的击穿电压和耐压性能得到改善，泄漏电流导致的缺陷也会减少。本发明提供了一种用于导电聚合物生产的氧化剂和掺杂剂溶液，其中包括一种有机磺酸铁氧化剂和掺杂剂，以及一种碳原子数为 1 至 4 的醇，氧化剂和掺杂剂溶液还包括一种具有缩水甘油基的化合物或其环开化合物。当然，还可以进一步加入多元醇。利用氧化剂和掺杂剂溶液，对噻吩或其衍生物进行氧化聚合，制备出导电聚合物，该聚合物可用作固体电解质电容器的固体电解质。
• CONDUCTIVE POLYMER AND SOLID-ELECTROLYTE CAPACITOR INCLUDING SAME AS SOLID ELECTROLYTE
  申请人：Tayca Corporation

  公开号：EP2508547A1

  公开（公告）日：2012-10-10

  There is provided a conductive polymer having a high electrical conductivity and an excellent heat resistance. Using it as a solid electrolyte, there is provided a solid electrolyte capacitor having a low ESR and a large capacitance with good reliability under a hot condition. A monomer mixture of 2,3-dihydro-thieno [3,4-b] [1,4] dioxine and 2-alkyl -2,3-dihydro-thieno [3,4-b] [1,4] dioxine at a mixture ratio of 0.05:1 1 to 1:0.1 by the molar ratio is polymerized in the presence of an organic sulfonic acid, and the organic sulfonic acid is included as a dopant. As the 2-alkyl -2,3-dihydro-thieno [3,4-b] [1,4] dioxine, the alkyl portion can be methyl, ethyl, propyl or butyl.

  本发明提供了一种导电聚合物，它具有高导电性和出色的耐热性。本发明提供了一种固体电解质电容器，将其用作固体电解质，在高温条件下具有较低的 ESR 和较大的电容，且可靠性良好。2,3- 二氢-噻吩并[3,4-b] [1,4] 二恶烷和 2- 烷基-2,3-二氢-噻吩并[3,4-b] [1,4] 二恶烷的单体混合物按摩尔比为 0.05:1 1 至 1:0.1 的混合比在有机磺酸存在下聚合，有机磺酸作为掺杂剂加入。作为 2-烷基-2,3-二氢噻吩并[3,4-b][1,4]二恶烷，烷基部分可以是甲基、乙基、丙基或丁基。
• Oxidant dopant agent for conductive polymer production, and a solution thereof, and a conductive polymer prepared by using either of them, as well as an electrolyte capacitor using the conductive polymer as an electrolyte
  申请人：TAYCA CORPORATION

  公开号：US10208160B2

  公开（公告）日：2019-02-19

  There is provided an oxidant dopant agent for conductive polymer production, and a solution thereof, in which they are capable of producing a conductive polymer suitable in producing an electrolyte capacitor having a low leak current. There is also provided a conductive polymer prepared by using either of them. There is also provided an electrolyte capacitor having a low leak current. The oxidant dopant agent includes: an organic ferric sulfonate; and at least one kind selected from the group consisting of phosphoric acid, phosphate, phosphorous acid, phosphite, boric acid, borate, thiophosphoric acid, thiophosphate, dithiophosphoric acid and dithiophosphate. The solution includes the oxidant dopant agent dissolved in water, an alcohol or a mixture of water and an alcohol. A conductive polymer is prepared by means of oxidation polymerization of a monomer such as thiophene or its derivative. The conductive polymer is used as an electrolyte to provide an electrolyte capacitor.

  本发明提供了一种用于生产导电聚合物的氧化剂掺杂剂及其溶液，它们能够生产导电聚合物，适用于生产泄漏电流较低的电解质电容器。此外，还提供了使用其中任一种制备的导电聚合物。还提供了一种具有低泄漏电流的电解质电容器。氧化剂掺杂剂包括：有机铁磺酸盐；以及至少一种选自磷酸、磷酸盐、磷酸、亚磷酸盐、硼酸、硼酸盐、硫代磷酸、硫代磷酸、二硫代磷酸和二硫代磷酸组成的组。溶液包括溶解在水、醇或水与醇混合物中的氧化剂掺杂剂。导电聚合物是通过单体（如噻吩或其衍生物）的氧化聚合而制备的。导电聚合物用作电解质，以提供电解质电容器。
• Method for preparing an electrolyte capacitor
  申请人：TAYCA CORPORATION

  公开号：US10336859B2

  公开（公告）日：2019-07-02

  The method for preparing an electrolyte capacitor includes: providing an oxidant dopant agent for preparing the conductive polymer including: ferric naphthalenesulfonate; and at least one compound selected from the group consisting of phosphate, phosphite, borate, thiophosphate, and dithiophosphate. The method also includes preparing a conductive polymer by using the oxidant dopant agent to obtain an electrolyte comprising the conductive polymer.

  制备电解质电容器的方法包括：提供用于制备导电聚合物的氧化剂掺杂剂，包括：萘磺酸铁；以及至少一种选自磷酸盐、亚磷酸盐、硼酸盐、硫代磷酸盐和二硫代磷酸盐的化合物。该方法还包括使用氧化剂掺杂剂制备导电聚合物，以获得包含导电聚合物的电解液。
• Meyer,A., Bulletin de la Societe Chimique de France, 1927, vol. <4> 41, p. 1627,1638
  作者：Meyer,A.

  DOI：——

  日期：——