N-(4,5-Dimethyl-2-oxo-1,3-diphenyl-2,3-dihydro-1H-2λ⁵-[1,3,2]diazaphosphol-2-yl)-N-ethyl-benzene-1,2-diamine | 133490-55-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N-(4,5-Dimethyl-2-oxo-1,3-diphenyl-2,3-dihydro-1H-2λ⁵-[1,3,2]diazaphosphol-2-yl)-N-ethyl-benzene-1,2-diamine
• 英文别名: 2-N-(4,5-dimethyl-2-oxo-1,3-diphenyl-1,3,2lambda5-diazaphosphol-2-yl)-2-N-ethylbenzene-1,2-diamine；2-N-(4,5-dimethyl-2-oxo-1,3-diphenyl-1,3,2λ5-diazaphosphol-2-yl)-2-N-ethylbenzene-1,2-diamine
• CAS: 133490-55-8
• 化学式: C₂₄H₂₇N₄OP
• 分子量: 418.478
• InChiKey: FLVBUXSKFIGIAF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.6
• 重原子数：
  30
• 可旋转键数：
  5
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.17
• 拓扑面积：
  52.8
• 氢给体数：
  1
• 氢受体数：
  5

反应信息

• 作为产物：
  描述：

  9'-ethyl-4,5-dimethyl-1,3-diphenylspiro[1,3-diaza-2λ5-phosphacyclopent-4-ene-2,8'-7,9-diaza-8λ5-phosphabicyclo[4.3.0]nona-1,3,5,7-tetraene] 在 水 作用下， 生成 N-(4,5-Dimethyl-2-oxo-1,3-diphenyl-2,3-dihydro-1H-2λ⁵-[1,3,2]diazaphosphol-2-yl)-N-ethyl-benzene-1,2-diamine
  参考文献：
  名称：

  Spirophosphazenes and the parent triazaphosphole : differences and similarity in chemical reactivity

  摘要：

  The first step of hydrolysis of compounds 1,2 and 4 involves the protonation of the P = N nitrogen atom. 3 does not react with water in the absence of a catalyst. Protonation of compounds 1-3 by a strong acid such as CF3SO3H is studied by N-15 and P-31 nmr spectroscopy. In all cases the P = N nitrogen appears to be the strongest basic site.

  DOI：

  10.1016/s0040-4039(00)79479-2

文献信息

• Spirophosphazenes and the parent triazaphosphole : differences and similarity in chemical reactivity
  作者：O.S. Diallo、L. Lopez、J. Barrans

  DOI：10.1016/s0040-4039(00)79479-2

  日期：1991.1

  The first step of hydrolysis of compounds 1,2 and 4 involves the protonation of the P = N nitrogen atom. 3 does not react with water in the absence of a catalyst. Protonation of compounds 1-3 by a strong acid such as CF3SO3H is studied by N-15 and P-31 nmr spectroscopy. In all cases the P = N nitrogen appears to be the strongest basic site.