9'-ethyl-4,5-dimethyl-1,3-diphenylspiro[1,3-diaza-2λ5-phosphacyclopent-4-ene-2,8'-7,9-diaza-8λ5-phosphabicyclo[4.3.0]nona-1,3,5,7-tetraene] | 107317-50-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 三嗪类
• 英文名称: 9'-ethyl-4,5-dimethyl-1,3-diphenylspiro[1,3-diaza-2λ5-phosphacyclopent-4-ene-2,8'-7,9-diaza-8λ5-phosphabicyclo[4.3.0]nona-1,3,5,7-tetraene]
• CAS: 107317-50-0
• 化学式: C₂₄H₂₅N₄P
• 分子量: 400.463
• InChiKey: DNWQXOAPFYZKFC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.38
• 重原子数：
  29.0
• 可旋转键数：
  3.0
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.17
• 拓扑面积：
  22.08
• 氢给体数：
  0.0
• 氢受体数：
  4.0

反应信息

• 作为反应物：
  描述：

  9'-ethyl-4,5-dimethyl-1,3-diphenylspiro[1,3-diaza-2λ5-phosphacyclopent-4-ene-2,8'-7,9-diaza-8λ5-phosphabicyclo[4.3.0]nona-1,3,5,7-tetraene] 在 水 作用下， 生成 N-(4,5-Dimethyl-2-oxo-1,3-diphenyl-2,3-dihydro-1H-2λ⁵-[1,3,2]diazaphosphol-2-yl)-N-ethyl-benzene-1,2-diamine
  参考文献：
  名称：

  Spirophosphazenes and the parent triazaphosphole : differences and similarity in chemical reactivity

  摘要：

  The first step of hydrolysis of compounds 1,2 and 4 involves the protonation of the P = N nitrogen atom. 3 does not react with water in the absence of a catalyst. Protonation of compounds 1-3 by a strong acid such as CF3SO3H is studied by N-15 and P-31 nmr spectroscopy. In all cases the P = N nitrogen appears to be the strongest basic site.

  DOI：

  10.1016/s0040-4039(00)79479-2
• 作为产物：
  描述：

  1,4-diphenyl-2,3-dimethyl-1,4-diazabutadiene 、 9,12,27,30-tetraethyl-1,2,9,12,19,20,27,30-octaza-10,11,28,29-tetraphosphanonacyclo[27.7.0.02,10.03,8.011,19.013,18.020,28.021,26.031,36]hexatriaconta-3,5,7,13,15,17,21,23,25,31,33,35-dodecaene 生成 9'-ethyl-4,5-dimethyl-1,3-diphenylspiro[1,3-diaza-2λ5-phosphacyclopent-4-ene-2,8'-7,9-diaza-8λ5-phosphabicyclo[4.3.0]nona-1,3,5,7-tetraene]
  参考文献：
  名称：

  DIALLO O.; BOISDON M. T.; LOPEZ L.; MALAVAUD C.; BARRANS J., TETRAHEDRON LETT., 27,(1986) N 26, 2971-2974

  摘要：

  DOI：

文献信息

• Composes du phosphore dicoordonne: Reaction de diaza-1,4 dienes-1,3 disubstitues sur les derives de diazaphosphole. Du triazaphosphole-1,2,4,3 et de precurseurs de composes du phosphore dicoordonne
  作者：O Diallo、M.T Boisdon、L Lopez、C Malavaud、J Barrans

  DOI：10.1016/s0040-4039(00)84693-6

  日期：1986.1

  Addition of diazadienes to dicoordinated phosphorus derivatives such as triazaphospholes or diazaphospholes leads to new tetracoordinated phosphorus spirocompounds or .

  diazadienes的加成到dicoordinated磷衍生物，例如triazaphospholes或diazaphospholes导致新四配磷spirocompounds或。