N-n-dodecylamino-1-anthraquinone | 29957-03-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: N-n-dodecylamino-1-anthraquinone
• 英文别名: 1-dodecylamino-anthraquinone；1-Dodecylamino-anthrachinon；1-(Dodecylamino)anthracene-9,10-dione
• CAS: 29957-03-7
• 化学式: C₂₆H₃₃NO₂
• 分子量: 391.554
• InChiKey: RPAYWEKSUYVFBC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  9.5
• 重原子数：
  29
• 可旋转键数：
  12
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.46
• 拓扑面积：
  46.2
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  N-n-dodecylamino-1-anthraquinone 在 吡啶 、 溴 作用下， 生成 1-bromo-4-dodecylamino-anthraquinone
  参考文献：
  名称：

  NITROANTHRAPYRIDONES

  摘要：

  DOI：

  10.1021/jo01182a016
• 作为产物：
  描述：

  十二烷基伯胺 、 1-氯蒽醌 在 吡啶 作用下， 生成 N-n-dodecylamino-1-anthraquinone
  参考文献：
  名称：

  NITROANTHRAPYRIDONES

  摘要：

  DOI：

  10.1021/jo01182a016

文献信息

• Sensitive fluorescent vesicles based on the supramolecular inclusion of β-cyclodextrins with<i>N</i>-alkylamino-<scp>l</scp>-anthraquinone
  作者：Tao Sun、Huacheng Zhang、Hui Yan、Jianye Li、Guanghui Cheng、Aiyou Hao、Hongwei Qiao、Feifei Xin

  DOI：10.1080/10610278.2010.514614

  日期：2011.5.1

  Self-assembly fluorescent vesicles were designed and prepared based on the supramolecular interaction of cyclodextrins and N-alkylamino-l-anthraquinone (n-AQ). As the guest molecules, n-AQs with alkyl lengths ranging from C0 to C18 were synthesised by the direct reaction of alkylamine with l-nitroanthraquinone in N,N-dimethylformamide. Transmission electron microscopy (TEM), scanning electron microscopy, dynamic light scattering and epi fluorescence microscopy were employed to study the vesicle system in detail. The formation mechanism of the vesicles was suggested based on the results of TEM observation, UV spectrum, fluorescence spectrum, 1H NMR and simulation in the software Materials 4.3. The fluorescent vesicles show sensitive and multi-responsive properties to external stimuli. Based on these properties, we tried to use the vesicle as a new kind of fluorescence staining material for living cells. The vesicles can effectively stain the human breast cancer cells (MCF-7) and mice mononuclear macrophages (REW-264.7). This paper provides a better understanding in the design and preparation of drug delivery, biomaterials and intelligent materials.
• NITROANTHRAPYRIDONES
  作者：C. F. H. ALLEN、C. V. WILSON

  DOI：10.1021/jo01182a016

  日期：1945.11