Phenylphosphonsaeure-mono-sec-butylester | 13399-76-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Phenylphosphonsaeure-mono-sec-butylester
• 英文别名: Phenylphosphonsaeure-sek.-butyl-ester；Butan-2-yloxy(phenyl)phosphinic acid；butan-2-yloxy(phenyl)phosphinic acid
• CAS: 13399-76-3
• 化学式: C₁₀H₁₅O₃P
• 分子量: 214.201
• InChiKey: NBYGUTRDALTRPS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.8
• 重原子数：
  14
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  46.5
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  苯膦酰二氯 在 吡啶 、 氢氧化钾 作用下， 生成 Phenylphosphonsaeure-mono-sec-butylester
  参考文献：
  名称：

  Conformation of Organophosphorus Compounds. II. Proton Magnetic Resonance Studies of Some Phosphites, Phosphonites, Phosphates, Phosphonates and Additional Phosphinates

  摘要：

  DOI：

  10.1021/ja00877a010

文献信息

• Production process of 2- chloropropionaldehyde
  申请人：MITSUI TOATSU CHEMICALS, Inc.

  公开号：EP0260944A1

  公开（公告）日：1988-03-23

  A process for the production of 2-chloropropionaldehyde from vinyl chloride, carbon monoxide and hydrogen which comprises using a rhodium compound and a trivalent organic phosphorus compound or the oxide of a trivalent organic phosphorus compound as a catalyst and carrying out the reaction under the co-existence of an acid the pka of which is in the range of 0.5 - 5, the oxide, hydroxide or a weak acid salt of an alkali metal or alkaline earth metal, or a buffer solution.

  一种从氯乙烯、一氧化碳和氢气制取 2-氯丙醛的工艺，包括使用铑化合物和三价有机磷化合物或三价有机磷化合物的氧化物作为催化剂，并在 pka 值在 0.5 - 5 之间的酸、碱金属或碱土金属的氧化物、氢氧化物或弱酸盐或缓冲溶液共存的条件下进行反应。
• POLYESTER AMIDE COMPOUND
  申请人：Mitsubishi Gas Chemical Company, Inc.

  公开号：EP2573127A1

  公开（公告）日：2013-03-27

  A polyester amide compound having a polycarboxylic acid unit in an amount of 25 to 50 mol%, the polycarboxylic acid unit containing an aromatic dicarboxylic acid unit represented by the following formula (I) in an amount of 70 mol% or more; a polyhydric alcohol unit in an amount of 25 to 50 mol%, the polyhydric alcohol unit containing an aliphatic diol unit represented by the following formula (II) in an amount of 70 mol% or more; and a structural unit represented by the following formula (III) in an amount of 0.1 to 50 mol%: wherein, in formula (I), Ar represents an arylene group; in formula (II), X represents a C2 to C20 alkylene group; and in formula (III), R represents a substituted or unsubstituted alkyl group or a substituted or unsubstituted aryl group.

  一种聚酯酰胺化合物，其聚羧酸单元的用量为 25 至 50 摩尔%，该聚羧酸单元含有下式 (I) 所代表的芳香族二羧酸单元，用量为 70 摩尔%或以上；聚醇单元的用量为 25 至 50 摩尔%，该聚醇单元含有下式 (II) 所代表的脂肪族二醇单元，用量为 70 摩尔%或以上；以及下式 (III) 所代表的结构单元，用量为 0.1 至 50 摩尔%： 其中，在式 (I) 中，Ar 代表芳烯基；在式 (II) 中，X 代表 C2 至 C20 亚烷基；在式 (III) 中，R 代表取代或未取代的烷基或取代或未取代的芳基。
• BIAXIALLY ORIENTED POLYESTER FILM AND METHOD FOR PRODUCING SAME
  申请人：TOYOBO CO., LTD.

  公开号：EP4079491A1

  公开（公告）日：2022-10-26

  A biaxially oriented polyester film having excellent impact strength and heat resistance and a method for producing same are provided. A method for producing biaxially stretched polyester film comprising Operation A through Operation D, below. Operation A: Operation in which composition comprising polyester resin for which Tc - (Tg + Tm)/2 is not less than 25° C but not greater than 30° C is melt extruded to obtain unstretched polyester resin composition sheet. Operation B: Operation in which the unstretched polyester resin composition sheet obtained at Operation A is heated so as to be within the range not less than Tg + 5 (° C) of the polyester resin but not greater than Tg + 40 (° C) of the polyester resin, and this is stretched so that the stretching ratio in the machine direction is within the range not less than 2x but not greater than 6x to obtain uniaxially oriented polyester resin composition film. Operation C: Operation in which the uniaxially oriented polyester resin composition film obtained at Operation B is heated so as to be within the range not less than Tc - 46 (° C) of the polyester resin but not greater than Tc + 25 (° C) of the polyester resin, and this is stretched so that the stretching ratio in the transverse direction is within the range not less than 4x but not greater than 8x to obtain biaxially oriented polyester resin composition film. Operation D: Operation in which the biaxially oriented polyester resin composition film obtained at Operation C is made to undergo relaxation within the range not less than 3% but not greater than 20% in the transverse direction of the film as it is heated so as to be within the range not less than Tm - 40 (° C) of the polyester resin but not greater than Tm - 5 (° C) of the polyester resin.

  本发明提供了一种具有优异抗冲击强度和耐热性的双向拉伸聚酯薄膜及其生产方法。生产双向拉伸聚酯薄膜的方法包括以下操作 A 至操作 D。操作 A：将 Tc - (Tg + Tm)/2 不小于 25 摄氏度但不大于 30 摄氏度的聚酯树脂组合物熔融挤出，得到未拉伸聚酯树脂组合物片材。操作 B：将在操作 A 中获得的未拉伸聚酯树脂组合片材加热，使其处于不小于聚酯树脂 Tg + 5（摄氏度）但不大于聚酯树脂 Tg + 40（摄氏度）的范围内，然后进行拉伸，使机器方向上的拉伸比处于不小于 2 倍但不大于 6 倍的范围内，从而获得单轴拉伸聚酯树脂组合薄膜。操作 C：将在操作 B 中获得的单轴拉伸聚酯树脂组合物薄膜加热，使其处于不低于聚酯树脂 Tc - 46 (°C)但不高于聚酯树脂 Tc + 25 (°C)的范围内，然后进行拉伸，使横向拉伸比处于不小于 4 倍但不大于 8 倍的范围内，从而获得双轴拉伸聚酯树脂组合物薄膜。操作 D：在操作 C 中得到的双轴取向聚酯树脂组合物薄膜在加热过程中，使其在横向方向上发生松弛，松弛率在不小于 3%但不大于 20%的范围内，使其在不小于聚酯树脂的 Tm - 40 (°C)但不大于聚酯树脂的 Tm - 5 (°C)的范围内。
• Particles, particle dispersion, particle-dispersed resin composition, producing method therefor, resin molded article, producing method therefor, catalyst particles, catalyst solution, catalyst composition, catalyst molded article, titanium complex, titanium oxide particles and producing method therefor
  申请人：NITTO DENKO CORPORATION

  公开号：US10265693B2

  公开（公告）日：2019-04-23

  Organic-inorganic composite particles that can be dispersed in a solvent and/or a resin as primary particles having an organic group on the surface of inorganic particles, the organic-inorganic composite particles having negative birefringence.

  有机-无机复合粒子，可作为初级粒子分散在溶剂和/或树脂中，无机粒子表面带有有机基团，有机-无机复合粒子具有负双折射。
• Composition based on copolycarbonates
  申请人：——

  公开号：US20020123567A1

  公开（公告）日：2002-09-05

  The invention relates to thermoplastic copolycarbonate compositions and moulded parts containing the latter having improved stress cracking resistance and thermal stability.

  本发明涉及热塑性共聚碳酸酯组合物和含有后者的模制件，这些组合物和模制件具有更好的抗应力开裂性和热稳定性。