3-{2-[2-(3-Amino-propylsulfanyl)-ethylsulfanyl]-ethylsulfanyl}-propylamine | 124640-44-4

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫醚类
• 英文名称: 3-{2-[2-(3-Amino-propylsulfanyl)-ethylsulfanyl]-ethylsulfanyl}-propylamine
• 英文别名: 3-[2-[2-(3-Aminopropylsulfanyl)ethylsulfanyl]ethylsulfanyl]propan-1-amine
• CAS: 124640-44-4
• 化学式: C₁₀H₂₄N₂S₃
• 分子量: 268.512
• InChiKey: FMEOYOZPVISLBD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1
• 重原子数：
  15
• 可旋转键数：
  12
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  128
• 氢给体数：
  2
• 氢受体数：
  5

反应信息

• 作为产物：
  描述：

  Trityl-[3-(2-{2-[3-(trityl-amino)-propylsulfanyl]-ethylsulfanyl}-ethylsulfanyl)-propyl]-amine 在 水 、 溶剂黄146 作用下， 生成 3-{2-[2-(3-Amino-propylsulfanyl)-ethylsulfanyl]-ethylsulfanyl}-propylamine
  参考文献：
  名称：

  A new method to extend dimercaptan or diamine chains with aminopropyl units using 3-bromo-N-tritylpropanamine

  摘要：

  Dimercaptans and diamines react with 3-bromo-N-tritylpropanamine to give the corresponding N,N'-ditrityldithia and N,N'-ditritylpolyaza compounds in yields of 50-80%. The trityl protecting groups are readily removed in acid. These reactions make possible the synthesis of a number of new alpha-omega-diamino compounds needed for the synthesis of new dithiadiaza, di- and polyaza macrocyclic ligands.

  DOI：

  10.1016/s0040-4039(00)71207-x

文献信息

• A new method to extend dimercaptan or diamine chains with aminopropyl units using 3-bromo-N-tritylpropanamine
  作者：Krzysztof E. Krakowiak、Peter Huszthy、Jerald S. Bradshaw、Reed M. Izatt

  DOI：10.1016/s0040-4039(00)71207-x

  日期：1991.1

  Dimercaptans and diamines react with 3-bromo-N-tritylpropanamine to give the corresponding N,N'-ditrityldithia and N,N'-ditritylpolyaza compounds in yields of 50-80%. The trityl protecting groups are readily removed in acid. These reactions make possible the synthesis of a number of new alpha-omega-diamino compounds needed for the synthesis of new dithiadiaza, di- and polyaza macrocyclic ligands.