phosphoric acid tri-[9]anthryl ester | 183297-77-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: phosphoric acid tri-[9]anthryl ester
• 英文别名: Phosphorigsaeure-tri-[9]anthrylester；Tri-(anthryl-(9))-phosphit；Trianthracen-9-yl phosphite
• CAS: 183297-77-0
• 化学式: C₄₂H₂₇O₃P
• 分子量: 610.648
• InChiKey: VHAHQCUPIDGTHM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  13
• 重原子数：
  46
• 可旋转键数：
  6
• 环数：
  9.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  27.7
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  9-羟基蒽 在 三氯化磷 作用下， 生成 phosphoric acid tri-[9]anthryl ester
  参考文献：
  名称：

  Anschuetz; Kraft; Schmidt, Justus Liebigs Annalen der Chemie, 1939, vol. 542, p. 14,20

  摘要：

  DOI：

文献信息

• Polymerization catalyst and process for polymerizing alpha-olefins
  申请人：PHILLIPS PETROLEUM COMPANY

  公开号：EP0012397A1

  公开（公告）日：1980-06-25

  Alpha-olefins are polymerized employing a catalyst which forms on mixing a catalyst component A formed by milling together a magnesium halide or manganous halide with selected catalyst adjuvants followed by treatment of the resulting milled product with a halogenated tetravalent titanium compound and combining the product thus formed with a cocatalyst component B comprising at least one of an organoaluminum compound and an organoaluminum monohalide with or without an aromatic ester as a part of the cocatalyst system.

  α-烯烃采用一种催化剂进行聚合，这种催化剂是通过将卤化镁或卤化锰与选定的催化剂辅助剂混合研磨形成催化剂组分 A，然后用卤代四价钛化合物对研磨产物进行处理，并将由此形成的产物与由有机铝化合物和有机铝单卤化物中的至少一种组成的助催化剂组分 B 相结合而形成的，助催化剂体系中可以有芳香族酯，也可以没有芳香族酯。
• Method for production of titanium halide catalyst component, catalyst system including such component, and polymerization of alpha-olefins using such system
  申请人：STAUFFER CHEMICAL COMPANY

  公开号：EP0043185A1

  公开（公告）日：1982-01-06

  A titanium halide containing component suitable for use in a catalyst system comprising said component and an aluminum containing component is obtained by co-pulverizing a halogen containing magnesium compound, e.g. MgCl2, with an electron-donor compound, e.g. ethyl benzoate, to produce a co-pulverized product. The co-pulverized product is then reacted with an organic phosphite, e.g. triphenyl phosphite, to produce a reaction product. The reaction product is then reacted with a titanium halide compound, e.g. TiC14. A catalyst system for the polymerization of alpha-olefins includes such titanium halide containing component and an organoaluminum component.

  通过将含卤素的镁化合物（如 MgCl2）与电子供体化合物（如苯甲酸乙酯）进行共粉化，生成共粉化产物，从而获得适用于包含上述组分和含铝组分的催化剂体系的含卤化钛组分。然后，将共粉化产物与有机亚磷酸酯（如亚磷酸三苯酯）反应，生成反应产物。反应产物再与卤化钛化合物（如 TiC14）反应。用于聚合α-烯烃的催化剂体系包括这种含卤化钛的组分和有机铝组分。
• Titanium halide containing catalyst
  申请人：STAUFFER CHEMICAL COMPANY

  公开号：EP0044445A2

  公开（公告）日：1982-01-27

  A novel catalyst system for the polymerization of alpha-olefins is provided. The catalyst system comprises: (a) an organoaluminum containing component, e.g. triethyl aluminum, and (b) a titanium halide containing component. The titanium halide containing component is obtained by reacting a halogen containing magnesium compound, e.g. MgCl2, with an organic phosphite, e.g. triphenyl phosphite, to produce a reaction product. The reaction product is then co-pulverized with a complex of a titanium halide compound and an electron donor compound, e.g. TiCl4 ethyl benzoate, to produce a co-pulverized product. The co-pulverized product is then reacted with a titanium halide compound, e.g. TiCI4. A novel titanium halide containing component is provided as well as a process for producing said component. A process for the polymerization of alpha-olefins is also provided.

  提供了一种用于α-烯烃聚合的新型催化剂体系。该催化剂系统包括 (a) 含有机铝成分，例如三乙基铝，以及 (b) 一种含卤化钛的组分。 卤化钛成分是通过含卤素的镁化合物（如 MgCl2）与有机亚磷酸酯（如亚磷酸三苯酯）反应生成反应产物而得到的。然后将反应产物与卤化钛化合物和电子供体化合物（如 TiCl4 苯甲酸乙酯）的络合物进行共粉碎，生成共粉碎产物。然后再将共粉碎产物与卤化钛化合物（如 TiCI4）反应。 本发明提供了一种新型含卤化钛成分以及生产该成分的工艺。此外，还提供了一种α-烯烃聚合工艺。
• Kutyrev; Fomin; Moskva, Russian Journal of General Chemistry, 1996, vol. 66, # 5, p. 757 - 764
  作者：Kutyrev、Fomin、Moskva

  DOI：——

  日期：——
• US4130503A
  申请人：——

  公开号：US4130503A

  公开（公告）日：1978-12-19