4-isopropylphenyl(p-tolyl)iodonium chloride | 178233-70-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 4-isopropylphenyl(p-tolyl)iodonium chloride
• 英文别名: (4-isopropylphenyl)-4'-methylphenyliodonium chloride；4-isopropyl-4'-methyldiphenyliodonium chloride；(4-Methylphenyl)[4-(propan-2-yl)phenyl]iodanium chloride；(4-methylphenyl)-(4-propan-2-ylphenyl)iodanium;chloride
• CAS: 178233-70-0
• 化学式: C₁₆H₁₈I*Cl
• 分子量: 372.676
• InChiKey: SBNUZKZHHCNPCN-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  -1.75
• 重原子数：
  18
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  溴五氟苯 、 4-isopropylphenyl(p-tolyl)iodonium chloride 在 gallium(III) trichloride 、 正丁基锂 作用下， 以 乙醚 、 正己烷 、 二氯甲烷 为溶剂， 反应 2.0h， 以85%的产率得到(4-isopropylphenyl)-4-methylphenyliodonium tetrakis(pentafluorophenyl)gallate
  参考文献：
  名称：

  Synthesis, properties and photolysis of new iodonium tetrakis(pentafluorophenyl)gallate photoinitiators and comparison with their indate and aluminate analogs

  摘要：

  A series of new iodonium tetrakis (pentafluorophenyl) gallates were synthesized in high yield via an improved preparation of the lithium gallate, their photoproducts analyzed by UV, F-19 NMR and GC-MS spectra and a photolysis mechanism postulated. The stability of these photoinitiators was also compared with their borate, aluminate and indate analogs. (C) 2002 Published by Elsevier Science Ltd.

  DOI：

  10.1016/s0040-4020(02)00497-0

文献信息

• CURABLE COMPOSITION AND CURED ARTICLE USING SAME
  申请人：SAN-APRO LTD.

  公开号：US20180329297A1

  公开（公告）日：2018-11-15

  The heat- or energy ray-curable composition for members contains an onium gallate salt having a specific structure. The invention is a heat- or energy ray-curable composition comprising a cationic polymerizable compound and an acid generator containing an onium gallate salt represented by general formula (1). In formula (1), R 1 -R 4 are each independently an alkyl group having 1 to 18 carbon atoms or Ar; however, at least one is Ar; Ar is an aryl group having 6 to 14 carbon atoms (not including the number of carbon atoms in the following substituents); some of the hydrogen atoms in the aryl group may be substituted by alkyl groups having 1 to 18 carbon atoms or the like; E represents an element of valence n of group 15 to group 17 (IUPAC notation); n is an integer of 1-3; and R 5 is an organic group bonded to E.

  该成员的热固化或能量光固化组合物包含具有特定结构的酚酸盐。该发明是一种热固化或能量光固化组合物，包括阳离子可聚合化合物和含有由通式（1）表示的酚酸盐的酸发生剂。在通式（1）中，R1-R4分别是具有1至18个碳原子的烷基基团或Ar；但至少有一个是Ar；Ar是具有6至14个碳原子的芳基团（不包括以下取代基中的碳原子数）；芳基团中的一些氢原子可以被具有1至18个碳原子的烷基基团或类似物所取代；E表示15族到17族（IUPAC符号）的n价元素；n是1-3的整数；R5是与E结合的有机基团。
• Electron-accepting compound and composition for charge-transporting film, and luminescent element using same
  申请人：Mitsubishi Chemical Corporation

  公开号：US11316112B2

  公开（公告）日：2022-04-26

  The present invention provides with an electron-accepting compound having a structure of the following formula (1):

  本发明提供了一种具有以下结构的电子受体化合物（1）：
• オニウムボレート塩、酸発生剤、硬化性樹脂組成物及びそれを用いた硬化体
  申请人：サンアプロ株式会社

  公开号：JP2017222621A

  公开（公告）日：2017-12-21

  【課題】カチオン重合性能や架橋反応性能を有するオニウムボレート塩等を提供する。【解決手段】下記一般式（１）で表されるオニウムボレート塩（ＯＢ１）と下記一般式（２）で表されるオニウムボレート塩（ＯＢ２）とを含むオニウムボレート塩であり、（ＯＢ１）及び（ＯＢ２）中の（ＯＢ２）の含有量が０．０１〜４重量％であるオニウムボレート塩。[ （Ｒ１）n＋１−Ｅ]＋ [ （Ｒ２）ｂＢ（Ａｒ）４‐b ]− （１）[ （Ｒ１）n＋１−Ｅ]＋ [ （ＯＨ）（Ｒ２）ｂＢ（Ａｒ）３‐b ]− （２）［式（１）、（２）中、ＥはＶＩＡ族〜ＶＩＩＡ族（ＣＡＳ表記）の原子価ｎの元素を表し、ｎは１または２の整数；Ｒ１はＥに結合している有機基；Ｒ２はＢ（ホウ素）に結合している有機基であり、ｂは1〜３の整数；Ａｒは置換フェニル基を表し、ｂは1〜３の整数]【選択図】なし

  【问题】提供具有阳离子聚合性能和交联反应性能的Onium Borate盐等。 【解决方案】包含以下通式（1）表示的Onium Borate盐（OB1）和以下通式（2）表示的Onium Borate盐（OB2）的Onium Borate盐，其中OB1和OB2中OB2的含量为0.01〜4重量％。 [（R1）n + 1-E] + [（R2）bB（Ar）4-b] -（1） [（R1）n + 1-E] + [（OH）（R2）bB（Ar）3-b] -（2） [在式（1）和（2）中，E表示VIA族〜VIIA族（CAS表示）的原子价n的元素，n是1或2的整数；R1是连接到E的有机基团；R2是连接到B（硼）的有机基团，b是1〜3的整数；Ar表示取代苯基，b是1〜3的整数] 【选择图】无
• [EN] COMPOUND, COATING COMPOSITION COMPRISING SAME, ORGANIC LIGHT-EMITTING DEVICE USING SAME, AND MANUFACTURING METHOD THEREFOR<br/>[FR] COMPOSÉ, COMPOSITION DE REVÊTEMENT LE COMPRENANT, DISPOSITIF ÉLECTROLUMINESCENT ORGANIQUE L'UTILISANT ET PROCÉDÉ DE FABRICATION ASSOCIÉ<br/>[KO] 화합물, 이를 포함하는 코팅 조성물, 이를 이용한 유기 발광 소자 및 이의 제조방법
  申请人：LG CHEMICAL LTD

  公开号：WO2022203454A1

  公开（公告）日：2022-09-29

  본 명세서는 화학식 1로 표시되는 화합물, 상기 화학식 1로 표시되는 화합물을 포함하는 코팅 조성물, 이를 이용한 유기 발광 소자 및 이의 제조 방법에 관한 것이다.

  这是关于包含化学式1的化合物和包含化学式1的涂层组合物以及使用它们制造有机发光器件的规范说明和制造方法。
• Studies of Weakly Coordinating Anions Paired with Iodonium Cations
  作者：Kangtai Ren、John H. Malpert、Huiying Li、Haiyan Gu、Douglas C. Neckers

  DOI：10.1021/ma010823o

  日期：2002.2.1

  Several new iodonium salts containing weakly coordinating anions were synthesized and characterized. Upon UV irradiation, the rates of photoacid generation in acetonitrile and their preliminary activity in the photopolymerization of epoxy silicones were compared. Studies showed those salts to be excellent photoacid generators. The anions [(C6F5)(3)B-C3H3N2-B(C6F5)(3)](-), B(C6F5)(4)(-), and Ga(C6F5)(4)(-) were more active and the compounds made from them more soluble in most solvents. The [(C6F5)(3)B-C6F4-B(C6F5)(3)](2-) anion was less active, and the compounds made from them were less soluble than compounds made from the three aforementioned anions. Compounds containing hexabromocarborane anion were quite similar to compounds containing SbF6- in both photoactivity and solubility.