pentabromothiophenol | 38049-51-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯硫酚类
• 英文名称: pentabromothiophenol
• 英文别名: 2,3,4,5,6-Pentabromobenzene-1-thiol；2,3,4,5,6-pentabromobenzenethiol
• CAS: 38049-51-3
• 化学式: C₆HBr₅S
• 分子量: 504.66
• InChiKey: UTLUYJULFYZZTK-UHFFFAOYSA-N

物化性质

• 沸点：
  419.1±45.0 °C(Predicted)
• 密度：
  2.758±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5.5
• 重原子数：
  12
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  1
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  六溴苯 生成 pentabromothiophenol
  参考文献：
  名称：

  Synthesis and reactions of some pentabromophenyl organometallics

  摘要：

  DOI：

  10.1016/s0022-328x(00)90075-5

文献信息

• Decomposition of cumene hydroperoxide with a halogen-substituted
  申请人：Gulf Research and Development Company

  公开号：US04210606A1

  公开（公告）日：1980-07-01

  Cumene hydroperoxide is decomposed to phenol and acetone using a halogen-substituted thiophenol as the catalyst.

  Cumene过氧化物通过使用卤代硫酚作为催化剂分解为苯酚和丙酮。
• Compositions for use in golf balls
  申请人：Bulpett A. David

  公开号：US20050245652A1

  公开（公告）日：2005-11-03

  A golf ball comprises a core, an outer cover layer, and, optionally, an intermediate layer disposed between the core and the outer cover layer. The outer cover layer may comprise a polyurethane or polyurea composition. At least one portion of the golf ball comprises a composition that enhances physical properties and/or performance characteristics (e.g., coefficient of restitution) of the golf ball. Preferably, the coefficient of restitution of the core is 0.8 or greater.

  高尔夫球由内核、外覆盖层和可选的中间层组成，外覆盖层可以包括聚氨酯或聚脲组成。高尔夫球的至少一部分包含一种增强物理特性和/或性能特征（例如反弹系数）的组合物。最好，内核的反弹系数为0.8或更高。
• COMPOSITIONS FOR USE IN GOLF BALLS
  申请人：Bulpett David A.

  公开号：US20080261722A1

  公开（公告）日：2008-10-23

  A golf ball including a core and at least one cover layer disposed about the core, wherein the core or the cover layer is formed from a composition comprising a base polymer, a crosslink initiator, and at least one additive comprising phenothiazine or a perhaloalkyl additive having a structure of: where R 1 or R 5 are —SZ, at least one of R 1 to R 5 is a perhaloalkyl, perhalocycloalkyl, or perhaloaryl substituent; the remainder of R 1 to R 5 are the same or different organic substituents or hydrogen; Z is a non-metal cation comprising quaternary ammonium, quaternary pyridinium, quaternary quinolinium, (organo)phosphonium, (organo)sulfonium, (organo)oxonium, (organo)iodonium, or (organo)azonium; and n is an integer of 1 or greater.

  一颗高尔夫球，包括一个核心和至少一层覆盖层，其中核心或覆盖层是由包含基础聚合物、交联引发剂和至少一种添加剂的组成物形成的，该添加剂包括苯并噻吩或具有以下结构的卤代烷基添加剂：其中R1或R5是—SZ，R1到R5中至少有一个是卤代烷基、卤代环烷基或卤代芳基取代基；R1到R5的其余部分是相同或不同的有机取代基或氢原子；Z是非金属阳离子，包括季铵盐、季吡啶盐、季喹啉盐、（有机）磷盐、（有机）硫盐、（有机）氧盐、（有机）碘盐或（有机）偶氮盐；n是大于等于1的整数。
• Compositions for Use in Golf Balls
  申请人：Bulpett David A.

  公开号：US20080176678A1

  公开（公告）日：2008-07-24

  A golf ball comprising a core and at least one layer disposed about the core, wherein at least one of the core or the layer is formed from a composition comprising a base polymer, a crosslink initiator, and an additive comprising an aromatic iodonium compound or an aromatic iodonium salt.

  一颗高尔夫球包括一个核心和至少一层沿核心排列的材料，其中核心或层中的至少一个是由包含基础聚合物、交联引发剂和添加剂的组合物形成的，该添加剂包括芳香碘化物或芳香碘化盐。
• METHOD FOR PRODUCING STRUCTURE WHEREIN AROMATIC POLYMER IS BONDED TO BASE, STRUCTURE HAVING AROMATIC POLYMER CHAIN BONDED TO CONDUCTIVE BASE, AND ELECTRONIC DEVICE COMPRISING THE STRUCTURE
  申请人：Tanaka Kenta

  公开号：US20100069603A1

  公开（公告）日：2010-03-18

  Disclosed is a method for efficiently producing a structure wherein an aromatic polymer is bonded to a base. Also disclosed is such a structure wherein the base is electrically conductive. Specifically disclosed is a method for producing a structure, which comprises a step for polycondensing an aromatic compound represented by the formula (I) below in the presence of a polymerization catalyst and a base having a group represented by the formula (II) below. MY n Ar—X  (I) (In the formula (I), Ar represents a divalent group composed of an aromatic ring; X represents a halogen atom or the like; Y represents an oxygen atom, a sulfur atom, an imino group or the like; n represents 0 or 1; and M represents a hydrogen atom, —B(OQ 1 ) 2 (wherein Q 1 represents a hydrogen atom, a hydrocarbon group or the like) or the like.) —Ar a —(X a ) p (II) (In the formula (II), Ar a represents a group having a valence of (p+1) and composed of an aromatic ring; X a represents a halogen atom or a monovalent group expressed as —SO 3 Q a (wherein Q a represents a substituted or unsubstituted hydrocarbon group); p represents an integer not less than 1, and when p is an integer not less than 2, the plurality of X a 's may be the same as or different from each other.)

  公开了一种高效生产芳香族聚合物与基体结合的结构的方法。还公开了这样一种结构，其中基体具有电导性。具体公开了一种生产结构的方法，该方法包括在聚合催化剂和具有以下式子（II）中表示的基团的碱存在下，聚合表示为以下式子（I）的芳香族化合物的步骤。MYnAr—X  (I)（在式（I）中，Ar表示由芳香族环组成的二价基团；X表示卤素原子或类似物；Y表示氧原子、硫原子、亚胺基或类似物；n表示0或1；M表示氢原子，-B（OQ1）2（其中Q1表示氢原子、碳氢基团或类似物）或类似物。）—Ara—（Xa）p（II）（在式（II）中，Ararepresents具有（p+1）价且由芳香族环组成的基团；Xarepresents卤素原子或表示为-SO3Qa的一价基团（其中Qarepresents取代或未取代的碳氢基团）；p表示不小于1的整数，当p为不小于2的整数时，Xa的多个可以相同也可以不同。）