3-Methyl-3-(tert.-butylmercapto)-hexan | 91964-16-8

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫醚类
• 英文名称: 3-Methyl-3-(tert.-butylmercapto)-hexan
• 英文别名: 3-tert-butylsulfanyl-3-methyl-hexane；3-Tert-butylsulfanyl-3-methylhexane；3-tert-butylsulfanyl-3-methylhexane
• CAS: 91964-16-8
• 化学式: C₁₁H₂₄S
• 分子量: 188.378
• InChiKey: AHEXVNRPEDAVFD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.3
• 重原子数：
  12
• 可旋转键数：
  5
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  25.3
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  3-甲基-3-己醇 、 叔丁基硫醇 在 高氯酸 、 乙酸酐 作用下， 生成 3-Methyl-3-(tert.-butylmercapto)-hexan
  参考文献：
  名称：

  323.叔烷基硫化物在乙酸-高氯酸中的可逆形成和溶剂分解

  摘要：

  DOI：

  10.1039/jr9620001694

文献信息

• Synthesis of cyclophanes for a self-assembly reaction
  申请人：University of Oregon

  公开号：US10344005B2

  公开（公告）日：2019-07-09

  Disclosed herein is a novel method for preparing cyclophanes, comprising forming a disulfide cyclophane by contacting a linker moiety which includes two or more thiol groups, with a metal salt and an oxidant. The disulfide cyclophane is then desulfurized to form a thiacyclophane comprising thioether bridges. This thiacyclophane optionally may be further desulfurized to form an unsaturated hydrocarbon cyclophane, which can then be reduced to form a saturated hydrocarbon cyclophane. The various cyclophanes can be synthesized in a ring form, such as a dimer, trimer or tetramer etc., or they can be synthesized in a tetrahedral or larger structure. Also disclosed are novel cyclophanes formed by the disclosed method.

  本文公开了一种制备环烷的新方法，该方法包括将包含两个或两个以上硫醇基团的连接分子与金属盐和氧化剂接触，形成二硫化环烷。然后将二硫化环烷脱硫，形成包含硫醚桥的硫代环烷。这种硫代环烷还可以进一步脱硫，形成不饱和烃环烷，然后再还原形成饱和烃环烷。各种环烷可合成为环状，如二聚体、三聚体或四聚体等，也可合成为四面体或更大的结构。同时公开的还有通过公开方法形成的新型环烷。
• N-SULFONYLDICARBOXIMIDE CONTAINING TETHERING COMPOUNDS
  申请人：Benson Karl E.

  公开号：US20080145907A1

  公开（公告）日：2008-06-19

  Compounds having two reactive functional groups are described that can be used as a tethering compound to immobilize an amine-containing material to a substrate. The first reactive functional group can be used to provide attachment to a surface of a substrate. The second reactive functional group is a N-sulfonyldicarboximide group that can be reacted with an amine-containing material, particularly a primary aliphatic amine, to form a connector group between the substrate and the amine-containing material. The invention also provides articles and methods for immobilizing amine-containing materials to a substrate.
• US7667046B2
  申请人：——

  公开号：US7667046B2

  公开（公告）日：2010-02-23
• 323. Reversible formation and solvolysis of tertiary alkyl sulphides in acetic acid–perchloric acid
  作者：M. E. Cain、M. B. Evans、D. F. Lee

  DOI：10.1039/jr9620001694

  日期：——