1-Chloro-3-[cyclopenta-2,4-dien-1-ylidene(phenyl)methyl]benzene | 915301-92-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1-Chloro-3-[cyclopenta-2,4-dien-1-ylidene(phenyl)methyl]benzene
• CAS: 915301-92-7
• 化学式: C₁₈H₁₃Cl
• 分子量: 264.754
• InChiKey: LILHIZDVOYBDAB-UHFFFAOYSA-N

物化性质

• 沸点：
  419.3±24.0 °C(Predicted)
• 密度：
  1.195±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  6
• 重原子数：
  19
• 可旋转键数：
  2
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  1,2-dicarba-closo-dodecaborane(12) 、 1-Chloro-3-[cyclopenta-2,4-dien-1-ylidene(phenyl)methyl]benzene 在 正丁基锂 、 碘 作用下， 以 正己烷 、 环己烷 为溶剂， 反应 8.5h， 以49%的产率得到
  参考文献：
  名称：

  邻碳硼炔与富勒烯的Diels-Alder反应：碳硼烷降冰片二烯的合成及其转化

  摘要：

  ø -Carboryne（1,2-脱氢ö -carborane）从所述前体中原位生成的1-碘-2- lithio- ö -carborane发生反应与6,6'- diarylfulvenes以得到中等产率具有优良的一系列carboranonorbornadienes的区域选择性。所得的[4 + 2]环加合物可以进一步衍生化，从而导致形成各种高度官能化的碳硼烷。这项研究表明，这种狄尔斯-阿尔德反应可作为一种方便的方法，用于制备可能在医学和材料科学中得到应用的新型多官能化的邻-碳环烷衍生物。

  DOI：

  10.1002/cplu.201402129

文献信息

• Catalyst for olefin polymerization, method for producing olefin polymer, method for producing propylene-based copolymer, propylene polymer, propylene-based polymer composition, and use of those
  申请人：Tohi Yasushi

  公开号：US20080220193A1

  公开（公告）日：2008-09-11

  A catalyst for olefin polymerization, comprising: (A-1) a bridged metallocene compound represented by the following Formula [1-1], and (b) at least one compound selected from: (b-1) an organoaluminum oxy compound, (b-2) a compound which forms an ion pair, and (b-3) an organoaluminum compound: wherein in Formula [1-1], R 1 , R 2 , R 3 , R 4 , R 5 , R 8 , R 9 , and R 12 are each selected from a hydrogen, a hydrocarbon group and a silicon-containing group; the four groups of R 6 , R 7 , R 10 , and R 11 are not hydrogen atoms, and are each selected from a hydrocarbon group or a silicon-containing group; R 13 and R 14 are each a hydrocarbon group or the like, excluding a hydrogen atom and a methyl group; M is Ti, Zr or the like; Y is carbon or the like; Q is a halogen or the like; and j is an integer from 1

  催化剂，用于烯烃聚合，包括：（A-1）桥联金属茂化合物，其表示为以下式[1-1]；以及（b）至少一种化合物，选自：（b-1）有机铝氧化合物，（b-2）形成离子对的化合物，以及（b-3）有机铝化合物。在式[1-1]中，R1、R2、R3、R4、R5、R8、R9和R12各自选自氢、烃基和含硅基团；R6、R7、R10和R11的四个基团不是氢原子，各自选自烃基或含硅基团；R13和R14各自是烃基或类似的基团，不包括氢原子和甲基基团；M是Ti、Zr或类似的金属；Y是碳或类似的元素；Q是卤素或类似的元素；j是整数1或更大。
• CATALYST FOR OLEFIN POLYMERIZATION, METHOD FOR PRODUCING OLEFIN POLYMER, METHOD FOR PRODUCING PROPYLENE COPOLYMER, PROPYLENE POLYMER, PROPYLENE POLYMER COMPOSITION, AND USE OF THOSE
  申请人：Mitsui Chemicals, Inc.

  公开号：EP1900758A1

  公开（公告）日：2008-03-19

  A catalyst for olefin polymerization, comprising: (A-1) a bridged metallocene compound represented by the following Formula [1-1], and (b) at least one compound selected from: (b-1) an organoaluminum oxy compound, (b-2) a compound which forms an ion pair, and (b-3) an organoaluminum compound: wherein in Formula [1-1], R1, R2, R3, R4, R5, R8, R9, and R12 are each selected from a hydrogen, a hydrocarbon group and a silicon-containing group; the four groups of R6, R7, R10, and R11 are not hydrogen atoms, and are each selected from a hydrocarbon group or a silicon-containing group; R13 and R14 are each a hydrocarbon group or the like, excluding a hydrogen atom and a methyl group; M is Ti, Zr or the like; Y is carbon or the like; Q is a halogen or the like; and j is an integer from 1 to 4.

  一种烯烃聚合催化剂，包括 (A-1)由下式[1-1]表示的桥接茂金属化合物，和(b)至少一种选自以下的化合物：(b-1)有机铝氧化合物，(b-2)形成离子对的化合物，和(b-3)有机铝化合物： 其中在式[1-1]中，R1、R2、R3、R4、R5、R8、R9和R12各自选自氢、烃基和含硅基团；R6、R7、R10和R11四个基团不是氢原子，各自选自烃基或含硅基团；R13 和 R14 各为烃基或类似物，不包括氢原子和甲基；M 为 Ti、Zr 或类似物；Y 为碳或类似物；Q 为卤素或类似物；以及 j 为 1 至 4 的整数。
• Method for producing propylene-based copolymer
  申请人：Mitsui Chemicals, Inc.

  公开号：EP2275451A2

  公开（公告）日：2011-01-19

  Provided is a method for producing a propylene-based copolymer comprising polymerising propylene and an α-olefin (excluding propylene and polyenes) in the presence of a catalyst. The catalyst comprises a bridged metallocene compound of specific formula and at least one compound selected from an organoaluminum oxy compound, a compound which reacts with the bridged metallocene compound to form an ion pair, and an organoaluminum compound.

  本发明提供了一种生产丙烯基共聚物的方法，该方法包括在催化剂存在下聚合丙烯和 α-烯烃（不包括丙烯和聚烯）。催化剂包括特定式的架桥茂金属化合物和至少一种选自有机铝氧化合物、与架桥茂金属化合物反应形成离子对的化合物和有机铝化合物的化合物。
• CATALYST FOR OLEFIN POLYMERIZATION, METHOD FOR PRODUCING OLEFIN POLYMER, METHOD FOR PRODUCING PROPYLENE-BASED COPOLYMER, PROPYLENE POLYMER, PROPYLENE-BASED POLYMER COMPOSITION, AND USE OF THOSE
  申请人：MITSUI CHEMICALS, INC.

  公开号：US20160280819A1

  公开（公告）日：2016-09-29

  A catalyst for olefin polymerization, comprising: (A-1) a bridged metallocene compound represented by the following Formula [1-1], and (b) at least one compound selected from: (b-1) an organoaluminum oxy compound, (b-2) a compound which forms an ion pair, and (b-3) an organoaluminum compound: wherein in Formula [1-1], R 1 , R 2 , R 3 , R 4 , R 5 , R 8 , R 9 , and R 12 are each selected from a hydrogen, a hydrocarbon group and a silicon-containing group; the four groups of R 6 , R 7 , R 10 , and R 11 are not hydrogen atoms, and are each selected from a hydrocarbon group or a silicon-containing group; R 13 and R 14 are each a hydrocarbon group or the like, excluding a hydrogen atom and a methyl group; M is Ti, Zr or the like; Y is carbon or the like; Q is a halogen or the like; and j is an integer from 1 to 4.
• US9382356B2
  申请人：——

  公开号：US9382356B2

  公开（公告）日：2016-07-05