1-p-tolyl-2,3-dichloropropane | 106017-82-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1-p-tolyl-2,3-dichloropropane
• 英文别名: 1-(2,3-Dichloropropyl)-4-methylbenzene
• CAS: 106017-82-7
• 化学式: C₁₀H₁₂Cl₂
• 分子量: 203.111
• InChiKey: LZRBUDCNNLOCDA-UHFFFAOYSA-N

物化性质

• 沸点：
  284.1±25.0 °C(Predicted)
• 密度：
  1.139±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.8
• 重原子数：
  12
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  1-p-tolyl-2,3-dichloropropane 在 四氯化锡 作用下， 生成 1-(2-Chloro-1-chloromethyl-ethyl)-4-methyl-benzene
  参考文献：
  名称：

  Aryl-assisted halogen exchange and rearrangements of 2-bromo-1-chloro-3-arylpropanes and 1-bromo-3-chloro-2-arylpropanes. Evidence for a competitive bromine-assisted pathway in the case of 1,2-dibromo-3-arylpropanes

  摘要：

  DOI：

  10.1021/jo00378a018
• 作为产物：
  描述：

  1-(2-Bromo-3-chloro-propyl)-4-methyl-benzene 在 四氯化锡 作用下， 生成 1-p-tolyl-2,3-dichloropropane
  参考文献：
  名称：

  Aryl-assisted halogen exchange and rearrangements of 2-bromo-1-chloro-3-arylpropanes and 1-bromo-3-chloro-2-arylpropanes. Evidence for a competitive bromine-assisted pathway in the case of 1,2-dibromo-3-arylpropanes

  摘要：

  DOI：

  10.1021/jo00378a018

文献信息

• Solid state ion selective electrodes and membranes
  申请人：BECKMAN INSTRUMENTS, INC.

  公开号：EP0021595A1

  公开（公告）日：1981-01-07

  A solid state electrode for use in determining ion concentration in an aqueous solution comprising an electrically conductive element (1) a first lipophilic-hydrophobic (hereinafter referred to as LH) layer (2) in intimate contact with the element (1), and a second LH layer (3) in initimate contact with the first layer (2). The first LH layer (2) comprises an ahesive, LH polymer having an intrinsic viscosity of from about 0.4 to about 0.9 ml/g; and an LH plasticizer. The second LH layer(3) comprises an LH polymer having an intrinsic viscosity of from about 1 to about 1.5 ml/g; an LH plasticizer, and an LH ion-selective ligand of the ion to be determined. Preferably, the first LH layer (2) further comprises an LH charge carrier. As used herein, the term "lipophilic-hydrophobic (LH)" denotes an organic solvent soluble-water insoluble substance.

  一种用于测定水溶液中离子浓度的固态电极，包括导电元件（1）、与元件（1）紧密接触的第一亲脂疏水（以下简称 LH）层（2）以及与第一层（2）初步接触的第二 LH 层（3）。第一 LH 层（2）包括一种粘性 LH 聚合物，其固有粘度约为 0.4 至 0.9 毫升/克；以及一种 LH 增塑剂。第二 LH 层（3）包括本征粘度约为 1 至约 1.5 毫升/克的 LH 聚合物、LH 增塑剂和待测离子的 LH 离子选择性配体。 第一 LH 层（2）最好还包括一个 LH 电荷载体。 本文所用术语 "亲油-疏水（LH）"指的是一种有机溶剂可溶-水不溶性物质。
• Salts of phosphoric acid diesters, their preparation and use in membranes, the membranes and their use in calcium ion determination, and the electrodes containing them
  申请人：BECKMAN INSTRUMENTS, INC.

  公开号：EP0021626A1

  公开（公告）日：1981-01-07

  A membrane for use in the determination of calcium ion concentration in an aqueous solution, the membrane being of the type comprising a calcium ion selective component and a carrier material. The membrane is characterized in that the calcium ion selective component is a compound having a formula (1) wherein X and Y are independently selected from a group consisting of aryl, alkyl(aryl), alkenyl(aryl), alkynyl(aryl), alkyl, cycloalkyl, alkenyl, cycloalkenyl, and alkynyl radicals wherein said alkyl moiety of said alkyl(aryl) radical consists of 1-12 carbon atoms; each alkenyl and alkynyl moiety of said alkenyl(aryl) and alkynyl(aryl) radicals, respectively, consists of 2-12 carbon atoms; each aryl moiety consists of 6,10,12, or 14 carbon atoms; and each alkyl, cycloalkyl, alkenyl, cycloalkenyl, and alkynyl radical consists of 6 to 14 carbon atoms; and Z is selected from a group consisting of alkyl radicals containing 1-12 carbon atoms; alkenyl and alkynyl radicals containing 4-12 carbon atoms; and cycloalkyl and cycloalkenyl radicals containing 6 to 12 carbon atoms. The membrane can be employed in an electrode system. A novel compound of formula I, supra, and a method for the manufacture thereof.

  一种用于测定水溶液中钙离子浓度的膜，该膜由钙离子选择性成分和载体材料组成。该膜的特征在于，钙离子选择性成分是一种具有式（1）的化合物 其中 X 和 Y 独立地选自由芳基、烷基（芳基）、烯基（芳基）、炔基（芳基）、烷基、环烷基、 烯基、环烯基和炔基组成的组，其中所述烷基（芳基）的烷基由 1-12 个碳原子组成；所述烯基（芳基）和炔基（芳基）的每个烯基和炔基分别由 2-12 个碳原子组成；每个芳基由 6、10、12 或 14 个碳原子组成；每个烷基、环烷基、烯基、环烯基和炔基由 6-14 个碳原子组成；以及 Z 选自由含 1-12 个碳原子的烷基、含 4-12 个碳原子的烯基和炔基以及含 6-12 个碳原子的环烷基和环烯基组成的组。 该膜可用于电极系统中。 一种上文式 I 的新型化合物及其制造方法。
• Grishchuk, B. D.; Gorbovoi, P. M.; Ganushchak, N. I., Russian Journal of General Chemistry, 1993, vol. 63, # 7.2, p. 1156 - 1158
  作者：Grishchuk, B. D.、Gorbovoi, P. M.、Ganushchak, N. I.、Brush, D. M.、Kudrik, E. Ya.

  DOI：——

  日期：——
• Obushak, N. D.; Karpyak, V. V.; Ganushchak, N. I., Russian Journal of Organic Chemistry, 1993, vol. 29, # 7.1, p. 1149 - 1156
  作者：Obushak, N. D.、Karpyak, V. V.、Ganushchak, N. I.、Koval'chuk, E. P.、Tikhonov, V. P.

  DOI：——

  日期：——
• FAIN D.; DUBOIS J. -E., J. ORG. CHEM., 52,(1987) N 2, 260-267
  作者：FAIN D.、 DUBOIS J. -E.

  DOI：——

  日期：——