1-(p-chlorophenyl)-3-(p-tolyl)-triazene | 25977-69-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1-(p-chlorophenyl)-3-(p-tolyl)-triazene
• 英文别名: N-(4-chloro-phenyl)-N'-p-tolyl-triazene；N-(4-chloro-phenyl)-N'-p-tolyl-triazene；N-(4-Chlor-phenyl)-N'-p-tolyl-triazen；4'-Chlor-4-methyl-diazoaminobenzol；p-Chlor-p'-methyldiazoaminobenzol；1-p-Tolyl-3-p-chlorphenyltriazen；4-chloro-N-[(4-methylphenyl)diazenyl]aniline
• CAS: 25977-69-9
• 化学式: C₁₃H₁₂ClN₃
• 分子量: 245.711
• InChiKey: ITZWPIVVJKJCHB-UHFFFAOYSA-N

物化性质

• 沸点：
  356.6±52.0 °C(Predicted)
• 密度：
  1.18±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5
• 重原子数：
  17
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.08
• 拓扑面积：
  36.8
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  1-(p-chlorophenyl)-3-(p-tolyl)-triazene 、 异氰酸苯酯 在 乙醚 作用下， 生成 1-(4-chloro-phenyl)-3-p-tolyl-triazene-1-carboxylic acid anilide
  参考文献：
  名称：

  MEASURING POVERTY AND DEPRIVATION IN SOUTH AFRICA

  摘要：

  This paper compares a standard expenditure‐based poverty measure with a specifically created composite measure of deprivation using household survey data from South Africa. While there is a strong overall correlation between expenditures and levels of deprivation, the correlation is much weaker among the worst‐off South Africans. In addition, the two measures differ considerably in the impact of race, headship, location (urban, rural), and household size on expenditure poverty versus deprivation. In general, the deprivation measure finds more Africans, rural dwellers, members of de facto female‐headed households, and members of smaller households deprived than expenditure poor. Only the differences in the effect of household size on poverty are sensitive to assumptions about equivalence scales. As a result, the two measures diverge greatly in identifying the poorest and most deprived sections of the population, which may have considerable consequences for targeting.

  DOI：

  10.1111/j.1475-4991.2000.tb00390.x
• 作为产物：
  描述：

  1,3-di(p-tolyl)triaz-1-ene 在 乙醇 、 sodium acetate 作用下， 生成 1-(p-chlorophenyl)-3-(p-tolyl)-triazene
  参考文献：
  名称：

  Heumann; Oeconomides, Chemische Berichte, 1887, vol. 20, p. 907

  摘要：

  DOI：

文献信息

• Multiwavelength spectrophotometric-thermodynamic studies of complexation reactions of newly synthesized triazenes with Hg2+, Pb2+, Zn2+, and Cd2+ in MeOH, EtOH, DMF, and DMSO
  作者：Mohammad Kazem Rofouei、Jahan B. Ghasemi、Leila Arjomandi-Behzad、Hassan Behnejad

  DOI：10.1016/j.molliq.2022.119145

  日期：2022.7

  at various temperatures. Stability constants (K1 and K2) and stoichiometries of formed adducts (1:1 and 1:2 ligand to metal ion) were calculated by computer refinement of experimental spectral mole ratio data by SQUAD program. The results indicated that the donor number, dielectric constant, the acceptor number of the solvents play an important role in the complex stability. Besides, the shape and size

  用分光光度法研究了Hg 2+、Pb 2+、Zn 2+和Cd 2+阳离子与四种新合成的三氮烯配体在不同温度下在非水溶剂（MeOH、EtOH、DMF 和DMSO）中的络合反应。通过 SQUAD 程序对实验光谱摩尔比数据进行计算机改进，计算了形成的加合物（1:1 和 1:2 配体与金属离子）的稳定性常数（K 1和 K 2 ）和化学计量。结果表明，溶剂的施主数、介电常数、受主数对配合物的稳定性有重要影响。此外，溶剂分子的形状和大小是研究反应的重要因素。对数 β 之间从图1和 log β 2可以看出，大多数配合物在不同条件下呈线性关系。Van't Hoff 方程用于根据地层常数对温度的依赖性计算 ΔG°、ΔS° 和 ΔH°。在计算不同温度下的热力学数据后，从 TΔS° - ΔH° 图中获得了良好的线性相关性，从而对络合反应进行了熵-焓补偿。
• Meldola; Streatfeild, Journal of the Chemical Society, 1889, vol. 55, p. 427
  作者：Meldola、Streatfeild

  DOI：——

  日期：——
• Stovpovoi, P. A.; Bagal, I. L.; El'tsov, A. V., Journal of general chemistry of the USSR, 1986, vol. 56, # 8, p. 1642 - 1654
  作者：Stovpovoi, P. A.、Bagal, I. L.、El'tsov, A. V.

  DOI：——

  日期：——
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Ag: MVol.B6, 1.16.5.4, page 300 - 300
  作者：

  DOI：——

  日期：——
• Meldola; Streatfeild, Journal of the Chemical Society, 1890, vol. 57, p. 786
  作者：Meldola、Streatfeild

  DOI：——

  日期：——