(E)-N,N-dimethyl-2-(styryloxy)ethanamine | 129126-30-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (E)-N,N-dimethyl-2-(styryloxy)ethanamine
• 英文别名: N,N-dimethyl-2-[(E)-2-phenylethenoxy]ethanamine
• CAS: 129126-30-3
• 化学式: C₁₂H₁₇NO
• 分子量: 191.273
• InChiKey: XMGREXCXPFEQPM-CSKARUKUSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.4
• 重原子数：
  14
• 可旋转键数：
  5
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  12.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  (E)-N,N-dimethyl-2-(styryloxy)ethanamine 、 (Z)-N,N-dimethyl-2-(styryloxy)ethanamine 以90%的产率得到
  参考文献：
  名称：

  Larhed Mats, Andersson Carl-Magnus, Hallberg Anders, Tetrahedron, 50 (1994) N 2, S 285-304

  摘要：

  DOI：
• 作为产物：
  描述：

  苯基三氟甲烷磺酸酯 、 B-二甲胺基乙基 乙烯基 醚 生成 (E)-N,N-dimethyl-2-(styryloxy)ethanamine
  参考文献：
  名称：

  Larhed Mats, Andersson Carl-Magnus, Hallberg Anders, Tetrahedron, 50 (1994) N 2, S 285-304

  摘要：

  DOI：

文献信息

• Chelation-controlled, palladium-catalyzed arylation of enol ethers with aryl triflates. Ligand control of selection for α-or β-arylation of [2-(dimethylamino)ethoxy]ethene.
  作者：Mats Larhed、Carl-Magnus Andersson、Anders Hallberg

  DOI：10.1016/s0040-4020(01)80755-9

  日期：1994.1

  Palladium-catalyzed arylation reactions of [2-(Dimethylamino)ethoxy]ethene (1) with a series of aryl triflates were performed under a variety of reaction conditions. In particular, the influence of phosphine ligands and halide additives on regioselectivity were studied. It was found that the chelation-controlled arylation of 1 affords an expedient route for the conversion of phenols into arylacetaldehydes

  在各种反应条件下，进行[2-（二甲基氨基）乙氧基]乙烯（1）与一系列芳基三氟甲磺酸酯的钯催化的芳基化反应。特别地，研究了膦配体和卤化物添加剂对区域选择性的影响。发现1的螯合控制的芳基化提供了将酚类转化为芳基乙醛的简便途径。或者，可以通过用双齿膦配体逆转区域选择性，将相同的起始原料用于合成苯乙酮。
• Liquid recording material
  申请人：——

  公开号：US20020081515A1

  公开（公告）日：2002-06-27

  A liquid recording material containing at least a carrier liquid, a resin, a coloring agent, and a reactive silicone material, an image transfer sheet for use with the liquid recording material, and a method of fixing images, using the liquid recording material, are disclosed.

  本发明公开了一种至少含有载液、树脂、着色剂和活性硅材料的液态记录材料，一种与液态记录材料配合使用的图像转印片材，以及一种使用液态记录材料固定图像的方法。
• Silicone-oil soluble polymer, image display medium using the silicone-oil soluble polymer and image display device using the image display medium
  申请人：——

  公开号：US20020146572A1

  公开（公告）日：2002-10-10

  An image display medium including: a pair of electroconductive layers, at least one of which is light-transmissive and which are opposed to each other to form a cell; and a dispersion contained in the cell and including a silicone oil; a colored particulate material dispersed in the silicone oil; and a polymer soluble in the silicone oil. The polymer preferably includes units obtained from a monomer having an acidic group or a basic group and a monomer having the following formula (1): 1 wherein R 1 represents a hydrogen atom or a methyl group; R 2 represents a hydrogen atom or an alkyl group having 1 to 4 carbon atoms; n is an integer; and x is an integer of from 1 to 3.

  一种图像显示介质，包括：一对导电层，其中至少有一层是透光的，它们相互对置形成一个单元；以及包含在单元中的分散体，包括硅油；分散在硅油中的有色颗粒材料；以及可溶于硅油的聚合物。聚合物最好包括由具有酸性基团或碱性基团的单体和具有下式（1）的单体得到的单元： 1 其中 R 1 代表氢原子或甲基； R 2 代表氢原子或具有 1 至 4 个碳原子的烷基；n 是整数；x 是 1 至 3 的整数。
• Electrophoretic composition, image display medium using same and image display device
  申请人：——

  公开号：US20030230487A1

  公开（公告）日：2003-12-18

  An electrophoretic composition in the form of a dispersion containing a dispersion medium, and electrophretic particles dispersed in the dispersion medium and having a color selected from white and non-white colors. The dispersion medium includes a non-polar solvent, a sulfonic acid compound soluble at least partly in said non-polar solvent, and a polymeric material soluble in said non-polar solvent.

  一种分散体形式的电泳组合物，含有分散介质和分散在分散介质中的电泳粒子，其颜色选自白色和非白色。分散介质包括非极性溶剂、至少部分溶于所述非极性溶剂的磺酸化合物和溶于所述非极性溶剂的聚合物材料。
• Kukharev, B. F.; Stankevich, V. K.; Klimenko, G. R., Russian Journal of Organic Chemistry, 1993, vol. 29, # 12, p. 2005 - 2012
  作者：Kukharev, B. F.、Stankevich, V. K.、Klimenko, G. R.

  DOI：——

  日期：——