6H-benzo[b]indeno[1,2-d]thiophene | 23339-79-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并噻吩类
• 英文名称: 6H-benzo[b]indeno[1,2-d]thiophene
• 英文别名: 6H-indeno[2,1-b][1]benzothiole
• CAS: 23339-79-9
• 化学式: C₁₅H₁₀S
• 分子量: 222.31
• InChiKey: WJXBPVFFGPFVTE-UHFFFAOYSA-N

物化性质

• 熔点：
  112-113 °C
• 沸点：
  396.8±11.0 °C(Predicted)
• 密度：
  1.292±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.6
• 重原子数：
  16
• 可旋转键数：
  0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.07
• 拓扑面积：
  28.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  6H-benzo[b]indeno[1,2-d]thiophene 在 aluminum (III) chloride 、 正丁基锂 作用下， 以 四氢呋喃 、 硝基甲烷 、 正己烷 为溶剂， 生成
  参考文献：
  名称：

  리간드 화합물, 전이금속 화합물 및 이를 포함하는 촉매 조성물

  摘要：

  This invention relates to novel ligand compounds, transition metal compounds, and catalyst compositions containing them, which can be useful as catalysts in the production of low-density olefinic polymers. The olefin polymers polymerized using the catalyst composition containing the transition metal compound can be used to produce high molecular weight products with low melt index (MI).

  公开号：

  KR20200101701A
• 作为产物：
  描述：

  benzothiophen-2-yllithium 在 三氯化铝 作用下， 以 二硫化碳 、 乙醚 为溶剂， 生成 6H-benzo[b]indeno[1,2-d]thiophene
  参考文献：
  名称：

  Study of some thiophene analogs of glycolic acid

  摘要：

  DOI：

  10.1021/jo00327a009

文献信息

• 실런트 경화용 가습 장치
  申请人：SAM HEUNG PRECISION CO.,LTD. 삼흥정공 주식회사(120010140072) Corp. No ▼ 194211-0042424

  公开号：KR20190001917U

  公开（公告）日：2019-07-29

  본 고안은 실런트 주위로 온풍과 함께 가열된 온수를 미세 수증기 형태로 분사함으로써, 주위 온습도 환경에 관계없이 항시 최적의 실런트 경화 조건을 충족시킬 수 있는 실런트 경화용 가습 장치에 관한 것이다.

  这项发明涉及一种用于实时固化的加湿装置，通过将预热的热水与环绕的热风一起喷射成微细水蒸气形式，以满足实时固化条件的最佳要求，无论周围的温湿度环境如何。
• 자동차 핸들용 논슬립 패드 구조체
  申请人：PARK IN KUK 박인국(420180033649)

  公开号：KR20190001918U

  公开（公告）日：2019-07-29

  본 고안에 의하면, 신축성을 가지는 논슬립패드; 논슬립패드의 하면에 도포되는 프라이머층; 프라이머층의 하면에 부착되고 자동차 핸들의 피착면에 부착되거나 피착면으로부터 박리되는 점착제층; 및 점착제층의 하면에 부착되어 점착제층을 보호하는 박리지를 포함하는 자동차 핸들용 논슬립 패드 구조체가 제공된다.

  根据该方案，提供了一种具有弹性的防滑垫；在防滑垫的底部涂覆有底漆层；附着在底漆层底部并粘附在汽车方向盘的握持面或从握持面剥离的粘合剂层；以及附着在粘合剂层底部以保护粘合剂层的剥离纸的汽车方向盘用防滑垫结构。
• Synthesis of cyclopentadiene derivatives
  申请人：Nifant'ev Ilya E.

  公开号：US20080287692A1

  公开（公告）日：2008-11-20

  A compound of formula (X): wherein R 1 , R 2 , equal to or different from each other are hydrogen or a linear or branched saturated or unsaturated C 1 -C 20 -alkyl, C 3 -C 20 -cycloalkyl, C 6 -C 20 -aryl, C 7 -C 20 -alkylaryl or C 7 -C 20 -arylalkyl radical, optionally containing heteroatoms belonging to groups 13-17 of the Periodic Table of the Elements; or they can form a C 4 -C 7 ring optionally containing O, S, N, P or Si atoms that can bear substituents; R 3 is hydrogen or a linear or branched saturated or unsaturated C 1 -C 20 -alkyl, C 3 -C 20 -cycloalkyl, C 6 -C 20 -aryl, C 7 -C 20 -alkylaryl or C 7 -C 20 -arylalkyl radical, optionally containing heteroatoms belonging to groups 13-17 of the Periodic Table of the Elements; or two adjacent R 3 groups can form a C 4 -C 7 ring optionally containing O, S, N, P or Si atoms, wherein said ring can bear substituents; and at least one of R 1 , R 2 or R 3 is different from hydrogen.

  化合物的化学式为(X)，其中R1，R2可以相同也可以不同，它们是氢原子或线性或支链饱和或不饱和的C1-C20烷基，C3-C20环烷基，C6-C20芳基，C7-C20烷基芳基或C7-C20芳基烷基基团，可选地含有周期表元素13-17组的杂原子；或它们可以形成一个C4-C7环，可选地含有O、S、N、P或Si原子，该环可以带有取代基；R3是氢原子或线性或支链饱和或不饱和的C1-C20烷基，C3-C20环烷基，C6-C20芳基，C7-C20烷基芳基或C7-C20芳基烷基基团，可选地含有周期表元素13-17组的杂原子；或相邻的两个R3基团可以形成一个C4-C7环，可选地含有O、S、N、P或Si原子，该环可以带有取代基；R1、R2或R3中至少有一个不是氢原子。
• Dihydrobenzo (B) indeno (2,1-D) thiophene compounds, intermediates, processes, compositions, and methods
  申请人：ELI LILLY AND COMPANY

  公开号：EP0832891A1

  公开（公告）日：1998-04-01

  The invention provides dihydrobenzo[b]indenothiophene compounds, intermediates, processes, formulations, and methods of inhibiting bone loss or bone resorption, particularly osteoporosis, cardiovascular-related pathological conditions including hyperlipidemia and related cardiovascular pathologies, and estrogen-dependent cancer.

  本发明提供了二氢苯并[b]茚并噻吩化合物、中间体、工艺、制剂以及抑制骨丢失或骨吸收（尤其是骨质疏松症）、心血管相关病症（包括高脂血症和相关心血管病症）和雌激素依赖性癌症的方法。
• Efficient Method for the Synthesis of Hetarenoindanones Based on 3-Arylhetarenes and Their Conversion into Hetarenoindenes
  作者：Igor A. Kashulin、Ilya E. Nifant'ev

  DOI：10.1021/jo049504w

  日期：2004.8.1

  A series of hetarenoindanones have been prepared by direct double metalation of the appropriate 3-phenylhetarene with butyllithium in the presence of TMEDA followed by treatment of the resulting dilithium compound with ethyl NiV-dimethylcarbamate. All hetarenoindanones were reduced according to Wolff-Kishner by hydrazine in the presence of KOH to the corresponding hetarenoindenes.