1-phenyl-3-((dimethylamino)styryl)-5-((dimethylamino)phenyl)-2-pyrazoline | 2564-18-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1-phenyl-3-((dimethylamino)styryl)-5-((dimethylamino)phenyl)-2-pyrazoline
• 英文别名: benzenamine, 4-[2-[5-[4-(dimethylamino)phenyl]-4,5-dihydro-1-phenyl-1H-pyrazol-3-yl]ethenyl]-N,N-dimethyl-；4-[(E)-2-[3-[4-(dimethylamino)phenyl]-2-phenyl-3,4-dihydropyrazol-5-yl]ethenyl]-N,N-dimethylaniline
• CAS: 2564-18-3
• 化学式: C₂₇H₃₀N₄
• 分子量: 410.562
• InChiKey: YJXSVVJXMDQNKF-XNTDXEJSSA-N

物化性质

• 熔点：
  192 °C(Solv: ethyl acetate (141-78-6))
• 沸点：
  590.3±60.0 °C(Predicted)
• 密度：
  1.06±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5.7
• 重原子数：
  31
• 可旋转键数：
  6
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.22
• 拓扑面积：
  22.1
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  2-甲基-2-戊烯 、 1-phenyl-3-((dimethylamino)styryl)-5-((dimethylamino)phenyl)-2-pyrazoline 在 rose bengal 氧气 作用下， 以 甲醇 、 苯 为溶剂， 反应 0.17h， 生成 2-甲基-1-戊烯-3-醇 、 反-2-甲基-3-戊烯-2-醇
  参考文献：
  名称：

  Quenching of singlet oxygen by 1,3,5-triaryl-2-pyrazolines

  摘要：

  DOI：

  10.1021/jo00152a025
• 作为产物：
  描述：

  1,4-戊二烯-3-酮,1,5-二[4-(二甲氨基)苯基]-,(1E,4E)- 、 苯肼,盐酸盐 在 盐酸 作用下， 以 乙醇 、 氯仿 为溶剂， 反应 3.0h， 生成 1-phenyl-3-((dimethylamino)styryl)-5-((dimethylamino)phenyl)-2-pyrazoline
  参考文献：
  名称：

  抗菌药物和抗菌药物：第1部分：2-吡唑啉衍生物的合成和活性。

  摘要：

  在催化剂量的催化下，将取代的α，β-不饱和酮与盐酸苯肼缩合，合成了一系列不同取代度的3-苯乙烯基-1,5-二苯基和5-苯乙烯基-1,3-二苯基2-吡唑啉。浓盐酸。3-苯乙烯基系列的化合物具有OMe，NMe2，NO2，OH和异丙基取代基，而5-苯乙烯基系列的化合物具有OMe，NMe2和NOs。就几何平均最小抑制浓度（MIC）而言，3-苯乙烯基-1,5-二苯基化合物对革兰氏阳性和革兰氏阴性细菌的抗菌活性几乎没有变化。发现4'，4“ -NMe2、4'，4” -NO2和4'，4“ -OMe化合物具有最高的活性。5-styryl-1,3-diphenyl系列的活性较低。比三苯乙烯系列。

  DOI：

  10.1248/cpb.46.1254

文献信息

• Organic photoconductor
  申请人：IMPERIAL CHEMICAL INDUSTRIES PLC

  公开号：EP0262761A1

  公开（公告）日：1988-04-06

  An organic photoconductor suitable for use in electroreprography comprising an electrically conducting support, a charge generating phase comprising a charge generator and a charge transport phase characterised in that the charge generator is a phthalocyanine compound in which each of at least four of the peripheral carbon atoms numbered from 1 to 16 in the phthalocyanine nucleus shown below is linked, by an atom from Group VA of Group VIA of the Periodic Table, to a carbon atom of an organic radical.

  一种适用于电泳的有机光电导体，包括一个导电支架、一个由电荷发生器组成的电荷发生相和一个电荷传输相，其特征在于电荷发生器是一种酞菁化合物，在该化合物中，下图所示酞菁核中编号为1至16的至少四个外围碳原子中的每一个都通过一个来自元素周期表VIA族VA组的原子与一个有机基的碳原子相连。
• Alpha-type titanyl phthalocyanine composition, method for production thereof, and electrophotographic sensitive material using same
  申请人：MITA INDUSTRIAL CO. LTD.

  公开号：EP0314100A2

  公开（公告）日：1989-05-03

  The first aspect of this invention resides in providing an α-type titanyl phthalocyanine composition comprising an α-type titanyl phthalocyanine and metal-­free phthalocyanine. This α-type titanyl phthalocyanine composition is stable, wide in range of absorption wavelengths, and high in spectral sensitivity because it contains an α-type titanyl phthalocyanine in combination with metal-free phthalocyanine. The second aspect of this invention resides in providing a method for the production of an α-type titanyl phthalocyanine composition comprising an α-type titanyl phthalocyanine and a metal-free phthalocyanine, which method comprises pigmenting a concentrated sulfuric acid solution containing at least titanyl phthalocyanine by the acid paste process consisting in pouring said concentrated sulfuric acid solution into water. By this method, an α-type titanyl phthalocyanine composition stable to withstand the impact of aging can be easily produced. The third aspect of this invention resides in providing an electrophotographic sensitive material having superposed on an electroconductive substrate a sensitive layer comprising an α-type titanyl phthalo­cyanine and a metal-free phthalocyanine. This electro­ photographic sensitive material excels in charging property and dark attenuation property and exhibits high sensitivity and sparing residual potential. The fourth aspect of this invention resides in providing an electrophotographic sensitive material having superposed on an electroconductive substrate a sensitive layer comprising an α-type titanyl phthalocyanine composition and an electric charge transferring material exhibiting oxidation potential in the range of 0.45 to 0.65 eV. This electrophotographic sensitive material enjoys high sensitivity and shows sparing residual potential.

  本发明的第一个方面是提供一种由α型钛酞菁和无金属酞菁组成的α型钛酞菁组合物。这种 α 型钛酞菁组合物稳定，吸收波长范围宽，光谱灵敏度高，因为它含有 α 型钛酞菁和无金属酞菁。 本发明的第二个方面是提供一种生产由 α 型钛酞菁和无金属酞菁组成的 α 型钛酞菁组合物的方法，该方法包括通过酸浆工艺将至少含有钛酞菁的浓硫酸溶液颜料化，酸浆工艺包括将所述浓硫酸溶液倒入水中。通过这种方法，可以很容易地生产出稳定的 α 型钛酞菁组合物，以抵御老化的影响。 本发明的第三个方面是提供一种电致发光感光材料，它在导电基底上叠加了由 α 型钛酞菁和无金属酞菁组成的感光层。这种电致发光感光材料具有优异的充电性能和暗衰减性能，并表现出高灵敏度和无残留电位。 本发明的第四个方面是提供一种电致发光感光材料，该材料在导电基底上叠加有感光层，感光层由 α 型钛酞菁成分和电荷转移材料组成，电荷转移材料的氧化电位在 0.45 至 0.65 eV 之间。这种电致发光感光材料灵敏度高，残留电位低。
• Electrophotographic photoreceptor, process for producing the same, and image forming apparatus using same
  申请人：Sharp Kabushiki Kaisha

  公开号：EP0926557A1

  公开（公告）日：1999-06-30

  The invention enables the forming of a highly characteristic image using an electrophotographic photoreceptor the charge-generating layer of which can be produced with better coating properties and which is highly sensitive and electrostatically highly stable in repeated use. The charge-generating layer of a function-separated type photoreceptor contains a τ-type non-metallic phthalocyanine and a vinyl chloride-vinyl acetate copolymer. The weight ratio of τ-type non-metallic phthalocyanine to the vinyl chloride-vinyl acetate copolymer is preferably 1/3 to 3/1 by weight and the copolymer is suitably of vinyl chloride and vinyl acetate, vinyl chloride, vinyl acetate and maleic acid or vinyl chloride, vinyl acetate and vinyl alcohol, especially one containing at least 10% by weight of vinyl alcohol.

  本发明可使用电致发光感光器形成高特征图像，该感光器的电荷发生层具有更好的涂层性能，在重复使用时具有高灵敏度和高静电稳定性。功能分离型感光器的电荷发生层含有τ型非金属酞菁和氯乙烯-醋酸乙烯共聚物。τ型非金属酞菁与氯乙烯-醋酸乙烯共聚物的重量比最好为 1/3 至 3/1（重量比），共聚物最好是氯乙烯和醋酸乙烯、氯乙烯、醋酸乙烯和马来酸或氯乙烯、醋酸乙烯和乙烯醇，特别是含有至少 10%（重量比）乙烯醇的共聚物。
• Mixture of titanyltetraazaporphyrin compounds and electrophotographic photoconductor using the same
  申请人：Ricoh Company, Ltd.

  公开号：US20020007056A1

  公开（公告）日：2002-01-17

  A mixture is made of a plurality of different titanyltetraazaporphyrin compounds, each of which is represented by formula (1): 1 wherein A, B, C and D are each independently an unsubstituted or substituted benzene ring or pyridine ring, a substituent thereof being selected from the group consisting of nitro group, cyano group, a halogen atom, an alkyl group having 1 to 8 carbon atoms, an alkoxyl group having 1 to a carbon atoms, and an aryl group. The above-mentioned mixture is contained in a photoconductive layer of an electrophotographic photoconductor as a photoconductive material.

  由多种不同的钛四氮杂卟啉化合物制成的混合物，每种化合物都用式（1）表示： 1 其中 A、B、C 和 D 各自独立地为未取代或取代的苯环或吡啶环，其取代基可选 自硝基、氰基、卤素原子、1 至 8 个碳原子的烷基、1 至 1 个碳原子的烷氧基和芳基。上述混合物作为光导材料包含在电子照相光电导体的光导层中。
• Reaction product, process for the production thereof, electrophotographic photoconductor using the reaction product, electrophotographic apparatus using the photoconductor, and process cartridge for electrophotographic apparatus
  申请人：Ricoh Company, Ltd.

  公开号：US20030013028A1

  公开（公告）日：2003-01-16

  [Problem] To provide a novel reaction product useful as an organic photoconductive material for electrophotographic photoconductors. [Means for Solution] A product obtainable by reacting (i) a nitrile derivative, (ii) a phthalonitrile derivative or a 1,3-diiminoisoindoline derivative and, if necessary, (iii) a metal or a metal-containing compound.

  问题] 提供一种新型反应产物，可用作电子照相光电导体的有机光电导材料。 腈衍生物、酞腈衍生物或 1,3-二亚氨基异吲哚啉衍生物和（必要时）金属或含金属化合物反应而得到的产物。