3,3',5,5'-tetrakis(1,1,3,3-tetramethylbutyl)-2,2'-dihydroxy-1,1'-biphenyl | 80198-31-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 3,3',5,5'-tetrakis(1,1,3,3-tetramethylbutyl)-2,2'-dihydroxy-1,1'-biphenyl
• 英文别名: 2,2'-dihydroxy-3,3',5,5'-tetra-(1,1,3,3-tetramethylbutyl)-biphenyl；2-[2-Hydroxy-3,5-bis(2,4,4-trimethylpentan-2-yl)phenyl]-4,6-bis(2,4,4-trimethylpentan-2-yl)phenol
• CAS: 80198-31-8
• 化学式: C₄₄H₇₄O₂
• 分子量: 635.07
• InChiKey: IFWFBTUMAFEHGV-UHFFFAOYSA-N

物化性质

• 沸点：
  631.4±55.0 °C(Predicted)
• 密度：
  0.930±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  16.4
• 重原子数：
  46
• 可旋转键数：
  13
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.73
• 拓扑面积：
  40.5
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  3,3',5,5'-tetrakis(1,1,3,3-tetramethylbutyl)-2,2'-dihydroxy-1,1'-biphenyl 、 二氯二甲基锗 在 三乙胺 作用下， 以 甲苯 为溶剂， 以43%的产率得到2,4,8,10-tetrakis(1,1,3,3-tetramethylbutyl)-6,6-methyl-dibenzo(d,f)(1,3,2)dioxagermepin
  参考文献：
  名称：

  The Synthesis and Conformation of Sterically Congested Seven-membered Rings Containing Tetracoordinate Germanium(IV):  Determination of the ΔG* For Ring Inversion¹

  摘要：

  DOI：

  10.1021/ic010180t

文献信息

• Hindered bis-phenol phenyl phosphites and synthetic resin compositions having enhanced stability to heat and light
  申请人：ADEKA ARGUS CHEMICAL CO., Ltd.

  公开号：EP0032681A2

  公开（公告）日：1981-07-29

  Hindered bis-phenol phenyl phosphites are provided having the structure: wherein: R is selected from the group consisting of alkyl having from one up to about eighteen carbon atoms; cycloalkyl having from three up to about twelve carbon atoms; alkaryl and aryl having from six to about eighteen carbon atoms; preferably, a bulky group such as iso, secondary or tertiary alkyl having from three to about ten carbon atoms; or cycloalkyl having six to twelve carbon atoms; R, and R2 are each selected from the group consisting of hydrogen; alkyl having from one to about eighteen carbon atoms; cycloalkyl having from three up to about twelve carbon atoms; alkaryl and aryl having from six to about eighteen carbon atoms; and are preferably in a position ortho to a phenolic hydroxyl or phenoxy group, if available; R3 is alkylene having from one to about six carbon atoms; R4 is selected from the group consisting of alkylene, cycloalkylene, and aralkylene, the residue of a monohydric or polyhydric alcohol, having from one to about eighteen carbon atoms, and from none to three hydroxyl groups (originally one to four hydroxyl groups); Y is selected from the group consisting of a direct carbon to carbon bond; thio sulfur -S-; oxy oxygen -0-; alkylidene having from one to about six carbon atoms; and cycloalkylidene having from four to about eight carbon atoms; and n is 1, 2, 3, or 4, according to the valence of R4; as well as synthetic resin compositions having an enhanced resistance to deterioration by heat and/or light due to the presence of an organic phosphite of this class.

  提供了具有以下结构的受阻双酚苯基磷酸盐： 其中 R 选自具有 1 至约 18 个碳原子的烷基、具有 3 至约 12 个碳原子的环烷基、具有 6 至约 18 个碳原子的芳基和芳烷基组成的组中；最好是具有 3 至约 10 个碳原子的大块基团，如异烷基、仲烷基或叔烷基；或具有 6 至 12 个碳原子的环烷基； R和R2各自选自由氢、具有 1 至约 18 个碳原子的烷基、具有 3 至约 12 个碳原子的环烷基、具有 6 至约 18 个碳原子的烷芳基和芳基组成的组，且最好位于酚羟基或酚氧基的正交位置（如有）； R3 是具有 1 至约 6 个碳原子的亚烷基； R4 选自由烷基、环烷基、芳烷基、一元醇或多元醇的残余物组成的组，具有 1 至约 18 个碳原子，无至 3 个羟基（最初为 1 至 4 个羟基）； Y 选自以下组别：碳-碳直接键；硫-硫-S-；氧-氧-0-；具有一至六个碳原子的亚烷基；以及具有四至八个碳原子的亚环烷基；以及 根据 R4 的化合价，n 为 1、2、3 或 4；以及合成树脂组合物，由于该类有机亚磷酸酯的存在，其耐热和/或耐光性得到增强。
• Pastor, Stephen D.; Spivack, John D.; Steinhuebel, L. P., Phosphorus and Sulfur and the Related Elements, 1983, vol. 15, p. 253 - 256
  作者：Pastor, Stephen D.、Spivack, John D.、Steinhuebel, L. P.、Matzura, Cynthia

  DOI：——

  日期：——
• PASTOR, S. D.;SPIVACK, J. D.;STEINHUEBEL, L. P.;MATZURA, C., PHOSPH. AND SULFUR, 1983, 15, N 2, 253-256
  作者：PASTOR, S. D.、SPIVACK, J. D.、STEINHUEBEL, L. P.、MATZURA, C.

  DOI：——

  日期：——
• Verfahren zur Herstellung von 2,2'-Dihydroxybiphenyl-Verbindungen
  申请人：CIBA-GEIGY AG

  公开号：EP0035965B1

  公开（公告）日：1983-05-18
• VERFAHREN ZUR HERSTELLUNG VON 6-CHLORODIBENZO [D,F][1,3,2]DIOXAPHOSPHEPIN
  申请人：BASF SE

  公开号：EP2797938A1

  公开（公告）日：2014-11-05