1-chloro-3,3,5,5-tetraphenyl-λ⁴-thia-2,4,6-triaza-3λ⁵,5λ⁵-diphosphorine | 84247-67-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1-chloro-3,3,5,5-tetraphenyl-λ⁴-thia-2,4,6-triaza-3λ⁵,5λ⁵-diphosphorine
• 英文别名: 1-Chloro-3,3,5,5-tetraphenyl-1lambda4-thia-2,4,6-triaza-3lambda5,5lambda5-diphosphacyclohexa-1,3,5-triene；1-chloro-3,3,5,5-tetraphenyl-1λ4-thia-2,4,6-triaza-3λ5,5λ5-diphosphacyclohexa-1,3,5-triene
• CAS: 84247-67-6
• 化学式: C₂₄H₂₀ClN₃P₂S
• 分子量: 479.909
• InChiKey: GOYKXGOPSDDUAY-UHFFFAOYSA-N

物化性质

• 密度：
  1.36±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  9
• 重原子数：
  31
• 可旋转键数：
  4
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  56.3
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  1-chloro-3,3,5,5-tetraphenyl-λ⁴-thia-2,4,6-triaza-3λ⁵,5λ⁵-diphosphorine 生成 amino-(diphenylphosphinimylamino)-diphenylphosphanium,chloride
  参考文献：
  名称：

  1-Chloro-3,3,5,5-tetraphenyl-λ⁴-thia-2,4,6-triaza-3λ⁵,5λ⁵-diphosphorine; preparation, X-ray crystal structure, and conversion into a tricyclic PSN ring

  摘要：

  氯二苯基膦与乙腈中的S4N4反应生成六元杂环（Ph2PN）2NSCl，在Me3SiNSNSiMe3的作用下转化为三环环；这些新的PSN环系统的结构已通过X射线晶体学测定。

  DOI：

  10.1039/c39820000982
• 作为产物：
  描述：

  N,N-双(二苯磷)胺 在 氯 作用下， 以 乙腈 为溶剂， 反应 0.5h， 生成 1-chloro-3,3,5,5-tetraphenyl-λ⁴-thia-2,4,6-triaza-3λ⁵,5λ⁵-diphosphorine
  参考文献：
  名称：

  Heterocyclic 1,2,4,6-thia- and 1,2,4,6-selenatriazinyl radicals: spin distributions and modes of association

  摘要：

  DOI：

  10.1021/ja00162a026

文献信息

• Preparation and X-ray crystal structure of 3,3,5,5,9,9,11,11-octaphenyl-1,7-di-λ⁴-thia-2,4,6,8,10,12-hexa-aza-3,5,9,11-tetra-λ⁵-phosphabicyclo[5.5.0]dodecahexene: a twelve-membered inorganic heterocycle with a transannular sulphur–sulphur bond
  作者：Tristram Chivers、M. N. Sudheendra Rao、John F. Richardson

  DOI：10.1039/c39830000186

  日期：——

  The reaction of the six-membered ring compound (Ph2PN)2NSCl with triphenylantimony is acetonitrile produces (Ph2PN)4(SN)2 shown by X-ray crystallography to consist of a twelve-membered ring with a transannular sulphur–sulphur bond.

  X射线晶体学显示，六元环化合物（Ph 2 PN）2 NSCl与三苯基锑的反应是乙腈生成的（Ph 2 PN）4（SN）2由十二元环和环戊硫组成。硫键。
• Formation and X-ray structural characterization of a twelve-membered P4S2N6 ring in the thermal conversion of a P2SN3 ring into the P4SN6 spirocycle
  作者：Tristram Chivers、M. N. Sudheendra Rao、John F. Richardson

  DOI：10.1039/c39830000702

  日期：——

  The thermal conversion of (Ph2PN)2NSNMe2 at 150–185 °C into the spirocyclic compound Ph8P4N6S occurs via a twelve-members ring whose structure has been determined by X-ray crystallography.

  （Ph 2 PN）2 NSNMe 2在150–185°C时通过十二元环热转化为螺环化合物Ph 8 P 4 N 6 S ，该环的结构已通过X射线晶体学确定。
• An inorganic heterocycle containing an exocyclic sulphur–iodine bond: synthesis and X-ray crystal structure of (Ph₂PN)₂NSI and its thermal conversion into a spirocyclic P₄SN₆ring
  作者：Tristram Chivers、M. N. Sudheendra Rao、John F. Richardson

  DOI：10.1039/c39830000700

  日期：——

  The reaction of (Ph2PN)2NSCI with KI in acetonitrile produces (Ph2PN)2NSI which is shown by X-ray crystallography to contain a six-membered P2SN3 ring with an exocyclic S–I bond; the thermal decomposition of (Ph2PN)2NSI leads to Ph8P4SN6, a spirocyclic compound in which two P2SN3 rings share a common sulphur atom.

  (Ph2PN)2NSCI与KI在乙腈中反应生成(Ph2PN)2NSI，X射线晶体学显示，(Ph2PN)2NSI包含一个具有外环SâI键的六元P2SN3环；(Ph2PN)2NSI热分解生成Ph8P4SN6，这是一种螺环化合物，其中两个P2SN3环共享一个共同的硫原子。
• Chivers, Tristram; Rao, M. N. Shudheendra, Canadian Journal of Chemistry, 1983, vol. 61, p. 1957 - 1962
  作者：Chivers, Tristram、Rao, M. N. Shudheendra

  DOI：——

  日期：——
• CHIVERS, TRISTRAM;DHATHATHREYAN, KAVERIPATNAM S.;LIBLONG, STEPHEN W.;PARK+, INORG. CHEM., 27,(1988) N 7, 1305-1307
  作者：CHIVERS, TRISTRAM、DHATHATHREYAN, KAVERIPATNAM S.、LIBLONG, STEPHEN W.、PARK+

  DOI：——

  日期：——