1,19-nonadecane diamine | 13439-54-8

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 1,19-nonadecane diamine
• 英文别名: Nonadecane-1,19-diamine
• CAS: 13439-54-8
• 化学式: C₁₉H₄₂N₂
• 分子量: 298.556
• InChiKey: VCAISILSXYFPGO-UHFFFAOYSA-N

物化性质

• 沸点：
  377.3±10.0 °C(Predicted)
• 密度：
  0.854±0.06 g/cm3(Temp: 20 °C; Press: 760 Torr)(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  6.8
• 重原子数：
  21
• 可旋转键数：
  18
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  52
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  油酸甲酯 在 甲烷磺酸 、 (6-(di-tert-butylphosphinomethylene)-2-(N,N-diethylaminomethyl)-1,6-dihydropyridine)Ru(H)(CO) 、 氯羰基氢化物[4,5-双-（二-i-丙基膦甲基）吖啶]钌（II） 、 氨 、 氢气 、 palladium diacetate 、 ALPHA,ALPHA'双(二叔丁基膦)邻二甲苯 作用下， 以 1,4-二氧六环 、 2-甲基-2-丁醇 为溶剂， 80.0~140.0 ℃ 、3.0 MPa 条件下， 反应 118.0h， 生成 1,19-nonadecane diamine
  参考文献：
  名称：

  α，ω功能化的C19单体

  摘要：

  高油酸葵花籽油是一种可再生资源，已被有效地纳入可持续和绿色化学过程：α，ω-官能化C19单体的合成。这些单体衍生自1,19-壬二酸二甲酯二甲酯，是一种新型的平台化学品，可以用作聚合物工业的原料。

  DOI：

  10.1002/cssc.201100187

文献信息

• α,ω-Functionalized C19 Monomers
  作者：Guido Walther、Jens Deutsch、Andreas Martin、Franz-Erich Baumann、Dirk Fridag、Robert Franke、Angela Köckritz

  DOI：10.1002/cssc.201100187

  日期：2011.8.22

  High‐oleic sunflower oil, a renewable resource, is efficiently incorporated into a sustainable and green chemical process: the synthesis of α,ω‐functionalized C19 monomers. These monomers, derived from dimethyl 1,19‐nonadecanedioate as a novel platform chemical, may find use as feedstock materials for the polymer industry.

  高油酸葵花籽油是一种可再生资源，已被有效地纳入可持续和绿色化学过程：α，ω-官能化C19单体的合成。这些单体衍生自1,19-壬二酸二甲酯二甲酯，是一种新型的平台化学品，可以用作聚合物工业的原料。
• Diamines for Polymer Materials via Direct Amination of Lipid- and Lignocellulose-based Alcohols with NH₃
  作者：Dennis Pingen、Judith B. Schwaderer、Justus Walter、Jiaqi Wen、George Murray、Dieter Vogt、Stefan Mecking

  DOI：10.1002/cctc.201800365

  日期：2018.7.19

  catalytic direct amination of long‐chain diols, derived from plant oils. High conversion was achieved with good selectivity, with the amount of nitrile impurities formed suppressed to a low level. From the lignocellulose‐based 5‐hydroxymethylfurfural (5‐HMF), or from bis(hydroxymethyl)furan, 2,5‐bis(aminomethyl)furan (BAMF) was generated. 5‐HMF was converted in a one‐pot, one‐step direct amination and reductive

  通过全催化途径，通过衍生自植物油的长链二醇的催化直接胺化来制备长链二胺。以良好的选择性实现了高转化率，并且将形成的腈杂质的量抑制到较低的水平。从木质纤维素基的5-羟甲基糠醛（5-HMF）或双（羟甲基）呋喃中生成了2,5-双（氨基甲基）呋喃（BAMF）。使用氨将5-HMF一步一步转化为直接胺化和还原胺化反应。在两种情况下，反应都非常有效地进行。在组合胺化和还原胺化中，H 2浓度是一个速率限制因素。降低H 2的分压也大大缩短了所需的反应时间。长链二胺与长链二酸的缩聚反应产生了更高分子量的聚酰胺，这说明了通过这种合成方法获得的二胺作为单体的质量。
• [EN] PHOSPHINYL AMIDINE COMPOUNDS, METAL COMPLEXES, CATALYST SYSTEMS, AND THEIR USE TO OLIGOMERIZE OR POLYMERIZE OLEFINS<br/>[FR] COMPOSÉS DE PHOSPHINYLAMIDINE, COMPLEXES DE MÉTAL, SYSTÈMES DE CATALYSEUR, ET LEUR UTILISATION POUR OLIGOMÉRISER OU POLYMÉRISER DES OLÉFINES
  申请人：CHEVRON PHILLIPS CHEMICAL CO

  公开号：WO2011082192A1

  公开（公告）日：2011-07-07

  N2-phosphinyl amidine compounds, N2-phosphinyl amidinates, N2-phosphinyl amidine metal salt complexes, N2-phosphinyl amidinate metal salt complexes are described. Methods for making N2-phosphinyl amidine compounds, N2-phosphinyl amidinates, N2-phosphinyl amidine metal salt complexes, and N2-phosphinyl amidinate metal salt complexes are also disclosed. Catalyst systems utilizing the N2-phosphinyl amidine metal salt complexes and N2-phosphinyl amidinate metal salt complexes are also disclosed along with the use of the N2-phosphinyl amidine compounds, N2-phosphinyl amidinates, N2-phosphinyl amidine metal salt complexes, and N2-phosphinyl amidinate metal salt complexes for the oligomerization and/or polymerization of olefins.

  描述了N2-膦胺化合物、N2-膦胺酸盐、N2-膦胺金属盐络合物、N2-膦胺酸盐金属盐络合物。还公开了制备N2-膦胺化合物、N2-膦胺酸盐、N2-膦胺金属盐络合物和N2-膦胺酸盐金属盐络合物的方法。还公开了利用N2-膦胺金属盐络合物和N2-膦胺酸盐金属盐络合物的催化剂系统，以及利用N2-膦胺化合物、N2-膦胺酸盐、N2-膦胺金属盐络合物和N2-膦胺酸盐金属盐络合物进行烯烃的寡聚和/或聚合的用途。
• PREPARATION OF PRIMARY DIAMINES HAVING A LINEAR MAIN CHAIN FOR POLYAMIDE SYNTHESES
  申请人：Baumann Franz-Erich

  公开号：US20120203033A1

  公开（公告）日：2012-08-09

  The invention provides a method to produce primary diamines by catalytic conversion of diols having a linear main chain of from 4 to 31 carbon atoms into the corresponding diamines. The reaction is conducted in a liquid or supercritical phase and is catalyzed by a homogeneous ruthenium-containing complex. The primary diamines obtained may be suitable for polyamide syntheses.

  该发明提供了一种方法，通过催化将具有4至31个碳原子的线性主链的二醇转化为相应的二胺来生产主要二胺。反应在液态或超临界相中进行，并由均相钌含配合物催化。得到的主要二胺可能适用于聚酰胺合成。
• FUNCTIONALIZED HIGHLY BRANCHED MELAMINE-POLYAMINE POLYMERS
  申请人：Peretolchin Maxim

  公开号：US20120252987A1

  公开（公告）日：2012-10-04

  The present invention relates to a method for producing amphiphilic functionalized highly branched melamine-polyamine polymers by condensing melamine and optionally a melamine derivate having at least one different amine having at least two primary amino groups and optionally also with urea and/or at least one urea derivative and/or with at least one at least difunctional diisocyanate or polyisocyanate and/or at least one carbolic acid having at least two carboxyl groups or at least one derivative thereof, optionally quaternizing a portion of the amino groups of the polymer thereby obtained, reacting the polymer thus obtained with at least one compound capable of undergoing a condensation or addition reaction with amino groups, and optionally quaternizing at least part of the amino groups of the polymer obtained in the first step. The invention further relates to the amphiphilic functionalized highly branched melamine-polyamine polymers that can be obtained by the method according to the invention, and to the use thereof as surface active agents.

  本发明涉及一种通过将三聚氰胺和至少一种具有至少两个主要氨基的不同氨基的三聚氰胺衍生物以及可能还包括尿素和/或至少一种尿素衍生物和/或至少一种至少双官能团二异氰酸酯或多异氰酸酯和/或至少一种至少具有两个羧基的羧酸或其衍生物缩合，从而制备含有两性功能化的高支化三聚氰胺-多胺聚合物的方法。可选地，对所获得的聚合物的部分氨基进行季铵化，然后将所获得的聚合物与至少一种能够与氨基发生缩合或加成反应的化合物反应，并可选地对第一步中获得的聚合物的部分氨基进行季铵化。本发明还涉及通过本发明的方法可以获得的含有两性功能化的高支化三聚氰胺-多胺聚合物，以及将其用作表面活性剂的用途。