2-(2-methyl-1,3-dioxolan-2-yl-methoxy)phenylsulfonamide | 87483-74-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2-(2-methyl-1,3-dioxolan-2-yl-methoxy)phenylsulfonamide
• 英文别名: 2-[(2-methyl-1,3-dioxolan-2-yl)methoxy]benzenesulfonamide
• CAS: 87483-74-7
• 化学式: C₁₁H₁₅NO₅S
• 分子量: 273.31
• InChiKey: NXQQUSLSCMZKPI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.3
• 重原子数：
  18
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.45
• 拓扑面积：
  96.2
• 氢给体数：
  1
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  2-(2-Propanon-1-yloxy)phenylsulfonamide 、 乙二醇 、 对甲苯磺酸 、 甲苯 在 水 、 碳酸氢钠 作用下， 以 乙酸乙酯 为溶剂， 反应 7.0h， 以affording 5 g of 2-(2-methyl-1,3-dioxolan-2-yl-methoxy)phenylsulfonamide in the form of a yellow viscous oil which的产率得到2-(2-methyl-1,3-dioxolan-2-yl-methoxy)phenylsulfonamide
  参考文献：
  名称：

  N-phenylsulfonyl-N'-pyrimidinyl- and -N'-triazinylureas

  摘要：

  通式为##STR1##的N-苯磺酰-N'-嘧啶脲和-N'-三嗪基脲，以及这些化合物与胺、碱金属基和碱土金属基或季铵盐基的盐，在前期和后期应用时具有良好的选择性除草和植物生长调节性能。在该式中，R.sub.1为氢、卤素、硝基、C.sub.1-C.sub.4卤代烷基、C.sub.1-C.sub.4烷基、C.sub.1-C.sub.4烷氧基、C.sub.2-C.sub.5烯基或C.sub.1-C.sub.4烷氧羰基，R.sub.2为C.sub.1-C.sub.3烷基或C.sub.1-C.sub.3烷氧基，每个未取代或被1至3个卤素原子取代，R.sub.3为卤素、氢、--NR.sub.4R.sub.5、C.sub.1-C.sub.3烷基，未取代或被1至3个卤素原子取代的C.sub.1-C.sub.4烷氧基，或为C.sub.1-C.sub.3烷氧基，未取代或被甲氧基、乙氧基或1至3个卤素原子取代，R.sub.4为氢或甲基，R.sub.5为氢、C.sub.1-C.sub.2烷基或甲氧基，A为C.sub.1-C.sub.4亚烷基或C.sub.2-C.sub.4烯亚烷基，每个未取代或被C.sub.1-C.sub.4烷基取代，m为0或1，E为氮或亚甲基基，X为氧、硫、--SO--或--SO.sub.2--，Q为羟基、氰基或从5-或6-成员杂环环和融合同系物、胺、缩醛、酯、酮、苯基、磺酸和羧酸中选择的基团，这些基团可能进一步被取代并具有功能结构。

  公开号：

  US04835311A1

文献信息

• N-phenylsulfonyl-N'-triazinylureas
  申请人：Ciba-Geigy Corporation

  公开号：US04648899A1

  公开（公告）日：1987-03-10

  N-Phenylsulfonyl-N'-pyrimidinylureas and -N'-triazinylureas of the general formula ##STR1## and the salts of these compounds with amines, alkali metal bases and alkaline earth metal bases or with quaternary ammonium bases, have good selective herbicidal and plant growth regulating properties when applied pre- and postemergence. In the formula R.sub.1 is hydrogen, halogen, nitro, C.sub.1 -C.sub.4 haloalkyl, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.2 -C.sub.5 alkenyl or C.sub.1 -C.sub.4 alkoxycarbonyl, R.sub.2 is C.sub.1 -C.sub.3 alkyl or C.sub.1 -C.sub.3 alkoxy, each unsubstituted or substituted by 1 to 3 halogen atoms, R.sub.3 is halogen, hydrogen, --NR.sub.4 R.sub.5, C.sub.1 -C.sub.3 alkyl, unsubstituted or substituted by 1 to 3 halogen atoms or C.sub.1 -C.sub.4 alkoxy, or is C.sub.1 -C.sub.3 alkoxy, unsubstituted or substituted by methoxy, ethoxy, or 1 to 3 halogen atoms, R.sub.4 is hydrogen or methyl, R.sub.5 is hydrogen, C.sub.1 -C.sub.2 alkyl or methoxy, A is C.sub.1 -C.sub.4 alkylene or C.sub.2 -C.sub.4 alkenylene, each unsubstituted or substituted by C.sub.1 -C.sub.4 alkyl, m is 0 or 1, E is nitrogen or the methine group, X is oxygen, sulfur, --SO--, or --SO.sub.2 --, and Q is hydroxyl, cyano or radicals selected from the group consisting of 5- or 6-membered heterocyclic rings and fused homologues, amines, acetals, esters, ketones, phenyls, sulfonic acid and carboxylic acids, which radicals may be further substituted and have functional structures.

  通式为##STR1##的N-苯磺酰-N'-嘧啶基脲和-N'-三嗪基脲及其与胺、碱金属碱和碱土金属碱或季铵碱的盐，在施用前和施用后具有良好的选择性除草和植物生长调节作用。在该式中，R.sub.1为氢、卤素、硝基、C.sub.1-C.sub.4卤代烷基、C.sub.1-C.sub.4烷基、C.sub.1-C.sub.4烷氧基、C.sub.2-C.sub.5烯基或C.sub.1-C.sub.4烷氧羰基，R.sub.2为C.sub.1-C.sub.3烷基或C.sub.1-C.sub.3烷氧基，每个未取代或取代1至3个卤素原子，R.sub.3为卤素、氢、--NR.sub.4 R.sub.5、C.sub.1-C.sub.3烷基、未取代或取代1至3个卤素原子或C.sub.1-C.sub.4烷氧基，或为C.sub.1-C.sub.3烷氧基，未取代或取代甲氧基、乙氧基或1至3个卤素原子，R.sub.4为氢或甲基，R.sub.5为氢、C.sub.1-C.sub.2烷基或甲氧基，A为C.sub.1-C.sub.4亚烷基或C.sub.2-C.sub.4烯亚烷基，每个未取代或取代C.sub.1-C.sub.4烷基，m为0或1，E为氮或甲基组，X为氧、硫、--SO--或--SO.sub.2--，Q为羟基、氰基或从5-或6-成员杂环环和融合同系物、胺、缩醛、酯、酮、苯基、磺酸和羧酸中选择的基团，这些基团可能进一步取代并具有功能结构。
• N-phenylsulfonyl-N'-pyrimidinylureas
  申请人：Ciba-Geigy Corporation

  公开号：US04726836A1

  公开（公告）日：1988-02-23

  N-Phenylsulfonyl-N'-pyrimidinylureas and -N'-triazinylureas of the general formula ##STR1## and the salts of these compounds with amines, alkali metal bases and alkaline earth metal bases or with quaternary ammonium bases, have good selective herbicidal and plant growth regulating properties when applied pre- and postemergence. In the formula R.sub.1 is hydrogen, halogen, nitro, C.sub.1 -C.sub.4 haloalkyl, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.2 -C.sub.5 alkenyl or C.sub.1 -C.sub.4 alkoxycarbonyl, R.sub.2 is C.sub.1 -C.sub.2 alkyl or C.sub.1 -C.sub.3 alkoxy, each unsubstituted or substituted by 1 to 3 halogen atoms, R.sub.3 is halogen, hydrogen, --NR.sub.4 R.sub.5, C.sub.1 -C.sub.3 alkyl, unsubstituted or substituted by 1 to 3 halogen atoms or C.sub.1 -C.sub.4 alkoxy, or is C.sub.1 -C.sub.3 alkoxy, unsubstituted or substituted by methoxy, ethoxy, or 1 to 3 halogen atoms, R.sub.4 is hydrogen or methyl, R.sub.5 is hydrogen, C.sub.1 -C.sub.2 alkyl or methoxy, A is C.sub.1 -C.sub.4 alkylene or C.sub.2 -C.sub.4 alkenylene, each unsubstituted or substituted by C.sub.1 -C.sub.4 alkyl, m is 0 or 1, E is nitrogen or the methine group, X is oxygen, sulfur, --SO-- or --SO.sub.2 --, and Q is hydroxyl, cyano or radicals selected from the group consisting of 5- or 6-membered heterocyclic rings and fused homologues, amines, acetals, esters, ketones, phenyls, sulfonic acid and carboxylic acids, which radicals may be further substituted and have functional structures.

  N-苯磺酰-N'-嘧啶基脲和-N'-三嗪基脲的一般式为##STR1##以及这些化合物与胺、碱金属碱和碱土金属碱或季铵盐的盐，在前和后出苗时具有良好的选择性除草和植物生长调节性能。在公式中，R.sub.1为氢、卤素、硝基、C.sub.1-C.sub.4卤代烷基、C.sub.1-C.sub.4烷基、C.sub.1-C.sub.4烷氧基、C.sub.2-C.sub.5烯基或C.sub.1-C.sub.4烷氧羰基；R.sub.2为C.sub.1-C.sub.2烷基或C.sub.1-C.sub.3烷氧基，每个未取代或取代1至3个卤素原子；R.sub.3为卤素、氢、--NR.sub.4R.sub.5、C.sub.1-C.sub.3烷基，未取代或取代1至3个卤素原子或C.sub.1-C.sub.4烷氧基，或为C.sub.1-C.sub.3烷氧基，未取代或取代甲氧基、乙氧基或1至3个卤素原子；R.sub.4为氢或甲基，R.sub.5为氢、C.sub.1-C.sub.2烷基或甲氧基；A为C.sub.1-C.sub.4亚烷基或C.sub.2-C.sub.4烯基，每个未取代或取代C.sub.1-C.sub.4烷基；m为0或1，E为氮或亚甲基基，X为氧、硫、--SO--或--SO.sub.2 --，Q为羟基、氰基或从5-或6-成员杂环环和融合同系物、胺、缩醛、酯、酮、苯基、磺酸和羧酸中选择的基团，这些基团可能进一步取代并具有功能结构。
• O-substituted-phenylsulfonamides
  申请人：Ciba-Geigy Corporation

  公开号：US04739068A1

  公开（公告）日：1988-04-19

  N-Phenylsulfonyl-N'-pyrimidinylureas and --N'-triazinylureas of the general formula ##STR1## and the salts of these compounds with amines, alkali metal bases and alkaline earth metal bases or with quaternary ammonium bases, have good selective herbicidal and plant growth regulating properties when applied pre- and postemergence. In the formula R.sub.1 is hydrogen, halogen, nitro, C.sub.1 -C.sub.4 haloalkyl, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.2 -C.sub.5 alkenyl or C.sub.1 -C.sub.4 alkoxycarbonyl, R.sub.2 is C.sub.1 -C.sub.3 alkyl or C.sub.1 -C.sub.3 alkoxy, each unsubstituted or substituted by 1 to 3 halogen atoms, R.sub.3 is halogen, hydrogen, --NR.sub.4 R.sub.5, C.sub.1 -C.sub.3 alkyl, unsubstituted or substituted by 1 to 3 halogen atoms or C.sub.1 -C.sub.4 alkoxy, or is C.sub.1 -C.sub.3 alkoxy, unsubstituted or substituted by methoxy, ethoxy, or 1 to 3 halogen atoms, R.sub.4 is hydrogen or methyl, R.sub.5 is hydrogen, C.sub.1 -C.sub.2 alkyl or methoxy, A is C.sub.1 -C.sub.4 alkylene or C.sub.2 -C.sub.4 alkenylene, each unsubstituted or substituted by C.sub.1 -C.sub.4 alkyl, m is 0 or 1, E is nitrogen or the methine group, X is oxygen, sulfur, --SO-- or --SO.sub.2 --, and Q is hydroxyl, cyano or radicals selected from the group consisting of 5- or 6-membered heterocyclic rings and fused homologues, amines, acetals, esters, ketones, phenyls, sulfonic acid and carboxylic acids, which radicals may be further substituted and have functional structures.

  通式为##STR1##的N-苯磺酰-N'-嘧啶脲和N'-三嗪基脲，以及这些化合物与胺、碱金属碱、碱土金属碱或季铵碱的盐，在预出苗和出苗后的植物生长调节和选择性除草方面具有良好的性能。其中，R.sub.1为氢、卤素、硝基、C.sub.1-C.sub.4卤代烷基、C.sub.1-C.sub.4烷基、C.sub.1-C.sub.4烷氧基、C.sub.2-C.sub.5烯基或C.sub.1-C.sub.4烷氧羰基；R.sub.2为C.sub.1-C.sub.3烷基或C.sub.1-C.sub.3烷氧基，每个未取代或取代1至3个卤素原子；R.sub.3为卤素、氢、--NR.sub.4 R.sub.5、C.sub.1-C.sub.3烷基，未取代或取代1至3个卤素原子或C.sub.1-C.sub.4烷氧基，或为C.sub.1-C.sub.3烷氧基，未取代或取代为甲氧基、乙氧基或1至3个卤素原子；R.sub.4为氢或甲基；R.sub.5为氢、C.sub.1-C.sub.2烷基或甲氧基；A为C.sub.1-C.sub.4亚烷基或C.sub.2-C.sub.4烯亚烷基，未取代或取代为C.sub.1-C.sub.4烷基；m为0或1；E为氮或亚甲基基团；X为氧、硫、--SO--或--SO.sub.2--；Q为羟基、氰基或从5-或6-成员杂环和融合同系物、胺、缩醛、酯、酮、苯基、磺酸和羧酸的基团中选择的基团，这些基团可能进一步取代并具有功能结构。
• N-Phenylsulfonyl-N'-pyrimidinyl- und -triazinylharnstoffe
  申请人：CIBA-GEIGY AG

  公开号：EP0085028A2

  公开（公告）日：1983-08-03

  N-Phenylsulfonyl-N'-pyrimidinyl- und -triazinylharnstoffe der allgemeinen Formel und die Salze dieser Verbindungen mit Aminen, Alkali- und Erdalkalimetallbasen oder quaternären Ammoniumbasen haben gute pre- und post-emergent-selektive herbizide und pflanzenwuchsregulierende Eigenschaften. In dieser Formel bedeuten R1 Wasserstoff, Halogen, Nitro, C1-C4-Halogenalkyl, Ci-C4-Alkyl, C2-Cs-Alkenyl oder C1-C4-Alkocycarbonyl, R2 gegebenenfalls durch 1-3 Halogenatome substituiertes C1-C3-Alkyl oder C1-C3-Alkoxy, R3 Wasserstoff, Halogen, -NR4Rs, gegebenenfalls durch 1-3 Halogenatome oder C1-C4-Alkoxy substituiertes C1-C3-Alkyl oder gegebenenfalls durch Methoxy, Äthoxy oder 1-3 Halogenatome substituiertes C1-C3-Alkoxy, R4 Wasserstoff oder Methyl, Rs Wasserstoff, C1-C2-Alkyl oder Methoxy, A C1-C4-Alkylen oder C2-C4-Alkenylen, m Null oder eins, E Stickstoff oder die Methingruppe, X Sauerstoff, Schwefel- -SO- oder -SO2-, Q Hydroxy, Cyan oder gegebenenfalls weiter substituierte Reste mit funktionellen Strukturen ausgewählt aus der Gruppe 5-6gliedrige Heterocyclen und benzanellierte Homologe, Amine, Acetale, Ester, Ketone, Phenyle, Sulfon- und Carbonsäuren.

  通式为 N-苯磺酰基-N'-嘧啶基-和三嗪基脲的化合物以及这些化合物与胺和碱土金属碱或季铵碱的盐类具有良好的病原前和病原后选择性除草和植物生长调节特性。 以及这些化合物与胺、碱金属碱基和碱土金属碱基或季铵盐的盐具有良好的苗前和苗后选择性除草和植物生长调节特性。 在此式中 R1 是氢、卤素、硝基、C1-C4-卤代烷基、Ci-C4-烷基、C2-Cs-烯基或 C1-C4-烷羰基、 R2 是被 1-3 个卤素原子任选取代的 C1-C3 烷基或 C1-C3 烷氧基、 R3 氢、卤素、-NR4Rs、任选被 1-3 个卤素原子取代的 C1-C3 烷基或任选被甲氧基、乙氧基或 1-3 个卤素原子取代的 C1-C4 烷氧基或 C1-C3 烷氧基、 R4 氢或甲基、 Rs 氢、C1-C2 烷基或甲氧基、 A C1-C4- 烷基或 C2-C4- 烯基、 m 零个或一个、 E 氮或甲基 X氧、硫-SO-或-SO2-、 Q 羟基、氰基或任选进一步取代的基团，其官能结构选自 5-6 元杂环和苯甲酰同系物、胺、乙醛、酯、酮、苯基、磺酸和羧酸组成的组。
• US4618363A
  申请人：——

  公开号：US4618363A

  公开（公告）日：1986-10-21